3M GENERAL OFFICES -- POLYURETHANE MARINE ADHESIVE SEALANT (SUPP DA
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Material Safety Data Sheet
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MSDS Num: BSWFG
MSDS NAME: POLYURETHANE MARINE ADHESIVE SEALANT (SUPP DATA)
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST. PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: EYES: MOD IRRIT INCLG REDNESS, SWELLING, PAIN, TEARING
& HAZY VISION. SKIN: ALLERGIC SKIN RXN INCLG REDNESS, SWELLING,
BLISTERING & ITCHING. MILD SKIN IRRIT INCLG REDNESS, SWELLING &
ITCHING. INHAL: A LLERGIC RESP RXN INCLG DFCLTY BRTHG, WHEEZING, TIGHTNESS OF
CHEST, & RESP FAILURE. UPPER RESP IRRIT (EFFECTS OF OVEREXP)
Explanation Of Carcinogenicity: TOLUENE DIISOCYANATE: ANTICIPATED TO BE A
CARCINOGEN, NTP 6TH ANNUAL RPT ON CARCIN0GEN, 1991; GROUP B, IARC
Signs And Symptions Of Overexposure: LTH HAZ: INCLG SORENESS OF NOSE &
THROAT, COUGHING & SNEEZING. VAPS OF UNCURED PROD MAY CAUSE IRRIT OF RESP
SYSTEM. INGEST: IRRIT OF GI TISSUES INCLG PAIN, VOMIT, ABDOM TENDERNESS,
NAUS, BLOOD IN VOMI TUS, & BLOOD IN FECES.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMED FLUSH EYES WITH LGE AMTS OF WATER FOR AT LEAST 15 MINS.
GET IMMED MED ATTN. SKIN: IMMED WASH SKIN W/SOAP & LGE AMTS OF WATER.
REMOVE CONTAMD CLTHG. IF SYMPS OCCUR, CALL MD. INHAL: REMOVE T O FRESH AIR.
IF BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GET IMMED MED ATTN. INGEST: DO
NOT INDUCE VOMITING. DRINK 2 GLASSES OF WATER. CALL MD.
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Handling and Disposal
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Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HLTH HAZ, RESP PROT, VENT & PERS PROT EQUIP. CALL (612)
733-1110/733-6100 FOR 24-HOUR SPILL ASSIST. CNTN SPILL. EVAC HAZ AREA OF
UNPROTECT ED PERS. POUR ISOCYANATE DECOMTAM SOLN (SUPP DATA)
Neutralizing Agent: NEUTRALIZE SPILL WITH DECONTAMINANT SOLUTION.
Waste Disposal Methods: CURE PROD ACCORDING TO PROD INSTRUCTIONS. INCIN IN
INDUSTRIAL/COMMERCIAL FACILITY IN PRESENCE OF COMBUST MATL. DISP OF
COMPLETELY CURED/POLYMERIZED MATL IN SANITARY LANDFILL. DISP OF WASTE PROD IN
FAC ILITY PERMITTED TO ACCEPT CHEM WASTE.
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions: DO NOT INGEST. AVOID EYE/SKIN CONTACT.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: >150F,>66C
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP(FP N).
Unusual Fire/Explosion Hazard: NONE KNOWN.
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Control Measures
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Respiratory Protection: AVOID INHAL OF VAPS. AVOID INHAL OF DUST CREATED BY
CUTTING, SANDING/GRINDING. SELECT ONE OF FOLLOWING NIOSH/MSHA APPRVD RESPS
BASED ON AIRBORNE CONC OF CONTAMS & IN ACCORD WITH OSHA REGS: APPRVD HALF
-MASK SUPPLIED AIR RESP. WHEN
Ventilation: USE IN WELL VENT AREA. PROVIDE SUFF VENT TO MNTN EMISSIONS BELOW
RECOM EXPOS LMTS. IF EXHST VENT IS NOT ADEQ,
Protective Gloves: POLYETHYLENE/ETHYLENE VINYL
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: APRON, COVERALLS.
Work Hygienic Practices: WASH CONTAM CLOTHING BEFORE REUSE & DISPOSE OF
CONTAMINATED SHOES.
Supplemental Safety and Health: TRADENAME/PART #:5200 WHITE 5203/5204/6500.
SPEC GRAV:1.17-1.22(H*20=1). SPILL PROC:(90% WATER,8% CONC AMMONIA, 2%
DETERGENT) ON SPILL & ALLOW TO REACT FOR 10 MINS. ALTERNATIVELY, POUR
WATER ON SPILL & ALLOW TO REACT FOR MORE THAN 30 MINS.COVER W/ABSORB.
PLACE IN APPRVD DRUM, DO NOT SEAL FOR 48 HRS TO AVOID
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Physical/Chemical Properties
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Spec Gravity: SUPP DATA
Solubility in Water: NIL
Appearance and Odor: THIXOTROPIC PASTE, WHITE, VERY SLIGHT ODOR.
Percent Volatiles by Volume: <1
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AMINES, ALCOHOLS, WATER. RXN W/WATER, ALCOHOLS & AMINES IS
NOT HAZ IF CNTNR CAN VENT TO ATMOS TO PVNT PRESS BUILDUP.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF
NITROGEN, HYDROGEN CYANIDE, ISOCYANATES, TOXIC VAPORS, GASES OR PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: POLYURETHANE MARINE ADHESIVE SEALANT (SUPP DATA)
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 07/26/1993
Status Code: C
Label Date: 07/26/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. ACUTE: EYE:MODERATE IRRIT INCLUDING
REDNESS, SWELLING, PAIN, TEARING & HAZY VISION. SKIN: MILD SKIN IRRITANT
INCLUDING REDNESS, SWELLING & ITCHING. INHAL: UPPER RESP IRRIT INCL
SORENESS OF NOSE & THROAT. INGEST: IRRIT OF GI TISSUES INCL PAIN, VOMIT,
ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS & BLOOD IN FECES. CHRONIC:
TOLUENE DIISOCYANATE IS LISTED AS A CARCINOGEN OF SUBCUTANEOUS TISSUE,
LIVER, GROIN, & OVARIES IN LAB ANIMALS (FP N). SKIN: ALLERGIC SKIN
REACTION INCLUDING REDNESS, SWELLING, BLISTERING & ITCHING. INHAL:
ALLERGIC RESPIRATORY REACTION INCLUDING DIFFICULTY BREATH ING, WHEEZING,
TIGHTNESS OF CHEST, & RESP FAILURE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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