US PAINT CORPORATION -- K LINE - LEAD FREE, AWLGRIP #2 HIGH SOLIDS (S
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Material Safety Data Sheet
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MSDS Num: CJHCM
MSDS NAME: K LINE - LEAD FREE, AWLGRIP #2 HIGH SOLIDS (SUPDAT)
Responsible Party
Name: US PAINT CORPORATION
Address: 831 S 21ST ST
City: ST LOUIS MO 63103-3043
Info Phone: 314-621-0525
Emergency Phone Number: 703-527-3887
Preparer's Name: ENVIR, HLTH & SFTY DEPT
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
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Item Description Information
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Ingredients
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Cas: 79-24-3
RTECS #: KI5600000
Name: NITROETHANE VP: 15.6 MMHG @ 20C. LD50: (ORAL, RAT) 1.1 G/KG.
% low Wt: 0.
% high Wt: 2.
OSHA PEL: 310 MG/M3;100 PPM
ACGIH TLV: 307 MG/M3;100 PPM
ACGIH STEL: NOT ESTABLISHED
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Cas: 108-03-2
RTECS #: TZ5075000
Name: 1-NITROPROPANE VP: 7.5 MMHG @ 20C. LD50: (ORAL, RAT) 0.46 G/KG.
% low Wt: 0.
% high Wt: 2.
OSHA PEL: 90 MG/M3;25 PPM
ACGIH TLV: 91 MG/M3;25 PPM
ACGIH STEL: NOT ESTABLISHED
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE. VP: 5.1 MMHG @ 20C. LD50: (ORAL, RAT) 4.3 G/KG.
% low Wt: 0.
% high Wt: 6.
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 78-93-3
RTECS #: EL6475000
Name: METHYL ETHYL KETONE. VP: 70 MMHG @ 20C. LD50: (ORAL, RAT) 2.7 G/KG.
% low Wt: 6.
% high Wt: 7.
OSHA PEL: 590 MG/M3;200 PPM
ACGIH TLV: 590 MG/M3;200 PPM
ACGIH STEL: 885 MG/M3;300 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 110-43-0
RTECS #: MJ5075000
Name: METHYL N-AMYL KETONE VP: 2.14 MMHG @ 20C. LD50: (ORAL, RAT) 1.7 G/KG
% low Wt: 0.
% high Wt: 8.
OSHA PEL: 465 MG/M3;100 PPM
ACGIH TLV: 233 MG/M3;50 PPM
ACGIH STEL: NOT ESTABLISHED
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Cas: 64742-95-6
RTECS #: WF3400000
Name: SOLVENT NAPHTHA (PETROLEUM) LIGHT AROMATIC; (AROMATIC PETROLEUM
DISTILLATES) VP: 3.0 MMHG @ 20C. LD50: (ORAL, RAT) 4.7 G/KG.
% low Wt: 0.
% high Wt: 2.
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Cas: 7440-66-6
RTECS #: ZG8600000
Name: ZINC
% low Wt: 0.
% high Wt: 1.
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 141-78-6
RTECS #: AH5425000
Name: ETHYL ACETATE VP: 76 MMHG @ 20C. LD50: (ORAL, RAT) 5.1 G/KG.
% low Wt: 0.
% high Wt: 3.
OSHA PEL: 1400 MG/M3;400 PPM
ACGIH TLV: 1440 MG/M3;400 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 108-65-6
RTECS #: AI8925000
Name: PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE VP: 37 MMHG @ 20C. LD50:
(ORAL, RAT) 8.5 G/KG.
% low Wt: 0.
% high Wt: 9.
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Name: PIGMENTS
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: CAN CAUSE SEV IRRIT, STINGING, REDNESS, TEARING,
SWELL & EYE DMG. CAN CAUSE SEV INJURY-DMG REVERSIBLE. MAY CAUSE BURNS.
