ALLIEDSIGNAL LAMINATE SYSTEMS -- FR406 N
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CJHHT
MSDS NAME: FR406 N
Responsible Party
Name: ALLIEDSIGNAL LAMINATE SYSTEMS
Address: 230 NORTH FRONT ST
Box: 1448
City: LA CROSSE WI 54602-1448
Info Phone: 608-784-6070
Emergency Phone Number: 608-784-6070
Resp. Party Other MSDS No.: ASLS0095
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ALLIEDSIGNAL LAMINATE SYSTEMS INC
Address: 230 N FRONT ST
Box: 1448
City: LA CROSSE WI 54602-1448
Phone: 608-784-6070
=======================================================
Item Description Information
=======================================================
Item Name: GLASS FABRIC-REINFORCED, EPOXY PREPREG
Type/Grade/Class: TYPE GFN; NEMA:FR-4
=======================================================
Ingredients
=======================================================
Name: *** PROPRIETARY ***
-----------------------------
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: DUST MAY CAUSE MODERATE IRRITATION. EYES:
DUST MAY CAUSE MODERATE IRRITATION. FUMES MAY IRRITATE EYES. INHALATION:
FIBROUS GLASS DUST MAY BE RELEASED FROM THE FIBER-GLASS CLOTH SUBSTANCE WHEN
MACHINED. ACGIH TLV IS 10 MG/M3 TWA FOR PARTICULATES <5 MICRONS IN
DIAMETER. INGESTION: DO NOT ALLOW FOOD, DRINK, OR TOBACCO IN AREA WHERE IT
MAY BE CONTAMINATED. CHRONIC: PRODUCT IS REINFORCED WITH CONTINUOUS FILAMENT
FIBROUS GLASS. DUST GENERATED FROM THE CUTTING, GRINDING, MACHINING, ETC,
WOULD NOT BE EXPECTED TO PRODUCE RESPIRABLE PARTICLES. IARC CONSIDERS
CONTINUOUS FILAMENTS AS UNCLASS IFIED OR PROBABLY NON-CARCINOGENIC.
Explanation Of Carcinogenicity: NTP HAS DETERMINED THAT RESPIRABLE SIZE
GLASSWOOL MAY BE REASONABLY ANTICIPATED TO BE A CARCINOGEN. IARC HAS ALSO
CLASSIFIED GLASSWOOL AS A POSSIBLE CARCINOGEN.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
First Aid: SKIN: WASH DUST OFF IN FLOWING WATER OR SHOWER. CHANGE CONTAMINATED
CLOTHING. EYES: IRRIGATE WITH FLOWING WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSISTS, CONSULT A PHYSICIAN. INHALATION: IF OVE RCOME BY DUST OR
SMOKE, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH-TO-MOUTH
RESUSCITATION. CALL A PHYSICIAN. INGESTION: IF LARGE AMOUNTS ARE INGESTED,
CONSULT A PHYSICIAN. ADVICE TO PHYSICIAN: TREAT SYMPTOMATICALLY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: (ALWAYS WEAR RECOMMENDED PERSONAL PROTECTIVE
EQUIPMENT). NOT APPLICABLE, MATERIAL IS AN ARTICLE. SPILLS AND RELEASES MAY
HAVE TO BE REPORTED TO FEDERAL AND/OR LOCAL AUTHORITIES. SPILLS/RELEASES
RESULT ING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS RQ REQUIRES
IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER (1-800-424-8802) AND
TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
Waste Disposal Methods: UNUSED PROD IS NOT A RCRA HAZ WASTE IF DISCHARGED. DISP
MUST BE MADE I/A/W ALL APPLIC LOC, STATE & FED REGS. INFO OFFERED HERE IS
FOR THE PROD AS SHIPPED. USE &/OR ALTERATIONS TO PROD SUCH AS MIXING W
/OTHER MATLS MAY SIGNIFICANTLY CHANGE CHARACTS OF MATL & ALTER RCRA
CLASSIFICATION & PROPER DISP MET H.
Handling And Storage Precautions: ALWAYS WEAR RECOMMENDED PERSONAL PROTECTIVE
EQUIPMENT. THE PRIMARY EXPOSURE ROUTE IS INHALATION OF DUST WHEN
MACHINED/PUNCHED OR FROM FUMES OR VAPORS WHEN HEATED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER, CARBON DIOXIDE, AND DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: MAY GIVE OFF TOXIC HYDROGEN BROMIDE GAS WHEN
THERMALLY DECOMPOSED. FLAME PROPAGATION RATE (SOLIDS): UL-VO. OSHA
FLAMMABILITY CLASS: N/A.
=======================================================
Control Measures
=======================================================
Respiratory Protection: ATMOSPHETIC LEVELS OF FIBROUS GLASS SHOULD BE
MAINTAINED BELOW EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED
FOR CERTAIN OPERATIONS, USE A NIOSH APPROVED DUST RESPIRATOR.
Ventilation: USE LOCAL EXHAUST VENTILATION TO CONTROL DUST.
