===================== Product Identification =====================
MSDS NAME:SERCON R-12 30 CYL EA UN1028
NIIN:00N067026
MSDS Number: CBFGP
=== Responsible Party ===
Company:TECHNICAL CHEMICAL CO
Address:10737 SPANGLER RD
City:DALLAS
State:TX
ZIP:75220
Country:US
Info Phone Num:214-556-1421
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:8X792
=== Contractor Identification ===
Company:TECHNICAL CHEMICAL COMPANY
Address:10737 SPANGLER ROAD
Box:20098
City:DALLAS
State:TX
ZIP:75220-7101
Country:US
Phone:972-556-1421
CAGE:8X792
============= Composition/Information on Ingredients =============
Name:METHANE, DICHLORODIFLUORO-; (DICHLORODIFLUOROMETHANE) (SARA
313) (CERCLA)
CAS:75-71-8
RTECS #:PA8200000
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
Name:SUPDAT:IN RESPONSE, IT IS DFCLT TO PREDICT WHICH SYMPS WILL
BE EXHIBITED FOLLOWING EXPOSURE. CHLOROFLUOROCARBON (ING 3)
RTECS #:9999999ZZ
Name:ING 2:(CFC) MATLS HAVE PRDCE SENSITIZ OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN (ING 4)
RTECS #:9999999ZZ
Name:ING 3:HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS(ING 5)
RTECS #:9999999ZZ
Name:ING 4:ACUTELY/CHRONICALLY EXPOSED TO CHLOROFLUORCARBON .
RTECS #:9999999ZZ
Name:FIRST AID PROC:AND AT REST. IF BRTHG IS DFCLT GIVE OXYG. IF
NOT BRTHG, GIVE ARTF RESP & CHECK FOR PULSE. IF NO (ING 7)
RTECS #:9999999ZZ
Name:ING 6:PULSE, START CPR. DO NOT GIVE STIMULANTS (ADRENALINE,
EPINEPHRINE OR HAND HELD AEROSOLS). KEEP PATIENT (ING 8)
RTECS #:9999999ZZ
Name:ING 7:AT REST FOR 24 HRS AFTER OVEREXPOSURE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HUMANS EXPOS TO 40,000 PPM (FOR
14 MINS) EXPERIENCED GENERALIZED TINGLING SENSATION, HUMMING IN
EARS, APPREHENSION & SLURRED SPEECH. AT 100,000 (FOR 11 MINS),
SUBJECT REPORTEDLY SHOWED DECREASE IN CONSCIOUSNESS W/AMNESIA
OCCURING IN ABOUT 10 MINS, WHICH WAS PROCEEDED W/IRREGULAR
HEARTBEAT. HUMANS(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EXPOS TO 20,000 PPM FOR SHORT TIME
EXPERIENCED SIGNIFICANT EYE IRRIT AS WELL AS CNS EFTS, ALL OF WHICH
DISAPPEARED W/IN MINS AFTER RETURN TO FRESH AIR. NOTE:HUMAN
POISONING POTNTL:SNIFFING FL UOROCARBON PROPELLANTS FOR THEIR
INTOXICATING EFTS IS EXTREMELY DANGEROUS & DEATH MAY OCCUR W/OUT
WARNING. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:VAP CONT:FLUSH W/FRESH WATER FOR @ LEAST 15 MINS. LIQ
CONT:FLUSH EXPOS AREA W/LUKEWARM WATER/OTHERWISE WARM SKIN SLOWLY.
FROSTBITE IS PROBABLE. CALL PHYS. INGEST:KEEP PATIENT CALM, IF
CONSCIOUS, & GET TO PHYS IMMED-FROSTBITE IS PROBABLE, INDICATED BY
NECROSIS BY LIP & TONGUE (CONTACTED TISS), BLANCHING OF SKIN, PAIN
& TENDERNESS. WARM SKIN SLOWLY. INHAL:REMOVE TO FRESH AIR. KEEP
WARM (ING 6)
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING AREA .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . USE NIOSH/MSHA APPRVD SCBA. PROT CLTHG SHOULD
MINIMIZE EXPOS SKIN & INCL GOGG, FULL (SUPDAT)
Unusual Fire/Explosion Hazard:NONFLAMMABLE AND NONEXPLOSIVE. THERMAL
DECOMPOSITION PRODUCTS MAY INCLUDE FLUORIDES, CHLORIDES, AND
PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP UPWIND. VENTILATE ENCLOSED SPACES UNTIL
GAS IS DISPERSED. BECAUSE OF ITS SUSPECTED INFLUENCE ON
STRATOSPHERIC OZONE REDUCTION PROD IS REGULATED FROM NON-ESSNL USE
AS PROPELLANT IN USA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:NOT RELEVANT.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR
PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORK GOGGLES .
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:DO NOT SMOKE OR OPERATE INTERNAL COMBUST
ENGINES IN IMMED VINCINITY.
Supplemental Safety and Health
FIRE FIGHT CNDTNS:FACED SHIELD IF POSS & LINED RUBB GLOVES. CNDTNS TO
AVOID:HF, HCL AND TRACES OF CARBONYL HALIDES (IE, PHOSGENE). HAZ
DECOMP PROD:TO FORM HF, HCL & TRACES OF CARBONYL HALIDES. EFTS OF
OVEREXP:FLUOROCARB EXHIBIT VERY TOX PROPERTIES (ASPHYX, CARD ARRHY)
WHEN SNIFFED; HOWEVER BECAUSE OF VARIATIONS (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<22F,<-6C
Vapor Pres:79.8 PSIG
Vapor Density:2.32 @ 77F
Spec Gravity:1.31 (H*2O=1)
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID AND VAPOR, VERY SLIGHT ETHERAL TO
ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CERTAIN ELASTOMERS, ALKALI/ALKALINE EARTH METALS, POWDERED ALUMINUM
ZINC, BERYLLIUM, ETC.
Stability Condition to Avoid:AVOID CNDTNS WHERE PROD MAY CONTACT OPEN
FLAMES OR EXTREMELY HOT METAL SURFACES AS PROD MAY DECOMPOSE TO
FORM (SUPDAT)
Hazardous Decomposition Products:CHLORIDES, FLUORIDES AND PHOSGENE . IF
PROD CONTACTS OPEN FLAMES/EXTREMELY HOT METAL SURF IT MAY
DECOMPOSE(SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF WASTE MATERIAL OR RESIDUE MAY BE
SUBJECT TO FEDERAL, STATE OR LOCAL REGULATION. BEFORE TRANSPORTING
WASTE MATERIAL SEE US PUBLICATION 49 CFR SECTION 172.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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