SKIN: PRLNGD/RPTD CNTCT CAN CAUSE MOD IRRIT, DEFAT & DERM. MATL IS
READILY ABSORBED THRU SKIN IN TOX AMTS. SENSITIZER-CAN CAUSE ALLERGIC SKIN
RXN WHICH MAY BE SEV IN CERTAIN PERS. PERS W/PRE-EXISTING SKIN DISORDERS MAY
BE MORE SUSCEPTIBLE TO EFTS OF MATL. PRLNGD CNTCT MAY R SLT IN CHEM BURNS
& PERM DMG. INHAL: CAN CAUSE NASAL & RESP TRACT IRRIT. CAN CAUSE CNS
EFTS INCLUDING FATG, WEAK, HDCH, DIZZ, NAUS, VOMIT, UNCON, COMA, RESP FAILURE
& DEATH. PRLNGD EXPOS CAN CAUSE HEA RING IMPAIRMENT. (EFFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZS: INGEST: MOD TOX. CAN CAUSE
IRRIT OF DIGEST TRACT, NAUS, VOMIT & DIARR. CAN CAUSE HDCH, DROW &
UNCON. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL.
POTNTL CHRONIC EFTS: PRLNGD & RPTD BRTHG OF VAPS, SPRAY, MIST &/OR
SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF LUNGS. RPTS HAVE ASSOC
RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/BRAIN & NERVOUS SYS DMG.
INTENTIONAL MISUSE BY DELIB CONC & INHALING PROD MAY BE HARMFUL/FATAL.
TARGET ORGANS: OVEREXP TO MATL/ITS COMPONENTS HAS BEEN SUGGESTED AS CAUSE OF
FOLLOWING EFTS IN LAB ANIMALS &/OR HUMANS & MAY AGGRAVATE PRE-EX
ISTING DISORDERS OF THESE (SUPDAT)
Medical Cond Aggravated By Exposure: ANEMIA, BLOOD DISORDERS, CARD ABNORM,
BRAIN, EYE, KIDNEY & LUNG DMG, LIVER ABNORMS, MENSTRUAL & FERTILITY
DISORDERS, REPRO ORGANS ABNORMS, SKIN & SPLEEN DMG, RESP SYS, CNS &
PERIPHERAL NERVOUS SYS.
First Aid: EYES: FLUSH W/WATER FOR AT LST 15 MIN WHILE HOLDING LIDS APART. SEEK
MED ATTN. SKIN: REMOVE CONTAM CLTHG & FLUSH CONTAM SKIN W/LG AMTS OF
WATER. IF SKIN IS DAMAGED/IF SYMPS PERSIST SEEK MED ATTN. LAUN DER CLTHG
BEFORE REUSE. INHAL: IF SYMPS DEVELOP, IMMED MOVE AWAY FROM EXPOS & INTO
FRESH AIR. SEEK IMMED MED ATTN. KEEP WARM & QUIET. IF NOT BRTHG BEGIN
ARTF RESP. IF BRTHG IS DFCLT, ADMIN OXYG. INGES T: DO NOT INDUCE VOMIT UNLESS
DIRECTED BY MED PERS. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH
MAY BE FATAL. IF DROWSY/UNCON, PLACE ON SIDE W/HEAD DOWN. SEEK MED ATTN. IF
POSS, DO NOT LEAVE UNATTENDED.
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Handling and Disposal
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Spill Release Procedures: SM SPILL:ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT
SOURCES (FLARES, FLAMES, INCL PILOT LIGHT, ELEC SPKS). PERS NOT WEARING PROT
EQUI P SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP COMPLETED. STOP
SPILL AT SOURCE, CNTN AREA OF SPILL TO PVNT SPREADING, PUMP LIQ TO SALVAGE
TANK. REMAINING LIQ MAY BE ABSORBED (FED REGULATORY)
Waste Disposal Methods: DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER AND UNUSED
CONTENTS IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: SENSITIVITY TO STATIC DISCHARGE -
GROUNDING/BONDING REQUIRED. KEEP CONTAINER TIGHT & UPRIGHT TO PREVENT
LEAKAGE. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT STORE ABOVE 40C/120F.
DO NOT TRANSFER CON TENTS TO BOTTLES OR OTHER UNLABELED CONTAINERS. PROTECT
FROM FREEZING.
