===================== Product Identification =====================
MSDS NAME:816 MEDIUM BLUE
MSDS Number: CDZHD
=== Responsible Party ===
Company:RAABE CORP
Box:23708
City:MILWAUKEE
State:WI
ZIP:53223
Country:US
Info Phone Num:414-255-9500
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:0A3L4
=== Contractor Identification ===
Company:RAABE CORPORATION THE PRECISION COLOR COMPANY
Address:N92 W14701 ANTHONY AVE.
Box:1090
City:MENOMONEE FALLS
State:WI
ZIP:53051-1630
Country:US
Phone:414-255-9500/800-966-7580
CAGE:0A3L4
============= Composition/Information on Ingredients =============
Name:AMORPHOUS SILICA GEL; (AMORPHOUS PRECIPITATED SILICA)
CAS:112926-00-8
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:10 MG/M3 (MFR)
Name:SUPP DATA:MAY TRAVEL A LONG DISTANCE TO A SOURCE OF
IGNITION & FLASH BACK.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:BE FATAL. CHRONIC:LAB ANIMAL EFTS:KIDNEY
DMG, EYE DMG, LUNG DMG, LIVER DMG, SPLEEN DMG, ANEMIA, (ING 19)
RTECS #:9999999ZZ
Name:ING 18:BRAIN DMG. HUMAN EFTS:LIVER DMG, CARD ABNORMS. RPTS
HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN(ING 20)
RTECS #:9999999ZZ
Name:ING 19:& NERV SYS DMG. ING 2:RPTD BRTHG/SKIN CONT MAY INCR
POTENCY OF NEUROTOXINS, SUCH AS HEXANE, WHEN EXPOS (ING 21)
RTECS #:9999999ZZ
Name:ING 20:OCCUR AT SAME TIME. ING 3:HAS BEEN SHOWN TO CAUSE
CANCER IN LAB ANIMALS (MFR). ING 4:LAB ANIMALS:MAY BE (ING 22)
RTECS #:9999999ZZ
Name:ING 21:HARMFUL TO FETUS. RPTD EXPOS HAS BEEN ASSOC W/HIGH
FREQUENCY HEARING LOSS; HUMAN CONSEQUENCES UNCERTAIN. (ING 23)
RTECS #:9999999ZZ
Name:ING 22:WARNING! PROD CNTNS CHEM(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS/OTHER REPRO HARM. (ING 24)
RTECS #:9999999ZZ
Name:ING 23:NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM
REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH (ING 25)
RTECS #:9999999ZZ
Name:ING 24:PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO &
SAFE HANDLING & EXPOSURE INFO .
RTECS #:9999999ZZ
Name:PIGMENTS; (ORGANIC & INORGANIC PIGMENTS)
Fraction by Wt: 19%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 36%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 6%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM;300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PHTHALIC ACID, BENZYL BUTYL ESTER (SARA 313) (CERCLA)
CAS:85-68-7
RTECS #:TH9990000
Fraction by Wt: 2%
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 13%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ALUMINUM; (ALUMINUM FLAKE) (SARA 313)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 2%
OSHA PEL:15 MG/M3 DUST
ACGIH TLV:10 MG/M3 DUST
Name:STODDARD SOLVENT; (MINERAL SPIRITS)
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 2%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Name:TRIMETHYL BENZENE; (TRIMETHYL BENZENE (MIXED ISOMERS))
CAS:25551-13-7
RTECS #:DC3220000
Fraction by Wt: 2%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM
Name:1,2,4-TRIMETHYLBENZENE (SARA 313)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 4%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM
Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 2%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:BUTANE; (N-BUTANE)
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 8%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 17%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (P.M. ACETATE)
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 8%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ACRYLIC POLYMER
CAS:25068-63-7
Fraction by Wt: 13%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:NITROCELLULOSE; (CELLULOSE, NITRATE)
CAS:9004-70-0
RTECS #:QW0970000
Fraction by Wt: 2%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE SEV IRRIT. LIQ
CONT MAY CAUSE SEV CORNEAL INJURY. SKIN:MAY CAUSE IRRIT. RPTD &
PRLNG CONT MAY CAUSE ALLERGIC DERM. INHAL:EXPOS TO HIGH CONCS OF
VAPS MAY CAUSE DIZZ, BRTHG DFCLTY, HDCHS/RESP IRRIT. EXTREMELY
HIGH CONCS MAY CAUSE DROW, STAG, CONFUSN, UNCON, COMA/DEATH. EXCESS
INHAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF VAPS CAN CAUSE NASAL & RESP IRRIT.
