===================== Product Identification =====================
MSDS NAME:ZINC CHROMATE, Z-35
NIIN:00N038397
MSDS Number: CDZKK
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ING 17:EFFECTIVE INITIALLY. IN PATIENTS W/DESPRESSED
RESP/IF EMESIS IS NOT PRDCD, PERFORM GASTRIC LAVAGE (ING 19)
RTECS #:9999999ZZ
Name:ING 18:CAUTIOUSLY. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
GASTRIC LAVAGE SHOULD BE PERFORMED BY QUALIFIED (ING 20)
RTECS #:9999999ZZ
Name:ING 19:MED PERS. GET MED ATTN IMMED. ANTIDOTE:CHROMIUM
POISONING:USE OF DIMERCAPROL HAS BEEN SUGGESTED ON THE (ING 21)
RTECS #:9999999ZZ
Name:ING 20:BASIS OF FINDINGS IN ANIMALS. GIVE 3 MG/KG (OR 0.3
ML/10 KG) EVERY 5 HRS, INTRAMUSCULARLY FOR FIRST (ING 22)
RTECS #:9999999ZZ
Name:ING 21:2 DAYS & THEN 2 MG/KG EVERY 12 HOURS FOR A TOTAL OF
10 DAYS. ANTIDOTE SHOULD BE ADMINISTERED BY (ING 23)
RTECS #:9999999ZZ
Name:ING 22:QUALIFIED MEDICAL PERSONNEL. FOR MORE ANTIDOTE INFO
CONTACT NEHC .
RTECS #:9999999ZZ
Name:SPILL PROC:DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL.
ISOLATE HAZARD AREA AND DENY ENTRY.
RTECS #:9999999ZZ
Name:RESP PROC:COMBINATION W/AUXILIARY SCBA OPERATED IN
PRESS-DEMAND/OTHER POS-PRESS MODE. CONT NEHC FOR MORE INFO .
RTECS #:9999999ZZ
Name:ING 3:NASAL SEPTUM W/FOUL DISCHARGE, CONGESTION, RHINITIS,
PHARYNGITIS, TRACHEITIS, LUNG INFLAMM, EMPHYSEMA, (ING 5)
RTECS #:9999999ZZ
Name:ING 4:BRONCH & POLYPS & HOARSENESS OF LARYNX & POLYPS/CYSTS
OF SINUSES HAVE ALSO BEEN RPTD. SENSIT RXNS MAY OCCUR(ING 6)
RTECS #:9999999ZZ
Name:ING 5:RSLTG IN BRONCH ASTHMATIC ATTACTS. KERATOSIS OF LIPS,
GINGIVA & PALATE HAVE BEEN RPTD AFTER YRS OF EXPOS. (ING 7)
RTECS #:9999999ZZ
Name:ING 6:SKIN:PRLNG EXPOS MAY CAUSE IRRITATIVE DERM, SENSIT
DERM, & CHROME ULCERS. SUNLIGHT SENSITIVITY HAS ALSO (ING 8)
RTECS #:9999999ZZ
Name:ING 7:BEEN RPTD. ULCERATION OCCURS ANWHERE ON BODY WHERE
SKIN IS BROKEN. KIDNEY DMG IN WORKERS HAS BEEN RPTD (ING 9)
RTECS #:9999999ZZ
Name:ING 8:FROM ABSORPTION THRU DAMAGED SKIN. EYE:RPTD & PRLNG
CNTCT MAY PRDCE CONJ, LACRIMATION, & DARK RED BANDS (ING 10)
RTECS #:9999999ZZ
Name:ING 9:AROUND CORNEA. INGEST:FIVE CASES OF STOMACH CANCER
HAVE BEEN REPORTED, APPARENTLY FROM SWALLOWING OF (ING 11)
RTECS #:9999999ZZ
Name:ING 10:CHROMATE DUST OR FROM EXCESSIVE MOUTH BREATHING. FOR
DETAILED HEALTH HAZARD INFO CONTACT NEHC .
RTECS #:9999999ZZ
Name:FIRST AID PROC:LESIONS CAN BE SCRUBBED W/20% SOLN OF SODIUM
HYPOSULFITE/TREATED W/CALCIUM DISODIUM EDETATE (ING 13)
RTECS #:9999999ZZ
Name:ING 12:OINTMENTS. FRESHLY PREPARED & PROMPTLY APPLIED 10%
ASCORBIC ACID SOLUTION MAY SPEED HEALING OF ULCERS. (ING 14)
RTECS #:9999999ZZ
Name:ING 13:EYE:WASH IMMED W/LRG AMTS OF H*2O, OCCAS LIFTING
UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (ING 15)
RTECS #:9999999ZZ
Name:ING 14:(AT LEAST 15-20 MIN). CONTINUE IRRIGATING W/NORMAL
SALINE UNTIL PH HAS RETURNED TO NORMAL (30-60 MIN). (ING 16)
RTECS #:9999999ZZ
Name:ING 15:COVER W/STERILE BANDAGES. GET MED ATTN IMMMED.
