LUCAS-MILHAUPT INC -- SILVER COPPER NICKEL ZINC BRAZING ALLOYS
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Material Safety Data Sheet
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NIIN: 01-388-4564
MSDS Num: CJHHL
MSDS NAME: SILVER COPPER NICKEL ZINC BRAZING ALLOYS
Responsible Party
Name: LUCAS-MILHAUPT INC
Address: 5656 S PENNSYLVANIA AVE
City: CUDAHY WI 53110-2453
Info Phone: 800-558-6003 JIM BACH/414-769-6000
Emergency Phone Number: 800-424-9300(CHEMTREC)
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Phone: 414-769-6000
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Item Description Information
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Item Manager: S9G
Specification Number: UNKNOWN
Unit of Issue: CL
Quantitative Expression: 00000000016OZ
UI Container Qty: 0
Type of Container: COIL, WIRE
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Ingredients
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA 313) (CERCLA)
% low Wt: 19.
% high Wt: 60.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.1MG/M3 FUME/1 DUST
ACGIH TLV: 0.2 MG/M3 FUME; 9596
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7440-02-0
RTECS #: QR5950000
Name: NICKEL (SARA 313) (CERCLA)
% low Wt: .5
% high Wt: 5.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3; 9596
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Cas: 7440-22-4
RTECS #: VW3500000
Name: SILVER (SARA 313) (CERCLA)
% low Wt: 1.
% high Wt: 55.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.01 MG/M3
ACGIH TLV: 0.1 MG/M3; 9596
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 7440-66-6
RTECS #: ZG8600000
Name: ZINC (SARA 313) (CERCLA)
% low Wt: 4.
% high Wt: 44.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: UNKNOWN
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: INHALATION OF THE COMPONENTS OF THESE PRODUCTS IS NOT
KNOWN TO PRESENT A SIGNIFICANT RISK TO HEALTH WHEN USED ACCORDING TO
INSTRUCTIONS & WITH APPROPRIATE PROTECTIVE MEASURES. INHALATION OF
COMPONENET ELEMENTS HAS BEEN REPORTED TO CAUSE ONE OR MORE OF THE FOLLOWING
SYMPTOMS AND EFFECTS UPON EXCESSIVELY HIGH OR PROLONGED EXPOSURE. (SEE
OVEREXPOSURE)
Explanation Of Carcinogenicity: NICKEL IS CLASSIFIED AS A POTENTIAL HUMAN
CARCINOGEN BY: IARC (GROUP 2B); NTP (GROUP 2B). NONE OF THE OTHER COMPONENTS
OF THESE PRODUCTS ARE CLASSIFIED AS POTENTIAL OR DEMONSTRATED CARCINOGENS BY
IARC , NTP OR OSHA.
Signs And Symptions Of Overexposure: COPPER: MAY CAUSE RESPIRATORY TRACT
IRRITATION, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & A METALLIC
TASTE. MAY DAMAGE THE LIVER, KIDNEY, SLEEN, PANCREAS & BRAIN. NICKEL:
MAY CAUSE HEADACHE, N AUSEA, VERTIGO, ASTHMA & PULMONARY EDEMA. MAY
INCREASE THE RISK OF CANCER TO THE NASOPHARYNX, LUNGS, PROSTATE & KIDNEY.
SILVER: MAY PRODUCE ARGYRIA, A PERMANENT BLUE-GRAY DISCOLORATION OF THE
SKIN, EYES, MUCOUS MEMBRANES & RESPIRATORY TRACT. ZINC: MAY CAUSE
RESPIRATORY TRACT IRRITATION & "METAL FUME FEVER" A METALLIC TASTE,
COUGH, DRY THROAT, CHILLS, FEVER, TIGHTNESS OF CHEST, HEADACHE, NAUSEA,
SHORTNESS OF BREATH, VOMITING & FATIGUE.
Medical Cond Aggravated By Exposure: PRE-EXIST PULMONARY DISEASES (E.G.
BRONCHITIS, ASTHMA) MAY BE AGGRAVATED BY INHALATION EXPOSURE, PARTICULARY AS
FUME. MAY AGGRAVATE THE LIVER, KIDNEYS, GASTROINTESTINAL SYSTEM,
MUSCULOSKELETAL SYSTEM.
First Aid: INHALATION-REMOVE SUBJECT FROM AREA, ADMINISTER OXYGEN & SEEK
MEDICAL ATTENTION.KEEP THE SUBJECT WARM & AT REST. PERFORM ARTIFICIAL
RESPIRATION IF BREATHING HAS STOPPED. SKIN-REMOVE CONTAMINATED CLOTH ING.
WASH AFFECTED AREA WITH LARGE QUANTITIES OF WATER FOR 5 MIN. SEEK MEDICAL
ASSISTANCE IF NEEDED. EYE-FLUSH AFFECTED AREA WITH WATER FOR 15 MIN. SEEK
MEDICAL ASSISTANCE IF NEEDED. IF CONSCIOUS, IND UCE VOMITING. IF CONSCIOUS OR
CONVULSIVE, SEEK IMMEDIATE MEDICAL ASSISTANCE.
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Handling and Disposal
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Spill Release Procedures: IF A FINELY DIVIDED FORM OF PRODUCT IS SPILLED,
CLEANUP SPILLAGE SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR
VACUUMING USING HEPA FILTRATION ARE RECOMMENDED.
