=====================  Product Identification  =====================

MSDS NAME:BUFFER SOLUTION (PH 6.00) UNDILUTED, SB106
NIIN:00N038309
MSDS Number: CDZKG
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LN
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Name:ING 22: CALIFORNIA SAFE DRINING WATER & TOXIC ENFORCEMENT
    ACT OF OF 1986 (PROPOSITION 65) PROHIBITS CONTAM ANY (ING 24)
RTECS #:9999999ZZ

Name:ING 23: KNOWN SOURCES OF DRINKING WATER W/SUBSTANCES KNOWN
    TO CAUSE CANCER &/OR REPRODUCTIVE TOXICITY.
RTECS #:9999999ZZ

Name:ING 8: DIOXIDE:SLOW RXN BECOMES EXPLOSIVE AROUND 180C.
    NITROMETHANE:FORMS EXPLO CMPD IN PRESENCE OF ALKALIES. (ING 10)
RTECS #:9999999ZZ

Name:ING 9: OXIDIZERS (STRONG): FIRE & EXPLO HAZ. PEROXYFORMIC
    ACID (CONCD): VIOLENT OXIDATION RXN. PHENOL: (ING 11)
RTECS #:9999999ZZ

Name:ING 10: POLYMERIZATION RXN W/SUDDEN PRESS DEVELOPMENT.
RTECS #:9999999ZZ

Name:EXPLAN OF CARCIN: TO BE CARCIN. OSHA REGULATED: CFR 29
    1910.1048.
RTECS #:9999999ZZ

Name:EFTS OF OVEREXP: PHOSPHATES ARE CAPABLE OF SERIOUSLY
    REDUCING IONIC SERUM CALCIUM. CHRONIC: SKIN:RPTD & PRLNGD (ING 14)
RTECS #:9999999ZZ

Name:ING 13: CNTCT MAY CAUSE DERM. INGEST:SODIUM PHOSPHATE,
    MONOBASIC IS USED AS FOOD ADDITIVE. NO ADVERSE EFTS REPORTED.
RTECS #:9999999ZZ

Name:FIRST AID PROC:EVID OF CHEM REMAINS(@ LST 15-20 MIN). IN
    CASE OF CHEM BURNS, COVER AREA W/STERILE, DRY DRESSING.(ING 16
RTECS #:9999999ZZ

Name:ING 15: BANDAGE SECURELY BUT NOT TOO TIGHTLY. GET MED ATTN
    IMMED. EYES:WASH IMMED W/LG AMTS OF WATER, OCCASNLY (ING 17)
RTECS #:9999999ZZ

Name:ING 16: LIFTING UPPER & LOWER LIDS UNTIL NO EVID OF CHEM
    REMAINS (@ LST 15-20 MIN). CONTINUE IRRIGATING W/NORM (ING 18)
RTECS #:9999999ZZ

Name:ING 17: SALINE UNTIL PH RETURNS TO NORM (30-60 MIN). COVER
    W/STERILE BANDAGES. GET MED ATTN IMMED. INGEST:TREAT (ING 19)
RTECS #:9999999ZZ

Name:ING 18: SYMP & SUPPORTIVELY. GET MED ATTN IMMED. IF VOMIT
    OCCURS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIR.
RTECS #:9999999ZZ

Name:SPILL PROC:REPORTABLE QUANTITY ESTABLISHED FOR THAT
    SUBSTANCE BE IMMED REPORTED TO LOCAL EMER PLANNING COMMITTEE(ING
    21)
RTECS #:9999999ZZ

Name:ING 20: & STATE EMER RESPONSE COMMISSION (40 CFR 355.40).
    IF RELS OF SUBSTANCE IS REPORTABLE UNDER CERCLA (ING 22)
RTECS #:9999999ZZ

Name:ING 21: SECTION 103, NRC MUST BE NOTIFIED IMMED AT
    800-424-8802 OR 202-426-2675 IN METRO WASHINGTON DC AREA. (ING 23)
RTECS #:9999999ZZ

Name:SODIUM PHOSPHATE, MONOBASIC; (POTASSIUM PHOSPHATE,
    MONOBASIC)	LD50: (ORAL, RAT) 8290 MG/KG
CAS:7558-80-7
RTECS #:WA1900000
Fraction by Wt: 8%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 0.7%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:FORMALDEHYDE (SARA 302/313) (CERCLA)  LD50: (ORAL, RAT) 100
    MG/KG
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 0.2%
OSHA PEL:N/K 
ACGIH TLV:0.3 PPM, C
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 0.08%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM; 250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 91.02%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:SUPDAT: ANILINE + PERCHLORIC ACID: ANILINE TREATED
    W/PERCHLORIC ACID, THEN W/FORMALDEHYDE, GIVES A RESINOUS PROD (ING
    7)
RTECS #:9999999ZZ