Other Precautions: CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED
BECAUSE THEY RETAIN PRODUCT RESIDUES (VAPOR, LIQUID &/OR SOLID). WHEN
EMPTY, MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEAR
THIS CONTAINER. ALL HAZARD PRECAUTIONS GIVEN IN MSDS MUST BE OBSERVED FOR
EMPTY CONTAINERS.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =-6.C, 21.2F
Autoignition Temp: =414.C, 777.2F
Lower Limits: 0.6%
Upper Limits: 13.1%
Extinguishing Media: CARBON DIOXIDE/DRY CHEM FOR SM FIRES; ALCOHOL-TYPE AQ
FILM-FORMING FOAM/WATER SPRAY FOR LG FIRES. WATER MAY BE INEFTIVE BUT SHOULD
BE USED TO COOL FIRE-EXPOS STRUCTURES & VESSELS.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
IN CASE OF FIRE, USE DRY CHEM, FOAM, CO*2 OR OTHER APPRVD METH FOR TREATING
CLASS B FIRE. SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX GASES &
SMO KE ARE IRRITANTS PRESENT FROM DECOMP/COMBUST. CLSD CNTNR MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard: FLAMMABILITY CLASSIFICATION: 1B. KEEP AWAY FROM
HEAT, SPKS & FLAME. DO NOT SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF
ALL SOURCES OF IGNIT, INCL HEATERS, FANS & OTHER NON-EXPLO PROOF ELEC
EQUIP, DURING USE & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLO. VAPS
MAY SPREAD LONG DISTS & BEYOND CLSD (FED REGULATORY)
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Control Measures
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Respiratory Protection: USE ONLY W/ADEQ VENT. MAINTAIN CONTINUOUS FLOW OF FRESH
AIR. DO NOT BREATHE VAPS, SPRAY MISTS OR SANDING DUSTS. WEAR APPROP NIOSH
APPRVD, PROPERLY FITTED RESP DURING & AFTER APPLICATN UNLESS AIR MONIT
ORING DEMONSTRATES VAP & PARTICULATE LEVELS ARE BELOW APPLIC LIMS. FOLLOW
RESP MFR'S DIRECTIONS FOR RESP USE.
Ventilation: ENGINEERING OR ADMIN CTLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS.
PROVIDE SUFFICIENT MECH (GEN &/OR LOC EXHST) VENT TO MAINTAIN EXPOS BELOW
TLVS.
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES & FULL LENGTH FACESHIELD (FP
N).
Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N).
SOLVENT IMPERMEABLE CLOTHING AND BOOTS SHOULD BE WORN TO PREVENT SKIN
CONTACT.
Work Hygienic Practices: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: POLYURETHANE TOPCOAT
- GLOSS. EFTS OF OVEREXP: ORGANS IN HUMANS: ANEMIA, BLOOD DISORDERS, BRAIN
DMG, CARD ABNORM, EYE DMG, KIDNEY DMG, LIVER ABNORMS, LUNG DMG, MENSTRUAL
& FE RTILITY DISORDERS, ABNORMS OF REPRO ORGANS, SKIN DMG, SPLEEN DMG,
RESP SYS, CNS & PERIPHERAL NERVOUS SYS (PNS).
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Physical/Chemical Properties
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Boiling Point: >76.C, 168.8F
B.P. Text: 76-213C/168-425F
Vapor Pres: SEE INGREDS
Vapor Density: 4.60
Spec Gravity: 1.11-1.58
Evaporation Rate & Reference: 0 (N-BUTYL ACETATE=1)
Appearance and Odor: LIQUID.
Percent Volatiles by Volume: 37-39
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Reactivity Data
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Stability Indicator: YES AGENTS, (FED REGULATORY)
Stability Condition To Avoid: STABLE UNDER ORDINARY CONDITIONS OF USE AND
STORAGE.
Materials To Avoid: ACIDS, ALUMINUM, ALKALI, ALKANOLAMINES, ALDEHYDES, AMINES,
AMMONIA, STRONG BASES, INORGANIC BASES, CAUSTICS, CALCIUM (II) HYDROXIDE,
CHLORINATED CMPDS, HALOGENATED HYDROCARBS, HYDROCARBS, HYDROXIDES, METAL
OXIDES, OXIDIZING
Hazardous Decomposition Products: (INCLUDING THERMAL DECOMP) CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, VARIOUS HYDROCARBONS, TOXIC FUMES, TOXIC
FUMES OF SULFUR OXIDES AND ACRID SMOKE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: NO ADDITIONAL TOXICOLOGICAL DATA AVAIL. PLEASE RESER
TO INGRED & HLTH HAZ SECTIONS.
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Ecological Information
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Ecological: NO ECOLOGICAL DATA AVAILABLE FOR THIS PROD.