Waste Disposal Methods: CONSULT THE MANUFACTURER FOR DISPOSITION OF UNUSED OR
UNUSABLE PRODUCT.
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMPATIBLE
MATERIALS.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE DRY CHEMICAL. DO NOT USE WATER.
Fire Fighting Procedures: IF FIGHTING A FIRE IN WHICH THESE PRODUCT ARE
PRESENT, WEAR A SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard: THESE PRODUCTS MAY REACT VIGOROUSLY OR IGNITE
WHEN EXPOSED TO INCOMPATIBLE MATERIALS. IF PRESENT IN A FIRE OR EXPLOSION,
THEY WILL EMIT FUMES OF THE CONSTITUENT METALS AND/OR METAL OXIDES.
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Control Measures
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Respiratory Protection: IF EXPOSURE LEVEL EXCEEDS OSHA PEL WEAR NIOSH/MSHA
APPROVED RESPIRATOR HAVING CONFIGURATION (CLASS,TYPE OF FACPIECE,FILTER
MEDIA,ASSIGNED PROTECTION FACTOR,ETC) APPROPRIATE TO CONCENTRATION OFTHE CONT
AMINANTS GENERATED. SELECTION GUIDANCE/PROPER USE SEE ANSI Z99.2-1992.
Ventilation: USE APPROPIATE VENTILATION (E.G. DILUTION, LOCAL EXHAUST) ADEQUATE
TO MAINTAIN CONCENTRATIONS OF ALL COMPONENTS & THEIR BY PRODUCTS.
Protective Gloves: APPROPRIATE PROTECTIVE GLOVES. AVOID FLAMMABLE FABRICS.
Eye Protection: SAFETY GLASSES, GOGGLES.
Other Protective Equipment: WEAR APPROPIATE PROTECTIVE GLOVES AND CLOTHING TO
PREVENT SKIN INJURIES FROM THE HAZARDS OF BRAZING AND FOR PROLONGED CONTACT
WITH FINLEY DIVIDED FORMS OF PRODUCT.
Work Hygienic Practices: TO AVOID INGESTION, WASH HANDS AND FACE BEFORE EATING,
DRINKING OR USING COSMETICS OR TABACCO.
Supplemental Safety and Health: EYE PROTECTION-PLASTIC FRAMED SPECTACLES WITH
SIDE SHIELDS AND FILTER LENSES (SHADE #3 OR #4) ARE RECOMMENDED.
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Physical/Chemical Properties
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HCC: N1
Melt/Freeze Pt: >660.C, ######F
Solubility in Water: INSOLUBLE
Appearance and Odor: NO ODOR,WHITE TO LIGHT YELLOW
METALS,FORM:WIRE,ROD,STRIP,POWDER,GRAIN,PREF SHAP
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Reactivity Data
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Stability Indicator: YES NITROBENZENE; SELENINYL BROM
Stability Condition To Avoid: SILVER AND COPPER CAN FORM UNSTABLE ACETYLIDES
UPON CONTACT WITH ACETYLENE GAS.
Materials To Avoid: SE; TE; MG; CHLORATES; NH3; HNO3; AZIDES, ETHANOL, ETHYLENE
IMINE; CLF3; INORGANIC AND ORGANIC PEROXIDES; PEROXYFORMIC ACID; CHLORINE AND
FLUORINE; PERMONOSULFURIC ACID; CRO3; MN AND CA CHLORIDES; CS2; HYDRAZINE
MONONITRATE
Hazardous Decomposition Products: HEATING TO ELEVATED TEMPS MAY LIBERATE
METAL/METAL OXIDE FUME.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: GENERIC/REPRODUCTIVE EFFECTS; NICKEL HAS PRODUCED
FETOTOXIC AND TERATOGENIC EFFECTS IN ANIMAL STUDIES AND MUTAGENIC RESPONSES
IN MAMMALIAN CELL CULTURES.
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Ecological Information
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MSDS Transport Information
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Transport Information: SHIPMENT NOT CONTROLLED BY USDOT/IATA/ICAO/IMO
REGULATIONS.
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Regulatory Information
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Sara Title III Information: COPPER, NICKEL, SILVER AND ZINC.
State Regulatory Information: WARNING: THESES PRODUCTS CONTAIN A CHEMICAL KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
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Other Information
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Transportation Information
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Trans ID NO: 145716
MSDS NAME: SILVER COPPER NICKEL ZINC BRAZING ALLOYS
MSDS Prepared Date: 02/03/1998
Review Date: 07/09/1999
Multiple KIT Number: 0
Unit Of Issue: CL
Container QTY: 0
Type Of Container: COIL, WIRE
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: SILVER COPPER NICKEL ZINC BRAZING ALLOYS
Company: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI
Zipcode: 53110
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 07/09/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: INHALATION OF THE COMPONENTS OF THESE PRODUCTS IS NOT
KNOWN TO PRESENT A SIGNIFICANT RISK TO HEALTH WHEN USED ACCORDING TO
INSTRUCTIONS & WITH APPROPRIATE PROTECTIVE MEASURES. INHALATION OF
COMPONENET ELEMENTS HAS BEEN REPORTED TO CAUSE ONEOR MORE OF THE FOLLOWING
SYMPTOMS AND EFFECTS UPON EXCESSIVELY HIGH OR PROLONGED EXPOSURE. (SEE
OVEREXPOSURE)
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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