Name:ING 6:WHICH BURNS W/EXPLO VIOLENCE. COPPER, COPPER ALLOYS,
    COPPER SALTS, STEEL: FORMALDEHYDE SOLNS MAY BE CORR. (ING 8)
RTECS #:9999999ZZ

Name:ING 7: HYDROCHLORIC ACID: FORMS HIGHLY TOX
    BIS(CHLOROMETHYL) ETHER. HYDROGEN PEROXIDE: VIOLENT RXN. NITROGEN
    (ING 9)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:SODIUM PHOSPHATE, MONOBASIC: ACUTE:
    INHAL: INHAL OF DUST MAY CAUSE IRRIT. SKIN: MAY CAUSE IRRIT. EYES:
    MAY CAUSE TRANSIENT IRRIT. TESTED ON RABBIT EYES BY CONTINUOUS
    EXPOS FOR 3 HRS AT 0.1 M SOLN AT P H 7.0-7.5 MADE UP TO 0.46
    OSMOLAR W/SODIUM CHLORIDE OR SUCROSE, CAUSED NO DISTURBS OF CORNEA.
    INGEST: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS, SUPP, VOL
    7, PG 211, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCONS, 1994:
    ANTIC (ING 12)
Effects of Overexposure:HLTH HAZ: MAY RSLT IN ABDOMINAL PAIN, NAUS,
    VOMIT, DIARR, CRAMPS, PAIN & BURNING IN MOUTH. DOSES OF 250 G/KG
    GIVEN ORALLY TO GUINEA PIGS, RATS & RABBITS PRDCED DIARR.
    GENERALLY, PHOSPHATES ARE SLOWLY  & INCOMPLETELY ABSORBED,
    THEREFORE SYSTEMIC RXNS ARE UNLIKELY WHEN THESE SALTS ARE GIVEN
    ORALLY. SODIUM (ING 13)
Medical Cond Aggravated by Exposure:PERSONS WITH ASTHMA, CHRONIC SKIN
    DISEASE OR PREEXISTING LUNG DISEASE ARE AT INCREASED RISK FROM
    EXPOSURE.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG HAS
    STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN
    OXYGEN IF AVAIL. KEEP AFFECTED PERSON WARM & AT REST. TREAT SYMP &
    SUPPORTIVELY.  ADMIN OF OXYGEN SHOULD BE PERFROMED BYQUALIFIED
    PERS. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED.
    WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF WATER
    UNTIL NO (ING 15)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
    REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
    FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
    CNTNR FROM AREA IF W/OUT RISK. DO NOT SCATTER SPILLED MATL
    W/HIGH-PRESS STREAMS. DIKE FIRE-CONTROL (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
    HEAT OR FLAME.

==================  Accidental Release Measures  ==================

Spill Release Procedures:STOP LEAK IF YOU CAN DO IT W/OUT RISK. FOR SM
    SPILLS, TAKE UP W/SAND OR OTHER ABSORB MATL & PLACE INTO CLEAN, DRY
    CNTNRS FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZ AREA &
    DENY ENTRY. SARA 304  REQS THAT RELS EQUAL TO OR GREATER THAN (ING
    20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
    SUBSTANCES.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. AVOID CONTACT
    WITH STRONG OXIDIZERS. EXCESSIVE HEAT, SPARKS OR OPEN FLAME.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED
    ON CONTAM LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE
    WORKING LIMITS OF THE RESPIRATOR & BE APPROVED BY NIOSH. FOR A LIST
    OF SPECIFIC RESPIRATORS  CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENT TO MEET
    PUBLISHED EXPOS LIMITS. VENT EQUIP MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
    WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT ANY SKIN
    CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: WATER FOR LATER DISP. USE AGENTS SUITABLE FOR TYPE OF
    SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, KEEP UPWIND. MATL TO AVOID:
    (STRONG), ANHYDRIDES, ISOCYANATES, OXIDES, UREA: FORMALDEHYDE 
    SOLNS REACT. AMMONIA, BISULFIDES, IODINE, IRON PREPARATIONS,
    POTASSIUM PERMANGANATE, SILVER SALTS: INCOMPATIBLE.(ING 6)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ING 1: BRASS, STEEL:MAY BE CORR IN PRESENCE OF MOISTURE. METALS:SOLNS
    MAY BE CORR. ING 2: ACIDS(INORG), ALKALIES(SUPDAT)
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
    PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
    TOXIC AND/OR HAZARDOUS GASES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
    WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE CONTACT
    THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***