LIQ/VAP MAY BE IRRIT TO SKIN, EYES, THROAT/LUNGS. INTENTIONAL
MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL.
INGEST:MOD TOX. MAY CAUSE STOM DISCOMFORT, NAUS, VOMIT, DIARR &
NARCOS. ASPIR INTO LUNGS IF SWALLOWED/BY VOMIT CAN CAUSE CHEM PNEUM
WHICH CAN (ING 18)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. GET MED
ATTN, IF IRRIT PERSISTS. SKIN:WASH THORO W/SOAP & WATER. SEEK MED
ATTN. REMOVE & LAUNDER CONTAM CLTHG BEFORE REUSE. INHAL:MOVE PERS
TO FRE SH AIR. IF BRTHG STOPS, APPLY ARTF RESP& SEEK MED ATTN.
INGEST:DECISION WHETHER TO INDUCE VOMIT/NOT MUST BE MADE BY MD
AFTER CAREFULY CONSIDERATION OF ALL MATLS INGESTED.
===================== Fire Fighting Measures =====================
Flash Point:-25F,-32C
Lower Limits:0.3%
Upper Limits:13.1%
Extinguishing Media:DRY CHEMICAL, CO*2 OR FOAM. WHEN FIGHTING FIRE
INVOLVING ALUMINUM FLAKE, DO NOT USE WATER/HALOGENATED EXTING
AGENTS.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY SHOULD NOT BE USED EXCEPT TO KEEP DOWN VAPS/COOL CLSD
CNTNRS TO PVNT BUILD-UP OF PRESS. IF (SUPDAT)
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESS. DO NOT USE/STORE
NEAR SOURCES OF HEAT, SPKS/OPEN FLAME. KEEP AWAY FROM ANY SOURCE OF
HEAT SUCH AS SUNLIGHT, HEATERS/STOVES THAT (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID HEAT,
SPARKS, FLAMES & ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA OF
SPILL & ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT VAPORS.
REMOVE W/INERT ABSORBE NT MATERIALS & NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA
W/VENTILATION SUITABLE FOR STORING MATERIALS SHOWN IN INGREDIENTS
SECTION. DO NOT STORE AT TEMPERATURES ABOVE 120F.
Other Precautions:STORE IN A COOL PLACE AWAY FROM DIRECT SUNLIGHT OR
ANY SOURCE OF IGNITION. SMOKE IN DESIGNATED AREAS ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR
ANY COMPONENT, A NIOSH APPROVED RESPIRATOR SUITABLE FOR COMPONENTS
LISTED IS RECOMMENDED.
Ventilation:LOC EXHST:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE
PROVIDED TO KEEP CONTAM BELOW CURRENT APPLIC OSHA EXPOS (SUPDAT)
Protective Gloves:CHEMICAL RESIST PLASTIC/RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . APPROP IMPERVIOUS CLTHG IS REC IF PRLNG/RPTD CONTACT IS
LIKELY.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. WASH
HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
FIRE FIGHT PROC:WATER IS USED, FOG NOZZ ARE PREF. VENT:LIMS/ACGIH'S TLV
LIMS. EYE PROT:FULL LGTH FCSHLD . EXPLO HAZ:COULD CAUSE CNTNR TO
BURST. DO NOT PUNCTURE/INCIN. DO NOT CRUSH/PLACE IN GARBA GE
COMPACTOR. DO NOT STORE >120F. AEROSOL CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. PROD VAPS ARE HVR/AIR &(ING 17)
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:>-44F,>-42C
Vapor Density:HVR/AIR
Spec Gravity:0.75-0.78
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Appearance and Odor:OPAQUE LIQUID; SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALUMINUM FLAKE CAN REACT VIOLENTLY W/HALOGENATED HYDROCARBS INCL
HALOGENATED EXTING AGENTS; ACIDS & CAUSTIC SOLNS.
Stability Condition to Avoid:AVOID CONTACT W/HEAT, SPARKS & OPEN FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON DIOXIDE, CARBON MONOXIDE & UNIDENTIFIABLE ORGANIC MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF PRODUCT
I/A/W LOCAL, COUNTY, STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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