Protective Gloves: WEAR IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
FOR BRIEF CONT TO DUST, NO PREC OTHER THAN CLEAN BODY-COVERING CLTHG SHOULD
BE NEEDED. USE APRONS WHEN PRLNG/FREQUENTLY RPTD CONT OCCURS.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.75 +/- 0.25 (H*2O=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: SOLID, YELLOW TO AMBER THIN SHEET MATERIAL WITH NO ODOR,
UNLESS HEATED.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: NOT DETERMINED.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, HBR, OXIDES
OF NITROGEN IF HEATED IN EXCESS OF 300C.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: IMMEDIATE (ACUTE) EFFECTS: DUST MAY CAUSE MODERATE
EYE, SKIN AND RESPIRATORY IRRITATION. DELAYED (SUBCHRONIC AND CHRONIC)
EFFECTS: SEE HEALTH HAZARDS AND EXPLANATION OF CARCINOGENICITY. OTHER DATA:
TH E TOXICITY OF THE COMBUSTION PRODUCTS WAS EVALUATED IN A SIMILAR PRODUCT
WITH 95% CONFIDENCE LIMITS, THE LC50 WAS CALCULATED (PROBIT ANALYSIS) TO BE
42.0 (35.0-50.0) MG/L. THE LC50 OF THE STANDARD REF ERENCE MATERIAL, DOUGLAS
FIR, IS 27.1 MG/L.
=======================================================
Ecological Information
=======================================================
Ecological: NOT BIODEGRADABLE.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: US DOT HAZARD CLASS: NOT REGULATED. US DOT ID NUMBER:
N/A. FOR ADDITIONAL INFORMATION ON SHIPPING REGULATIONS AFFECTING THIS
MATERIAL, CONTACT THE INFORMATION NUMBER FOUND ON THE FIRST PAGE.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: SARA TITLE III/
CERCLA: REPORTABLE QUANTITIES (RQ'S) AND THRESHOLD PLANNING QUANTITIES (TPQ'S)
EXIST FOR THE FOLLOWING INGREDIENTS: N/A. SECTION 311 HAZARD CLASS: N/A. SARA
313 TOXIC CHEMICALS: THE FOL LOWING INGREDIENTS ARE SARA 313 "TOXIC
CHEMICALS". CAS #'S AND WT % ARE FOUND IN INGREDIENTS SECTION: NONE.
Federal Regulatory Information: TSCA INVENTORY STATUS: THE RESIN SYSTEM
COMPONENTS USED TO MAKE THIS MATERIAL ARE ON THE TSCA INVENTORY LIST. OTHER
TSCA ISSUES: N/A. ADDITIONAL REGULATORY INFORMATION: ALLIED SIGNAL LAMINATE
SYSTEMS DOES NOT USE POLYBROMIDE-BIPHENYLS OR POLYBROMIDE-BIPHENYLOXIDES AS
A FIRE RETARDANT IN ANY OF THEIR EPOXY OR PHENOLIC RESIN SYSTEMS. WHERE
PROPRIETARY INGREDIENT SHOWS, THE IDENTITY MAY BE MADE AVAIL ABLE AS PROVIDED
IN THE OSHA STANDARD (1910.1200). W CLASSIFICATION (CANADA): N/A. FOREIGN
INVEN TORY STATUS: N/A.
State Regulatory Information: STATE RIGHT-TO-KNOW: IN ADDITION TO THE
INGREDIENTS FOUND IN INGREDIENTS SECTION, THE FOLLOWING ARE LISTED FOR STATE
RIGHT-TO-KNOW PURPOSES: N/A.
=======================================================
Other Information
=======================================================
Other Information: PROD USE: MILITARY: TYPE GFN: NEMA: FR-4 (SUBSTRATE FOR
PRINTED CIRCUITRY). RATING: HEALTH/FLAMMABILITY: 1; REACTIVITY: 0; PERSONAL
PROTECTION: X. THERE IS AN INGREDIENT CONTAINED IN FORMULATION OF THIS
MATERIAL CONSIDERED A TRADE SECRET AS DEFINED IN APPENDIX C TO SECTION
1910.1200 FOR OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION MANUAL 29 CFR
CH. XVI (7-1-89 EDITION). INQUIRIES TO SPECIFIC N ATURE OF THESE INGREDIENTS
& POTENTIAL HEALTH & SAFETY ISSUES ASSOCIATED W/THEM SHOULD BE
DIRECTED TO THE MANAGER, OCCUPATIONAL HEALTH, ALLIEDSIGNAL LAMINATE SYSTEMS,
230 NORTH FRONT ST, LA CROSSE, WI 54602-1448, (608) 784-6070.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: FR406 N
Company: ALLIEDSIGNAL LAMINATE SYSTEMS INC
Street: 230 N FRONT ST
PO Box: 1448
City: LA CROSSE WI
Zipcode: 54602-1448
Health Emergency Phone: 608-784-6070
Label Required IND: Y
Date Of Label Review: 04/19/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: DUST MAY CAUSE MODERATE IRRITATION. EYES:
DUST MAY CAUSE MODERATE IRRITATION. FUMES MAY IRRITATE EYES. INHALATION:
FIBROUS GLASS DUST MAY BE RELEASED FROM THE FIBER-GLASS CLOTH SUBSTANCE WHEN
MACHINED. INGESTION: DO NOT ALLOW FOOD, DRINK, OR TOBACCO IN AREA WHERE IT
MAY BE CONTAMINATED. CHRONIC: PRODUCT IS REINFORCED WITH CONTINUOUS FILAMENT
FIBROUS GLASS. DUST GENERATED FROM THE CUT TING, GRINDING, MACHINING, ETC,
WOULD NOT BE EXPECTED TO PRODUCE RESPIRABLE PARTICLES. IARC CONSIDERS
CONTINUOUS FILAMENTS AS UNCLASSIFIED OR PROBABLY NON-CARCINOGENIC. POSSIBLE
CARCINOGEN.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|