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MSDS Transport Information
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Transport Information: DOT HAZARD CLASS: 3. DOT PROPER SHIPPING NAME: PAINT.
DOT PACKAGING GROUP: II. DOT PLACARD: FLAMMABLE. DOT LABEL: FLAMMABLE LIQUID.
UN/NA NUMBER: 1263.
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Regulatory Information
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Sara Title III Information: THIS PROD CONTAINS THE FOLLOWING SUBSTANCES SUBJECT
TO REPORTING REQS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS
& REAUTHORIZATION ACT OF 1986 & 40 CFR 372: XYLENE, CAS #1330-20-7, %
BY W T: 0-5; METHYL ETHYL KETONE, CAS #78-93-3, % BY WT: 0-7; ZINC, CAS
#7440-66-6, % BY WT: 0-1.
Federal Regulatory Information: EXPLO HAZ: DOORS. PVNT BUILD UP OF VAPS BY
MAINTAINING A CONTINUOUS FLOW OF FRESH AIR. SPILL PROCS: W/INERT MATL SUCH AS
SAND, CLAY, EARTH OR FLOOR ABSORB & SHOVELED INTO CNTNRS W/NON-SPKG
TOOLS. PVNT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF
OCCURS NOTIFY PROPER AUTHS AS REQD THAT A SPILL HAS OCCURRED. MATLS TO AVOID:
PHOSPHOROUS, SODIUM HYDROXIDE & POTASSIUM HYDROXIDE. THIS PROD WILL
DISSOLVE SOME PLASTICS, RUBBER & COATINGS.
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Other Information
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Other Information: VOC OF MATL: 331-338 G/L OR 276-282 LBS/GAL. IMPORTANT! THIS
PROD MAY BE BLENDED W/OTHER PRODS PRIOR TO USE. READ ALL WARNINGS &
PRECAUTIONS ON MSDS & LABELS OF ALL PRODS BEING BLENDED AS COMBINATION
MAY CONTAIN HAZS OF EACH COMPONENT. FOR INDUSTRIAL USE ONLY - THIS PROD IS
FOR USE BY PROFESSIONAL, TRAINED PERSONNEL USING PROPER EQUIP, & IS NOT
INTENDED FOR SALE TO, OR USE BY THE GENERAL PUBLIC. T HIS PROD CNTNS PIGMENTS
WHICH MAY BECOME DUST NUISANCE WHEN REMOVED BY ABRASIVE BLASTING, SANDING OR
GRINDING. AIRBORNE NUISANCE PARTICULATES HAVE ACGIH TLV FOR TDUST OF 10
MG/M3.
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HAZCOM Label
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MSDS NAME: K LINE - LEAD FREE, AWLGRIP #2 HIGH SOLIDS (SUPDAT)
Company: US PAINT CORPORATION
Street: 831 SOUTH 21ST STREET
City: ST LOUIS MO
Zipcode: 63103-3092
Health Emergency Phone: 703-527-3887
Label Required IND: Y
Date Of Label Review: 04/07/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAM. ACUTE: EYES: CAN CAUSE SEV IRRIT, STINGING,
REDNESS, TEARING, SWELL & DMG. CAN CAUSE SEV INJURY-DMG REVERSIBLE. MAY
CAUSE BURNS. SKIN: PRLNGD/RPTD CNTCT CAN CAUSE MOD IRRIT, DEFAT & DERM.
MATL I S READILY ABSORBED IN TOX AMTS. SENSITIZER-CAN CAUSE ALLERGIC SKIN RXN
WHICH MAY BE SEV IN CERTAIN PERS.PRLNGD CNTCT MAY RSLT IN CHEM BURNS &
PERM DMG. INHAL: CAN CAUSE NASAL & RESP TRACT IRRIT. CAN C AUSE CNS EFTS
INCLUDING FATG, WEAK, HDCH, DIZZ, NAUS, VOMIT, UNCON, COMA, RESP FAILURE
& DEATH. CHRONIC: PRLNGD & RPTD INHAL OVER PERIOD OF YRS MAY CAUSE
LUNG DISEASES. RPTS HAVE ASSOC RPTD & PRLNGD O CCUP OVEREXP TO SOLVS
W/BRAIN & NERV SYS DMG.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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