=====================  Product Identification  =====================

MSDS NAME:TIN REFERENCE STANDARD SOLUTION 1000 PPM SN
NIIN:00N015362
MSDS Number: CDZJS
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Name:ING 21:OR MILK. IF VOMIT PERSISTS, ADMINISTER FLUIDS
    REPEATEDLY. INGESTED ACID MUST BE DILUTED APPROX 100 FOLD (ING 23)
RTECS #:9999999ZZ

Name:ING 22:TO RENDER IT HARMLESS TO TISSUES. MAINTAIN AIRWAY &
    TREAT SHOCK. GET MEDICAL ATTENTION IMMED. IF VOMIT (ING 24)
RTECS #:9999999ZZ

Name:ING 23:OCCURS, KEEP HEAD BELOW HIPS TO HELP PREVENT
    ASPIRATION.
RTECS #:9999999ZZ

Name:ING 7:EROSION OF CORNEAL EPITHELIUM. CNTCT W/COMPRESSED GAS
    MAY CAUSE FROSTBITE. INGEST:MAY (ING 9)
RTECS #:9999999ZZ

Name:ING 8:CAUSE BURNS OF MOUTH, THROAT, ESOPHAGUS & STOMACH
    W/CONSEQUENT PAIN, UNEASINESS, NAUS, SALIVATION, VOMIT, (ING 10)
RTECS #:9999999ZZ

Name:ING 9:DIARR, CHILLS, SHOCK & INTENSE THIRST. NEPHRITIS,
    FEVER & PERFORATION OF INTESTINAL TRACT, & CIRCULATORY (ING 11)
RTECS #:9999999ZZ

Name:ING 10:COLLAPSE MAY OCCUR. DEATH MAY BE DUE TO
    ESOPHAGEAL/GASTRIC NECROSIS. CHRONIC:INHAL:RPTD/PRLNG EXPOS MAY
    (ING 12)
RTECS #:9999999ZZ

Name:ING 11:CAUSE EROSION & DISCOLORATION OF EXPOSED TEETH,
    CHRONIC BRONCHITIS & GASTRITIS. SKIN:RPTD/PRLNG CNTCT (ING 13)
RTECS #:9999999ZZ

Name:ING 12:W/VAP/DILUTE SOLUTIONS MAY CAUSE DERMATITIS.
    PHOTOSENSITIZATION MAY OCCUR. EYE:ANIMAL EXPOSED TO VAP AT (ING 14)
RTECS #:9999999ZZ

Name:ING 13:100 PPM FOR 6 HOURS DAILY FOR 50 DAYS SHOWED ONLY
    SLIGHT UNREST & IRRIT OF EYES, BUT NO OCULAR INJURY. (ING 15)
RTECS #:9999999ZZ

Name:ING 14:EFTS ARE DEPENDENT UPON CONC & DURATION OF EXPOS.
    CONJ/EFTS SIMILAR TO THOSE FOR ACUTE EXPOS MAY OCCUR. (ING 16)
RTECS #:9999999ZZ

Name:ING 15:LOCAL EFFECTS: CORROSIVE-INHALATION, SKIN, EYE AND
    INGESTION. ACUTE TOX LEVEL:MODERATELY TOXIC BY INHALATION.
RTECS #:9999999ZZ

Name:FIRST AID PROC:UNTIL NO EVID OF CHEM REMAINS (AT LEAST
    15-20 MIN). IN CASE OF CHEM BURNS, COVER AREA W/STERILE, (ING 18)
RTECS #:9999999ZZ

Name:ING 17:DRY DRESSING, BANDAGE SECURELY, BUT NOT TOO TIGHTLY.
    GET MED ATTN IMMED. EYE:WASH IMMED W/LARGE AMTS OF (ING 19)
RTECS #:9999999ZZ

Name:ING 18:H*2O, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO
    EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). CONTINUE (ING 20)
RTECS #:9999999ZZ

Name:ING 19:IRRIGATING W/NORMAL SALINE UNTIL PH HAS RETURNED TO
    NORMAL (30-60 MINS). COVER W/STERILE BANDAGES. GET (ING 21)
RTECS #:9999999ZZ

Name:ING 20:MED ATTN IMMED. INGEST:DO NOT USE GASTRIC
    LAVAGE/EMESIS. DILUTE ACID IMMED BY DRINKING LRG QTIES OF H*2O (ING
    22)
RTECS #:9999999ZZ

Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313)
    (CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 10.0%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:TIN; (TIN METAL)
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 0.03%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9495

Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 89.9%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:SUPDAT:PREVIOUSLY EXPOSED. CNTCT W/COMPRESSED GAS MAY CAUSE
    FROSTBITE. EYE:CNTCT MAY CAUSE SEVERE IRRIT, CONJ, (ING 5)
RTECS #:9999999ZZ

Name:ING 4:CORNEAL NECROSIS & BURNS W/IMPAIRMENT/PERMANENT LOSS
    OF VISION. A DROP OF HYDROCHLORIC ACID SPLASHED IN (ING 6)
RTECS #:9999999ZZ

Name:ING 5:EYE & IMMED WASHED OUT HAS PRDCD A WHITE COAGULATION
    OF THE CORNAL & CONJ EPITHELIUM. ANIMALS EXPOS TO VAP (ING 7)
RTECS #:9999999ZZ

Name:ING 6:CONCS OF 1350 PPM FOR ONE & A HALF HRS SHOWED
    CLOUDING OF THE CORNEA & 300 PPM FOR 6 HRS SHOWED SLIGHT (ING 8)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:GAS/FUMES AT LEVELS OF
    5-35 PPM MAY CAUSE IRRIT & BURNING OF THROAT, COUGHING & CHOKING;
    50-100 PPM MAY BE BARELY TOLERABLE FOR 1 HR. HIGH LEVELS MAY CAUSE
    INFLAMM & OCCAS ULCERATION OF NO SE, THROAT/LARYNX, BRONCHITIS,
    PNEUMONIA, PALPITATIONS & HDCH. HIGHER CONC MAY CAUSE (EFTS OF
    OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:NECROSIS OF TRACHEAL & BRONCHIAL
    EPITHELIUM, NASOSEPTAL PERFORATION, ATELECTASIS, EMPHYSEMA, DMG TO
    PULM BLOOD VESSELS & LESIONS OF LIVER & OTHER ORGS. DEATH MAY BE
    DUE TO LARYNGEAL SPASM, BR ONCHOPNEUMONIA/PULM EDEMA. 1300-2000 PPM
    MAY BE DANGEROUS, EVEN ON BRIEF EXPOS. REPROD EFTS HAVE BEEN
    REPORTED (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS
    STOPPED. GIVE ARTF RESP. MAINATIN AIRWAY & BLOOD PRESS & ADMIN OXYG
    IF AVAIL. KEEP AFFECTED PERS WARM & AT REST. TREAT SYMPTOMATICALLY
    & S UPPORTIVELY. ADMIN OF OXYG SHOULD BE PERFORMED BY QUALIFIED
    PERS. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED.
    WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS OF H*2O (ING
    17)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER
    SPRAY/STANDARD FOAM. FOR LARGER FIRES, USE WATER SPRAY,
    FOG/STANDARD FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIPMENT
    . NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID
    BREATHING VAPORS OR DUSTS; KEEP UPWIND.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

==================  Accidental Release Measures  ==================

Spill Release Procedures:OCCUPATIONAL SPILL: COVER WITH SODA ASH. SCOOP
    UP AND PLACE IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:USE NIOSH APPROVED RESPIRATORS. 50 PPM-ANY
    SUPPLIED-AIR RESPIRATOR. ANY SCBA. 100 PPM-ANY SUPPLIED-AIR RESP
    OPERATED IN A CONTINUOUS FLOW MODE. ANY SUPPLIED-AIR RESP WITH A
    FULL FACEPIECE. FOR COMPLET E LIST OF RESP CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
    MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
    ANSI DESIGN CRITERIA . PROT CLTHG & EQUIP TO PVNT CNTCT W/PROD.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EYE PROT:& FULL LENGTH FACESHIELD . EFTS OF OVEREXP:IN ANIMALS.
    SKIN:CONTACT MAY CAUSE SEVERE IRRIT, INFLAMM, ULCERATION, NECROSIS
    & CHEM BURNS. SHOCK SYMPS MAY DEVELOP INCL RAPID PULSE, SWEATIN G &
    COLLAPSE. PHOTOSENSITIZATION RXNS MAY OCCUR IN PERS (ING 4)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:14 @ 20C
Vapor Density:0.7 (H*2O)
Spec Gravity:1.0
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:COMPLETELY
Appearance and Odor:COLORLESS LIQUID

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDRIDE, BASES, FLUORINE, METALS, OXIDIZERS (STRONG). FOR
    COMPLETE LISTING OF MATLS TO AVOID CNTCT NEHC .
Stability Condition to Avoid:NONE REPORTED.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
    CORROSIVE HYDROGEN CHLORIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
    STATE AND LOCAL REGULATIONS .

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***