===================== Product Identification =====================
MSDS NAME:PHENOL ACC18380
NIIN:00N036979
MSDS Number: CDZKD
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ING 21:BY GASTRIC LAVAGE/EMESIS. ACTIVATED CHARCOAL IS
USEFUL. FOLLOW W/240 ML OF MILK, GASTRIC LAVAGE & EMESIS (ING 23)
RTECS #:9999999ZZ
Name:ING 22:ARE NOT TO BE USED IN PRESENCE OF ESOPHAGEAL INJURY.
GASTRIC LAVAGE SHOULD BE PERFORMED BY QUALIFIED (ING 24)
RTECS #:9999999ZZ
Name:ING 23:MED PERS. GET MED ATTN IMMED. NO SPECIFIC ANTIDOTE.
TREAT SYMPTOMATICALLY & SUPPORTIVELY.
RTECS #:9999999ZZ
Name:SPILL PROC:FROM SPILL AREA. LARGER SPILLS-DIKE FAR AHEAD OF
SPILL FOR LATER DISP. ISOLATE HAZ AREA & DENY ENTRY.
RTECS #:9999999ZZ
Name:ING 7:WHITE/BROWNISH STAINS & AREAS OF NECROSIS ON LIPS &
IN MOUTH & ESOPHAGUS, MARKED ABDOM PAIN, PALE FACE, (ING 9)
RTECS #:9999999ZZ
Name:ING 8:& CONTRACTED/DILATED PUPILS. SYSTEMIC EFTS MAY OCCUR
AS DETAILED IN ACUTE INHAL EXPOS. APPROXIMATE LETHAL (ING 10)
RTECS #:9999999ZZ
Name:ING 9:DOSE IN MAN IS 140 MG/KG. CHRONIC:INHAL:SYMPS OF
CHRONIC POIS MAY INCL VOMIT, DFCLTY SWALLOWING, PTYALISM,(ING 11)
RTECS #:9999999ZZ
Name:ING 10:DIARR, ANOREXIA, HDCH, MUSCLE WEAK & PAIN, MENTAL
DISTURB, & POSSIBLY SKIN ERUPTIONS. EXTENSIVE DMG TO (ING 12)
RTECS #:9999999ZZ
Name:ING 11:LIVER & KIDNEYS MAY BE FATAL. SKIN:MAY CAUSE
BLUE/BROWNISH DISCOLORATION OF TENDONS OVER KNUCKLES, DERM,(ING 13)
RTECS #:9999999ZZ
Name:ING 12:& RARELY SKIN SENSITIZATION. SYMPTOMS OF CHRONIC
POISONING MAY OCCUR. EYE:REPEATED EXPOSURE TO (ING 14)
RTECS #:9999999ZZ
Name:ING 13:VAPORS MAY CAUSE CONJUNCTIVITIS & HAS CAUSED GRAY
DISCOLORATION OF SCLERA W/BROWN SPOTS NEAR INSERTION OF(ING 15)
RTECS #:9999999ZZ
Name:ING 14:RECTUS MUSCLE TENDON. INGEST:PERSONS INGESTING
PHENOL CONTAMD WELL WATER EXPERIENCED DIARR, DARK URINE, (ING 16)
RTECS #:9999999ZZ
Name:ING 15:& SORES AND BURNING IN MOUTH. OTHER SYMPTOMS OF
CHRONIC PHENOL POISONING MAY OCCUR. REPRODUCTIVE (ING 17)
RTECS #:9999999ZZ
Name:ING 16:EFFECTS HAVE BEEN REPORTED IN ANIMALS.
