LOCTITE CORPORATION -- QUICK SET (TM) 404 INSTANT ADHESIVE, 46551
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Material Safety Data Sheet
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NIIN: 01-315-1759
MSDS Num: CJHTR
MSDS NAME: QUICK SET (TM) 404 INSTANT ADHESIVE, 46551
Responsible Party
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Info Phone: 800-243-4874
Emergency Phone Number: 860-571-5100
Resp. Party Other MSDS No.: REVISION: 0029; FAX: 860-571-5465
Preparer's Name: STEPHEN REPETTO
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
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Item Description Information
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Item Manager: N35
Item Name: ADHESIVE
Unit of Issue: EA
UI Container Qty: 1
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Ingredients
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Cas: 7085-85-0
RTECS #: UD3330000
Name: ETHYL CYANOACRYLATE
% low Wt: 90.
% high Wt: 95.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.2 PPM
ACGIH STEL: N/K (FP N)
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Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYL METHACRYLATE; (POLY (METHYL METHACRYLATE))
% low Wt: 5.
% high Wt: 10.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE
% low Wt: .1
% high Wt: 1.
Other REC Limits: N/K (FP N)
OSHA PEL: 2 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 2 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Health Hazards Data
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LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND
STRONGLY. SKIN AND EYE IRRITANT.
Signs And Symptions Of Overexposure: VAPOR IS IRRITATING TO EYES AND MUCOUS
MEMBRANES ABOVE TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY
PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA IN SENSITIVE INDIVIDUALS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: CYANOACRYLATE ADHESIVE IS A VERY FAST SETTING & STRONG ADHESIVE.
IT BONDS HUMAN TISS INCL SKIN IN SECS. EXPERIENCE HAS SHOWN THAT ACCIDENTS
DUE TO CYANOACRYLATES ARE HANDLED BEST BY PASSIVE, NONSURGIC AL FIRST AID.
TREATMENT OF SPECIFIC TYPES OF ACCIDENTS ARE GIVEN BELOW. INGEST: NOT LIKELY.
IF LIPS ARE ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM WATER TO LIPS
& ENCOURAGE MAX WETTING & PRESS FR OM SALIVA INSIDE MOUTH. PEEL/ROLL
LIPS APART. DO NOT TRY TO PULL LIPS W/DIRECT OPPOSING ACTION. IT IS ALMOST
IMPOSS TO SWALLOW CYANOACRYLATE. ADHESIVE SOLIDIFIES & ADHERES IN MOUTH.
(SUP DAT)
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Handling and Disposal
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Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE COMPLETELY. SOAK UP
WITH AN INERT ABSORBENT.
Waste Disposal Methods: POLYMERIZE AS ABOVE. INCINERATE IN ACCORDANCE WITH EPA
AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: NH - NOT A RCRA HAZARDOUS
WASTE MATERIAL. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDE RAL
REGULATIONS (FP N).
Handling And Storage Precautions: STORE AT OR BELOW 75F. CONTACT LOCTITE
CUSTOMER HANDLING SERVICE 1-800-243-4874 FOR SHELF LIFE INFORMATION. AVOID
CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: >65.6C, 150.F
Flash Point Text: 150F-200F
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE. HAZARDOUS PRODUCTS FORMED BY FIRE OR
THERMAL DECOMPOSITION: IRRITATING ORGANIC VAPORS.
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Control Measures
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Respiratory Protection: NOT AVAILABLE. USE NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES. DO NOT USE COTTON.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). NITRILE OR POLYETHYLENE APRONS. DO NOT USE COTTON.
Supplemental Safety and Health: FIRST AID PROC: SALIVA WILL LIFT ADHESIVE IN
ONE HALF TO TWO DAYS. IN CASE LUMP FORMS IN MOUTH, POSITION PATIENT TO PVNT
INGEST OF LUMP WHEN IT DETACHES. INHAL: REMOVE TO FRESH AIR. IF SYMPS
PERSIST, OBTAIN MED ATTN. SKIN: REMOVE EXCESS ADHESIVE. SOAK IN WARM SOAPY
WATER. (OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: >148.9C, 300.F
Vapor Pres: <0.2 MM
Vapor Density: APPROX 3
Spec Gravity: 1.09 @ 75F
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: CLEAR LIQUID WITH PUNGENT ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NOT AVAILABLE.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: ESTIMATED ORAL LD50: >5000 MG/KG. ESTIMATED
DERMAL LD50: >2000 MG/KG.
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Ecological Information
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Ecological: NO DATA AVAIL. OTHER INFO: & STRONG, IRRITATING VAPS. WEAR
NITRILE/POLYETHYLENE GLOVES & APRON WHEN HNDLG LGE AMTS OF ADHESIVE. SKIN
ADHESION: FIRST IMMERSE BONDED SURFS IN WARM, SOAPY WATER. PEEL/ROL L SURFS
APART W/AID OF BLUNT EDGE, E.G.SPATULA/TEASPOON HANDLE; THEN REMOVE ADHESIVE
FROM SKIN W/SOAP & WATER. DO NOT TRY TO PULL SURFS APART W/DIRECT
OPPOSING ACTION. EYELID TO EYELID/EYEBALL ADHESIO N: IN EVENT THAT EYELIDS
ARE STUCK TOGETHER/BONDED TO EYEBALL, WASH THORO W/WARM WATER FOR AT LEAST 15
MINS & APPLY GAUZE PATCH. EYE WILL OPEN W/OUT FURTHER ACTION, TYPICALLY
IN 1-4 DAYS. (SARA REG IN FO)
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MSDS Transport Information
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Transport Information: DOT (49 CFR 172): DOMESTIC GROUND TRANSPORT: PROPER
SHIPPING NAME: UNRESTRICTED (NOT MORE THAN 450 LITERS), COMBUST LIQS, N.O.S.
