=====================  Product Identification  =====================

MSDS NAME:MANGANESE SULFATE SOLUTION, SO-M-20
NIIN:00N022024
MSDS Number: CDZJX
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Name:FIRST AID PROC:CHEM BURNS, COVER AREA W/STERILE, DRY
    DRESSING. BANDAGE SECURELY, BUT NOT TOO TIGHTLY. GET MED (ING 18)
RTECS #:9999999ZZ

Name:ING 17:ATTN IMMED. EYE:WASH IMMED W/LRG AMTS OF H*2O, OCCAS
    LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM (ING 19)
RTECS #:9999999ZZ

Name:ING 18:REMAINS (AT LEAST 15-20 MIN). CONTINUE IRRIGATING
    W/NORM SALINE UNTIL PH HAS RETURNED TO NORM (30-60 (ING 20)
RTECS #:9999999ZZ

Name:ING 19:MIN). COVER W/STERILE BANDAGES. GET MED ATTN IMMED.
    INGEST:DO NOT USE GASTRIC LAVAGE/EMESIS. DILUTE ACID (ING 21)
RTECS #:9999999ZZ

Name:ING 20:IMMED BY DRINKING LRG QTIES OF H*2O OR MILK. IF
    VOMIT PERSIST, ADMINISTER FLUIDS REPEATEDLY. INGESTED (ING 22)
RTECS #:9999999ZZ

Name:ING 21:ACID MUST BE DILUTED APPROX 100 FOLD TO RENDER IT
    HARMLESS TO TISSUE. MAINTAIN AIRWAY & TREAT SHOCK. (ING 23)
RTECS #:9999999ZZ

Name:ING 22:GET MEDICAL ATTENTION IMMEDIATELY. IF VOMITING
    OCCURS, KEEP HEAD BELOW HIPS TO HELP PREVENT ASPIRATIONS.
RTECS #:9999999ZZ

Name:SPILL PROC:LARGER SPILLS-DIKE FAR AHEAD OF SPILL FOR LATER
    DISPOSAL. ISOLATE HAZARD AREA AND DENY ENTRY.
RTECS #:9999999ZZ

Name:RESP PROC:IN CONTINUOUS-FLOW MODE. ANY SCBA WITH A FULL
    FACEPIECE OPERATED IN PRESSURE-DEMAND/OTHER POSITIVE PRESS MODE.
RTECS #:9999999ZZ

Name:ING 15:DISTURBS SIMULATE PARKINSON'S DISEASE. FOR MORE
    DETAILED HLTH HAZ INFO CONTACT NEHC .
RTECS #:9999999ZZ

Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 66.0%

Name:EFTS OF OVEREXP:W/POSS DMG TO LUNG TISS. SKIN:MAY CAUSE SEV
    SECOND & THIRD DEGREE SKIN BURNS W/NECROSIS DUE TO (ING 5)
RTECS #:9999999ZZ

Name:ING 4:ITS AFFINITY FOR H*2O & SUBSEQUENT SEV DEHYDRATING
    ACTION. POSS CHARRING MAY OCCUR LEADING TO SHOCK & (ING 6)
RTECS #:9999999ZZ

Name:ING 5:COLLAPSE DEPENDING ON AMT OF TISS INVOLVED. DILUTE
    SOLS MAY CAUSE IRRIT. EYE:VAP MAY CAUSE A BURNING OR (ING 7)
RTECS #:9999999ZZ

Name:ING 6:STINGING SENSATION W/LACRIMATION, BLURRED VISION &
    CONJ CONGESTION. SPLASHES MAY PRODUCE DEEP CORNEAL (ING 8)
RTECS #:9999999ZZ

Name:ING 7:ULCERATION, KERATO-CONJUNCTIVITIS & PALPEBRAL LESIONS
    W/SEV SEQUELAE. IRREPARABLE CORNEAL DMG & BLINDNESS (ING 9)
RTECS #:9999999ZZ

Name:ING 8:AS WELL AS SCARRING OF EYELIDS MAY OCCUR. DILUTE ACID
    MAY PRODUCE MORE TRANSIENT EFTS FROM WHICH RECOVERY (ING 10)
RTECS #:9999999ZZ

Name:ING 9:MAY BE COMPLETE. INGEST:MAY CAUSE BURNING PAIN IN
    MOUTH, THROAT EXOPHAGUS & ABDOMEN, SOUR TASTE & NAUSEA (ING 11)
RTECS #:9999999ZZ

Name:ING 10:FOLLOWED BY VOMIT & DIARRHEA OF CHARRED BLACK
    STOMACH CONTENTS. THIRST, DIFFICULT SWALLOWING, ACIDEMIA, (ING 12)
RTECS #:9999999ZZ

Name:ING 11:STOMATITIS, RAPID & WEAK PULSE, SHALLOW BRTHG, SHOCK
    & POSS CONVL & DEATH MAY OCCUR. CHRONIC:MANGANESE: (ING 13)
RTECS #:9999999ZZ

