===================== Product Identification =====================
MSDS NAME:MGI 24875, PROPANE, CARBON MONOXIDE, AND (SUPDAT)
NIIN:00N009378
MSDS Number: CDZJK
=== Responsible Party ===
Company:MG INDUSTRIES
Address:3 GREAT VALLEY PARKWAY
City:MALVERN
State:PA
ZIP:19355
Country:US
Info Phone Num:215-695-7400
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:08772
=== Contractor Identification ===
Company:MG INDUSTRIES
Address:3 GREAT VALLEY PKY
Box:City:MALVERN
State:PA
ZIP:19355-1424
Country:US
Phone:610-695-7400 / 610-695-7449
CAGE:08772
============= Composition/Information on Ingredients =============
Name:ING 9:INSOMNIA, & PERSONALITY CHANGES, LARGELY DEPRESS AND
IRRITABILITY. INCREASE IN BOTH RATE & DEPTH OF VENT. (ING 11)
RTECS #:9999999ZZ
Name:ING 10:HYPER/HYPOVENTILATION, RESP ACIDOSIS, DEATH FROM
ASPHY. HDCH SHOULD BE TAKEN AS WARNING. WEAK & DIZZ (ING 12)
RTECS #:9999999ZZ
Name:ING 11:MAY BE ONLY SYMPS PRECEDING COLLAPSE.
CARBOXYHEMOGLOBIN:SYMPTOMS MAY INCLUDE INCREASINGLY SEV HDCH, (ING
13)
RTECS #:9999999ZZ
Name:ING 12:DYSPNEA ON EXERTION, DECR MANUAL DEXTERITY, IMPAIRED
JUDGEMENT & MEMORY, IRRITABILITY. EMOTIONAL (ING 14)
RTECS #:9999999ZZ
Name:ING 13:INSTABILITY, DIZZ, FATG, DROW, CONFUSION, NAUS,
VOMIT, PALPITATION, IMPAIRED VISION AND HEARING, ANGINAL (ING 15)
RTECS #:9999999ZZ
Name:ING 14:PAIN, INCOORDINATION, HALLUCINATIONS, LETHARGY.
SYNCOPE AND COLLAPSE. INCREASED RESP & PULSE, DECREASED (ING 16)
RTECS #:9999999ZZ
Name:ING 15:RESPIRATORY, BLOOD PRESSURE, AND PULSE, DEEPENING
COMA, CONVULSIONS, INCONTINENCE OF URINE AND FECES. (ING 17)
RTECS #:9999999ZZ
Name:ING 16:SKIN DISCOLORATION, CYANOSIS AND PALLOR, INCREASED
TEMP, DILUTED PUPILS, PERSPIRATION, MUSCLE SPASMS, (ING 18)
RTECS #:9999999ZZ
Name:ING 17:HYPERREFLEXIA, ACHING, HEMMORHAGE, VENOUS
ENLARGEMENT, DEATH, RESP/CARDIAC ARREST. SKIN, EYE & INGEST: (ING
19)
RTECS #:9999999ZZ
Name:ING 18:FROSTBITE. CHRONIC:CARDIOVASCULAR AND CENTRAL
NERVOUS SYSTEM DAMAGE. FOR MORE SPECIFIC HEALTH HAZARD (ING 20)
RTECS #:9999999ZZ
Name:ING 19:INFORMATION CONTACT NEHC .
RTECS #:9999999ZZ
Name:NITROGEN
CAS:7727-37-9
RTECS #:QW9700000
Fraction by Wt: 80-95%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 4-12%
OSHA PEL:5000 PPM
ACGIH TLV:5000 PPM/30000 STEL
Name:CARBON MONOXIDE
CAS:630-08-0
RTECS #:FG3500000
Fraction by Wt: 4-12%
OSHA PEL:50 PPM
ACGIH TLV:25 PPM
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Name:SUPDAT:FOR 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL
CAR/TANK TRUCK IS INVOLVED IN FIRE. EXTING USING AGENT (ING 6)
RTECS #:9999999ZZ
Name:ING 5:INDICATED. COOL CYLS W/FLOODING AMTS OF WATER FROM AS
FAR DIST AS POSS. DO NOT USE WATER DIRECTLY ON MATL.(ING 7)
RTECS #:9999999ZZ
Name:ING 6:USE WATER SPRAY TO ABSORB VAPS. AVOID BRTHG VAPS.