(CYANOACRYLATE ESTER) (MORE THAN 450 LITERS); HAZ CLASS/DIVISION: UNRES
TRICTED (NOT MORE THAN 450 LITERS), COMBUST LIQ (MORE THAN 450 LITERS);
IDENTIFICATION #: NONE (NOT MORE THAN 450 LITERS), NA 1993 (MORE THAN 450
LITERS); MARINE POLLUTANT: NONE. IATA: PROPER SHIPPING NAME: UNRESTRICTED
(NOT MORE THAN 1 PINT), OTHER REGULATED SUBSTANCES (MORE THAN 1 PINT);
CLASS/DIVISION: UNRESTRICTED (NOT MORE THAN 1 PINT), CLASS 9 (MORE THAN 1
PINT); UN/ID #: NONE (NOT MORE THAN 1 PINT), ID 8027 (MORE THAN 1 PINT).
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Regulatory Information
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Sara Title III Information: ECOLOGICAL INFO: THERE WILL BE NO RESIDUAL DMG. DO
NOT TRY TO OPEN EYES BY MANIPULATION. ADHESIVE TO EYEBALL: CYANOACRYLATE
INTRODUCED INTO EYES WILL ATTACH ITSELF TO EYE PROTEIN & WILL
DISASSOCIATE F ROM IT OVER INTERMITTENT PERIODS, GEN COVERING SEVERAL HRS.
THIS WILL CAUSE PERIODS OF WEEPING UNTIL CLEARANCE IS ACHIEVED. DURING PERIOD
OF CONTAM, DOUBLE VISION MAY BE EXPERIENCED TOGETHER W/LACHRYM ATORY EFT,
& IT IS IMPORTANT TO UNDERSTAND CAUSE & REALIZE THAT DISASSOCIATION
WILL NORMALLY OCCUR W/IN A MATTER OF HRS, EVEN W/GROSS CONTAM. (FED REG INFO)
Federal Regulatory Information: SARA REG INFO: BURNS: CYANOACRYLATES GIVE OFF
HEAT ON SOLIDIFICATION. IN RARE CASES A LARGE DROP WILL INCREASE IN
TEMPERATURE ENOUGH TO CAUSE A BURN. BURNS SHOULD BE TREATED NORMALLY AFTER
THE LUMP OR CYANOACRYLATE IS RELEASED FROM THE TISSUE AS DESCRIBED ABOVE.
SURGERY: IT SHOULD NEVER BE NECESSARY TO USE SUCH A DRASTIC METHOD TO
SEPARATE ACCIDENTALLY BONDED SKIN.
State Regulatory Information: CA PROPOSITION 65: NOT AVAILABLE.
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Other Information
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Other Information: VOC (EPA METH 24): 93.0%; 1013.7 G/L. ESTIMATED NFPA(R)
CODE: HLTH HAZ/FIRE HAZ: 2; REACTIVITY HAZ: 1; SPECIFIC HAZ: N/A. ESTIMATED
(R) CODE: HLTH HAZ/FIRE HAZ:2; REACTIVITY HAZ: 1; PERS PROT: SEE CTL
MEASURES SECTION. NFPA IS A REGISTERED TRADEMARK OF NATL FIRE PROT ASSN. IS
A REGISTERED TRADEMARK OF NATL PAINT & COATINGS ASSN. SUP DAT: ADHESIVE
WILL COME LOOSE FROM SKIN IN SEVERAL HRS. CURED ADHESIVE DOES NOT PRESENT
HLTH HAZ EVEN WHEN BONDED TO SKIN. AVOID CONTW/CLOTHES, FABRICS, RAGS/TISS.
CONT W/THESE MATLS MAY CAUSE POLYM. POLYM OF LGE AMTS OF ADHESIVE WILL
GENERATE HEAT CAUSING SMOKE, SKIN BURNS (ECOLOGICAL INFO)
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Transportation Information
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Trans ID NO: 146884
MSDS NAME: QUICK SET (TM) 404 INSTANT ADHESIVE, 46551
MSDS Prepared Date: 09/08/1998
Review Date: 08/03/1999
Multiple KIT Number: 0
Unit Of Issue: EA
Container QTY: 1
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: QUICK SET (TM) 404 INSTANT ADHESIVE, 46551
Company: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT
Zipcode: 06067-3910
Health Emergency Phone: 860-571-5100
Label Required IND: Y
Date Of Label Review: 07/16/1999
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: SKIN CONTACT MAY CAUSE BURNS. BONDS
SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT. VAPOR IS IRRITATING TO EYES
AND MUCOUS MEMBRANES ABOVE TLV. CHRONIC: PROLONGED AND REPEATED OV EREXPOSURE
TO VAPORS MAY PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA IN SENEITIVE
INDIVIDUALS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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