Name:ING 12:RPTD EXPOS FROM 3 MONTHS TO 2 YRS MAY PRDCE CHRONIC
    MANGANESE POISONING W/SYMPS OF APATHY, ANOREXIA, (ING 14)
RTECS #:9999999ZZ

Name:ING 13:HDCH, SPASMS, WEAK OF LEGS, & IRRITABILITY. AS
    DISEASE PROGRESS INTO INTERMEDIATE PHASE, PHYCHOSIS (ING 15)
RTECS #:9999999ZZ

Name:ING 14:DEVELOPS W/VISUAL HALLUCINATIONS, DOUBLE VISION,
    MENTAL CONFUSN, & EUPHORIA. IN LAST STAGE NEUROLOGICAL (ING 16)
RTECS #:9999999ZZ

Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 1.0%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:MANGANESE SULFATE
CAS:7785-87-7
RTECS #:OP1050000
Fraction by Wt: 33.0%
OSHA PEL:CL, 5.0 MG/M3 (MN)
ACGIH TLV:5.0 MG/M3 (MN)

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL, RAT): 2140 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:MANGANESE SULFATE: INHAL:10,000 PPM
    IMMED DANGEROUS TO LIFE/HLTH. DUST MAY CAUSE IRRIT OF MUCS MEMB
    W/COUGHING & SHORTNESS OF BRTH. MAY BE ABSORBED INTO BLOOD STREAM &
    DEPOSITED INTO LIVER, SPLEEN, BR AIN & OTHER ORGANS WHERE IT
    ACCUMS. SKIN CNTCT:MAY CAUSE IRRITATION. EYE CONTACT:MAY CAUSE
    REDNESS & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:IRRIT. INGEST:MAY CAUSE GI DISTURB
    W/ABDOM PAIN & NAUS. SULFURIC ACID:INHAL:80 MG/M3 IMMED DANGEROUS
    TO LIFE/HLTH. MISTS MAY CAUSE MUC MEMB IRRIT. LOW CONCS, MAY CAUSE
    INCR PULM AIR FLOW RESI STANCE & SUBSEQUENT SHALLOW & MORE RAPID
    BRTHG. HOT CONCENTRATED MISTS MAY CAUSE RAPID LOSS OF CONSCIOUSNESS
    (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF
    RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMINISTER OXYGEN IF AVAIL.
    KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ADMIN OF
    OXYGE N SHOULD BE PERFORMED BY QUALIFIED PERS. GET MED ATTN IMMED.
    SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AREA W/SOAP & H*2O
    UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). IN CASE OF (ING
    17)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
    REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
    FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
    CNTNR FROM AREA IF CAN W/OUT RISK. APPLY COOLING WATER TO SIDES OF
    CNTNRS THAT EXPOSED TO FLAMES (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
    HEAT OR FLAME.

==================  Accidental Release Measures  ==================

Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK IF CAN
    W/OUT RISK. SMALL SPILLS-TAKE UP W/OTHER ABSORBENT MATL & PLACE
    INTO CNTNRS FOR LATER DISP. SMALL DRY SPILLS-W/CLEAN SHOVEL PLACE
    MATL INTO CLEAN, DRY CNTNR S & COVER. MOVE CNTNRS FROM SPILL
    AREA.(ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:RESPS MUST BE NIOSH APPRVD. ANY CHEM CARTRIDGE
    RESP W/ACID GAS CARTRIDGE(S) & W/FULL FACEPIECE. ANY TYPE 'C'
    SUPPLIED-AIR RESP W/FULL FACEPECE OPERATED IN PRESS-DEMAND/OTHER
    POS PRESS MODE/WITH FULL F ACEPIECE, HELMET/HOOD OPERATED (ING 25)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION
    VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
    APPROPRIATE PROTECTIVE CLOTHING & EQUIPMENT TO PREVENT SKIN
    CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF
    TANKS. DO NOT USE H*2O DIRECTLY ON MATL. USE WATER SPRAY/FOG IN
    FLOODING AMTS TO COOL CNTNRS FROM AS FAR A DISTANCE AS POSS. KEEP U
    PWIND. CNDTNS (STAB):COMBUST (WOOD, PAPER, OIL, ETC.).

==================  Physical/Chemical Properties  ==================

Vapor Pres:14 @ 20C
Vapor Density:0.7 (H*2O)
Spec Gravity:1.27
pH:0.60
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR PINK LIQUID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACETALDEHYDE, BASES, COMBUSTIBLE MATERIALS, METALS, ORGANICS. FOR
    DETAILED LIST OF MATLS TO AVOID CONT NEHC .
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY.
    FLAMMABLE, POISONOUS GASES MAY ACCUM IN TANKS & HOPPER CARS. MAY
    IGNITE (SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
    TOXIC OXIDES OF SULFUR.

====================  Disposal Considerations  ====================

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
    WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,
    CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION
    AGENCY.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***