KEEP UPWIND. CONSIDER EVAC OF DOWNWIND AREA IF MATL IS LEAKING.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:TRACHYCARDIA & ARRHY, HYPOCALCEMIA
CARPOPEDAL SPASMS. VISION CONSTRICTION OF FIELDS, ENLARGEMENT (ING
9)
RTECS #:9999999ZZ
Name:ING 8:OF BLIND SPOTS, PHOTOPHOBIA, LOSS OF CONVERGENCE &
ACCOMMODATION, & DEFICIENT DARK ADAPTATION, HDCH, (ING 10)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CARBON MONOXIDE APPEARS ON NAVY
LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP
HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG &
EXPOS INFO . ACUTE:NITROGEN:INH AL:DISSOLVES IN FAT-CONTAINING
BRAIN CELLS, & ACT AS ANESTH, CAUSING NARCOS. DECOMPRESSION
SICKNESS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CARBON DIOXIDE:VERY VOLAT. ACIDIC
TASTE, DYSPNEA, HDCH, VERTIGO, NAUS, LABORED BRTHG, WEAK, DROW,
MENTAL CONFUSN & INCR IN BLOOD PRESS, PULSE, & RESP RATE, VISUAL
DISTURB, TINNITUS, TREMORS, PROFUSE PERSPIRATION, RESTLESSNESS,
PARESTHESIAS, GENERAL FEELING OF DISCOMFORT, LOSS OF CONSCIOUSNESS
& COMA, (ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) .
EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR AT LEAST 15 MINS, SEEK
ASSISTANC E FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL
MD . FOR MORE SPECIFIC INFORMATION ON FIRST AID CONTACT NEHC .
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL/CARBON DIOXIDE. LARGER FIRES:USE WATER
SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM FIRE IF CAN BE DONE W/OUT RISK. APPLY COOLING WATER TO
SIDES OF CNTNRS THAT ARE EXPOS TO (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME. CYLINDER MAY EXPLODE IN HEAT OF FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP LEAK IF CAN BE DONE W/OUT RISK. KEEP
UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY ENTRY. STAY
UPWIND; KEEP OUT OF LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.101. STORE
AWAY FROM INCOMPATIBLE SUBSTANCES. DO NOT PERMIT PHYSICAL
DMG/OVERHEATING OF CONTAINERS.
Other Precautions:CONTENTS ARE UNDER PRESSURE; CONTAINERS MAY VIOLENTLY
RUPTURE AND TRAVEL CONSIDERABLE DISTANCE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION ON RESPIRATORS
CONTACT NEHC .
Ventilation:PROVIDE LOC EXHAUST/PROCESS ENCLOSURE VENT TO MEET EXPOS
LIMITS. VENT EQUIPMENT MUST BE EXPLOSION PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . AVOID
RPTD/PRLNGD CONTACT WITH SUBSTANCE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:CARBON DIOXIDE IN NITROGEN. FIRE FIGHT
PROC:FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF
TANKS. WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY
DEVICE/AN Y DISCOLORATION OF TANK DUE TO FIRE. SOME OF THESE MATLS,
IF SPILLED, MAY EVAP LEAVING FLAMM RESIDUE. ISOLATE (ING 5)
================== Physical/Chemical Properties ==================
Spec Gravity:>1.0
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:ODORLESS, COLORLESS GAS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAGNESIUM, BARIUM PEROXIDE, BROMINE TRIFLUORIDE, CHLORINE, CHLORINE
DIOXIDE. CONT NEHC FOR MORE SPECIFIC INFO .
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC AND/OR HAZARDOUS GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,
CONTACT DISTRICT DIRECTOR OF ENVIRONMENTAL PROTECTION AGENCY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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