RTECS #:9999999ZZ
Name:FIRST AID PROC:COVER AREA W/STERILE, DRY DRESSING, BANDAGE
SECURELY, BUT NOT TOO TIGHTLY, GET MED ATTN IMMED. (ING 19)
RTECS #:9999999ZZ
Name:ING 18:EYE:WASH IMMED W/LG AMTS OF WATER, OCCASNLY LIFTING
UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (ING 20)
RTECS #:9999999ZZ
Name:ING 19:(AT LST 15 MINS). CONTINUE IRRIGATING W/NORM SALINE
UNTIL PH HAS RETURNED TO NORM (30-60 MIN). COVER W/ (ING 21)
RTECS #:9999999ZZ
Name:ING 20:STERILE BANDAGES. GET MED ATTN IMMED. INGEST:IF
VICTIM CONSCIOUS, & CORR INJURY IS ABSENT, REMOVE POISON(ING 22)
RTECS #:9999999ZZ
Name:PHENOL (SARA 302/313) (CERCLA)
CAS:108-95-2
RTECS #:SJ3327000
Fraction by Wt: 100%
OSHA PEL:S, 5 PPM
ACGIH TLV:S, 5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:EFTS OF OVEREXP:IN ACUTE INHAL EXPOS. PROFOUND COMA & DEATH
HAVE BEEN RPTD TO OCCUR W/IN 10 MIN FOLLOWING SKIN (ING 3)
RTECS #:9999999ZZ
Name:ING 2:CONT. EYE:VAPS HAVE CAUSED MARKED IRRIT FROM BRIEF,
INTERMITTENT INDUST EXPOS TO 48 PPM. CONCENTRATED LIQ (ING 4)
RTECS #:9999999ZZ
Name:ING 3:OR SOLID MAY CAUSE SEV IRRIT W/REDNESS, PAIN, &
BLURRED VISION. CONCENTRATED PHENOL HAS CAUSED CHEMOTIC (ING 5)
RTECS #:9999999ZZ
Name:ING 4:CONJUNCTIVA, HYPESTHETIC, WHITE CORNEA, EDEMATOUS
EYELIDS, & SEV IRITIS. IN SOME CASES, EYELIDS HAVE BEEN (ING 6)
RTECS #:9999999ZZ
Name:ING 5:BEEN SO SEV DAMAGED THAT THEY REQD PLASTIC SURGERY.
FINAL VISUAL RSLTS HAVE VARIED FROM COMPLETE RECOVERY, (ING 7)
RTECS #:9999999ZZ
Name:ING 6:TO PARTIAL RECOVERY, TO BLNDNESS & LOSS OF EYE.
INGEST:MAY CAUSE IMMED INTENSE BURNING OF MOUTH & THROAT, (ING 8)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 317 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:250 PPM IDLH. MAY CAUSE
SEV IRRIT OF MUC MEMB, PROFUSE SWEAT, HDCH, INTENSE THRIST, NAUS &
VOMIT, ABDOM PAIN, DIARR, SALIVATION, CYANOSIS, TREMORS, &
CONVULSIONS. CNS MAY INITIALLY BE STIM ULATED FOLLOWED BY DEPRESS
PROGRESSING TO COMA. DEATH MAY OCCUR FROM RESPIRATORY, CIRCULATORY
OR CARD (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:FAILURE. IF DEATH IS NOT IMMED,
JAUNDICE & OLIGURIA/ANURIA MAY OCCUR. SKIN:0.5% SOLNS MAY CAUSE
LOCAL ANESTH, 1% SOLNS SOMETIMES CAUSE NECROSIS, & 10% SOLNS MAY
CAUSE BURNS. BURNS MAY BE SEV, BUT PAINLESS DUE TO DMG TO NERVE
ENDINGS. VAPS & LIQ MAY BE READILY ABSORBED TO CAUSE SYSTEMIC EFTS
AS DETAILED (ING 2)
Medical Cond Aggravated by Exposure:PERSONS WITH CONVULSIVE DISORDERS
AND ABNORMALITIES OF THE SKIN, RESPIRATORY TRACT, LIVER AND
KIDNEYS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF
RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN OXYG IF AVAIL. KEEP
WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ADMIN OF OXYG
SHOULD BE PERFORMED BY QUALIFIED PERS. GET MEDATTN IMMED.
SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AREA W/SOAP & WATER
UNTIL NO EVID OF CHEM REMAINS (@ LST 15-20 MIN). IN CASE OF CHEM
BURNS, (ING 18)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:174F,79C
Lower Limits:1.7%
Upper Limits:8.6%
Extinguishing Media:DRY CHEMICAL, WATER SPRAY OR REGULAR FOAM. LARGER
FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM AREA IF CAN W/OUT RISK. FIGHT FIRE FROM MAX DIST. STAY
AWAY FROM ENDS OF TANKS. DIKE FIRE- (SUPDAT)
Unusual Fire/Explosion Hazard:MOD FIRE HAZ WHEN EXPOS TO HEAT/FLAME.
VAP-AIR MIX ARE EXPLO ABOVE FL PT. VAPS ARE HVR/AIR & MAY TRAVEL
CONSIDERABLE DIST TO SOURCE OF IGNIT & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK IF CAN DO
W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SM SPILLS-TAKE UP
W/ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. SM DRY
SPILLS-W/CLEAN SHOVEL PLACE MATL I NTO CLEAN, DRY CNTNRS & COVER.
MOVE CNTNRS(ING 25)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MAY BURN BUT DOES NOT IGNITE READILY.
CNTNRS MAY EXPLODE IN HEAT OF FIRE. PROTECT AGAINST PHYSICAL DMG.
OUTSIDE/DETACHED STORAGE IS PREFERRED.
Other Precautions:STORE IN COOL, DRY, WELL-VENTILATED LOCATION, AWAY
FROM ANY AREAS WHERE FIRE HAZ MAY BE ACUTE. SEPARATE FROM OTHER
STOR. STORE AWAY FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPS MUST BE NIOSH APPRVD. 50 PPM-ANY CHEM
CARTRIDGE RESP W/ORG VAP CARTRIDGE(S) IN COMBINATION W/DUST & MIST
FILTER. ANY SCBA. 125 PPM-ANY SUPPLIED-AIR RESP OPERATED IN
CONTINUOUS FLOW MODE. 250 PPM -ANY SCBA W/FULL FACEPIECE.
Ventilation:PROCESS ENCLOSURE VENT TO MEET PUBLISHED EXPOS LIMITS.
VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
APPROP PROT CLTHG & EQUIP TO PVNT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:6 (AQ SOLN). APPEAR/ODOR:SWEET, TARRY ODOR AND A SHARP BURNING
TASTE. FIRE FIGHT PROC:CONTROL WATER FOR LATER DISP; DO NOT SCATTER
MATL. USE FLOODING QTYS OF WATER AS FOG. COOL FIRE-EXPOS CNTNRS W/
WATER FROM AS FAR A DIST AS POSS. KEEP UPWIND. MATLS TO AVOID:TO
AVOID CONT NEHC .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:359F,182C
Melt/Freeze Pt:M.P/F.P Text:106F,41C
Vapor Pres:0.36 @ 20C
Vapor Density:3.2
Spec Gravity:1.07
pH:SUPDAT
Evaporation Rate & Reference:0.01 (BUTYL ACETATE =1)
Solubility in Water:8.4%
Appearance and Odor:COLORLESS TO PINKISH, HYGROSCOPIC CRYSTALLINE SOLID
WITH A SHARP, (SUPDAT)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACETALDEHYDE, FORMALDEHYDE, METALS & ALLOYS, OXIDIZERS (STRONG),
PEROXODISULFURIC ACID. FOR MORE DETAILED MATLS (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FED, STATE & LOC REGS WHEN DISPOSING
OF THIS SUBSTANCE. FOR ASSISTANCE, CONT DISTRICT DIRECTOR OF
ENVIRONMENTAL PROTECTION AGENCY. DISPOSAL MUST BE I/A/W FEDERAL,
STATE & LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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