INGEST:IF CONSCIOUS & NOT CONVULSING, INDUCE EMESIS BY (ING 17)
RTECS #:9999999ZZ
Name:ING 16:GIVING SYRUP OF IPECAC (KEEPING HEAD BELOW HIPS TO
PVNT ASPIR), FOLLOWED BY H*2O. RPTD IN 20 MIN IF NOT (ING 18)
RTECS #:9999999ZZ
Name:CHROMIC ACID, ZINC SALT; (ZINC CHROMATE)
CAS:13530-65-9
RTECS #:GB3290000
Fraction by Wt: 100%
OSHA PEL:0.1 MG(CRO3)/M3
ACGIH TLV:0.01MG(CR)/M3,A1; 95
Name:SUPDAT:BLOOD LOSS INTO GI TRACT & @ OTHER SITES, CAUSING
CVS SHOCK. MAY BE FATAL. APPROXIMATE LETHAL DOSE IS 1.0-(ING 3)
RTECS #:9999999ZZ
Name:ING 2:16.0 GRAMS. CHRONIC:INHAL:RPTD EXPOS HAS PRDCD
INFLAMM, BLEEDING, PAINLESS ULCERATION & PERFORATION OF (ING 4)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:30 MG(CR)/M3 IMMED DANGEROUS TO
LIFE/HLTH. MAY CAUSE CORR INJURY TO MUC MEMB. MAY CAUSE IRRIT,
TRACHEOBRONCHITIS, COUGH, SORE THROAT, CHEST PAIN, HDCH, SINUSITUS,
LARYNGITIS, SNEEZING, WHEEZING, PULM EDEMA, ANOREXIA, FEVER, &
GENERALIZED BRONCHOSPASM. SENSIT RXN MAY OCCUR. SKIN CNTCT:HIGH
CONCS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:ZINC CHROMATE:IARC MONO ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990:GRP 1. NTP 7TH ANN
RPT ON (SUPDAT)
Effects of Overexposure:HLTH HAZ:MAY CAUSE REDNESS, PAIN, & ULCERATION.
APPLIC TO BROKEN SKIN HAS PRDCD LOC NECROSIS, NAUS, VOMIT, SHOCK,
COMA, KIDNEY NECROSIS, & DEATH. SENSIT RXNS MAY OCCUR. EYE
CNTCT:SOLNS MAY CAUSE SEV, PERM CORNEAL INJURY. MAY CAUSE IRRIT
CONJ. INGEST:MAY CAUSE GASTROENTERITIS W/NAUS, VOMIT, THIRST,
VERTIGO, (SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
RESPIRATORY DISEASE OR INJURY, SKIN DISEASE, VASCULATURE DAMAGE,
LIVER DISEASE, OR BLOOD DISORDERS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE
ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMINISTER OXYGEN IF
AVAILABLE. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY &
SUPPORTIVELY. ADMIN OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED
PERSONNEL. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES
IMMED. WASH AREA W/SOAP & H*2O UNTIL NO EVID OF CHEM REMAINS
(APPROX 15-20 MIN). (ING 12)
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM AREA IF CAN W/OUT RISK. APPLY COOLING H*2O TO SIDES OF
CNTNRS EXPOSED TO FLAMES UNTIL (SUPDAT)
Unusual Fire/Explosion Hazard:DO NOT USE H*2O DIRECTLY ON MATL. IF LRG
AMTS OF COMBUST MATLS ARE INVOLVED, USE WATER SPRAY/FOG IN FLOODING
AMTS. ABSORB CORR VAPS. COOL COOL CNTNRS (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK W/OUT
RISK. SMALL SPILLS-TAKE UP W/ABSORB MATL & PLACE INTO CNTNRS FOR
LATER DISPOSAL. SMALL DRY SPILLS-W/CLEAN SHOVEL PLACE MATL INTO
CLEAN, DRY CNTNR & COVER, MO VE CNTNRS FROM SPILL AREA. LRGR
SPILLS-(ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESP MUST BE NIOSH APPRVD. ANY DETECTABLE
CONC:ANY SCBA THAT HAS FULL FACEPIECE & IS OPERATED IN A
PRESS-DEMAND/OTHER POS-PRESS MODE. ANY SUPPLIED AIR RESP THAT HAS
FULL FACEPIECE & IS OPERATED IN PRE SS-DEMAND/POS-PRESS MODE IN
(ING 25)
Ventilation:PROCESS ENCLOSURE RECOMMENDED TO MEET PUBLISHED EXPOSURE
LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:WELL AFTER FIRE IS OUT. STAY AWAY FROM END OF TANKS.
EXPLO HAZ:W/H*2O FROM AS FAR A DISTANCE AS POSS. KEEP UPWIND.
CNDTNS (STAB):COMBUSTIBLES (WOOD, PAPER, OIL, ETC.). EXPLAN OF
CARCIN :CARCIN, 1994:KNOWN TO BE CARCIN. EFTS OF OVEREXP:MUSCLE
CRAMPS, CONVULSIONS, & COMA. EARLY DEATH MAY RSLT FROM (ING 2)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:320F,160C
Spec Gravity:3.40
Solubility in Water:INSOLUBLE
Appearance and Odor:ODORLESS, LEMON YELLOW PRISMS OR FINE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUSTIBLES, HYDRAZINE, ORGANIC MATERIALS.
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY,
FLAMM, POISONOUS GASES MAY ACCUM IN TANKS & HOPPER CARS. MAY IGNITE
(SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC FUMES OF ZINC AND CHROMIUM.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FED, STATE AND LOC REGS WHEN
DISPOSING OF SUBSTANCE. CHROMIUM-REGULATOR LEVEL:5.0 MG/L. MATLS
WHICH CNTN ABOVE SUBSTANCE @/ABOVE REGULATORY LEVEL MEET EPA
CHARACT OF TOX & MUST BE DISPOS O F I/A/W 40 CFR PART 262. EPA HAZ
WASTE NO:D007.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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