===================== Product Identification =====================
MSDS NAME:CASCOPHEN G-4422A, 321792
NIIN:00N091608
Status Code:A
MSDS Number: CJMZD
=== Responsible Party ===
Company:BORDEN CHEMICAL INC
Address:155 W A ST
City:SPRINGFIELD
State:OR
ZIP:97477
Country:US
Info Phone Num:541-744-3256
Emergency Phone Num:800-228-5635
CAGE:5M413
=== Contractor Identification ===
Company:BORDEN CHEMICAL INC
Address:155 W A ST
Box:City:SPRINGFIELD
State:OR
ZIP:97477
Country:US
Phone:541-744-3256
CAGE:5M413
============= Composition/Information on Ingredients =============
Name:FORMALDEHYDE LD50: (ORAL, RAT) 0.8 G/KG
CAS:50-00-0
RTECS #:LP8925000
< Wt:.1
OSHA PEL:see 1910.1048
ACGIH STEL:C0.37 MG/M3;C0.3 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:METHANOL LD50: (ORAL, RAT) 5628 MG/KG
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:RESORCINOL LD50: (ORAL, RAT) 301 MG/KG
CAS:108-46-3
RTECS #:VG9625000
Minumum % Wt:5.
Maxumum % Wt:10.
ACGIH TLV:45 MG/M3;10 PPM
ACGIH STEL:90 MG/M3;20 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PHENOL LD50: (ORAL, RAT) 414 MG/KG
CAS:108-95-2
RTECS #:SJ3325000
Minumum % Wt:5.
Maxumum % Wt:10.
OSHA PEL:19 MG/M3;5 PPM
ACGIH TLV:19 MG/M3;5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL) >0.5 G/KG (SIMILAR PROD)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IMMED HAZS:INGEST:NOT EXPECTED TO BE
HARMFUL UNDER NORM CNDTNS OF USE. INHAL:NOT EXPECTED TO BE HARMFUL
UNDER NORM CNDTNS OF USE. HOWEVER, OVEREXP MAY CAUSE CNS DEPRESS.
ALSO, IF ALLOWED TO BECOME AIR BORNE, MAY CAUSE IRRIT OF
NOSE,THROAT & LUNGS. SKIN:MAY CAUSE IRRIT ON PRLNGD/RPTD CNTCT.
EYES:CAUSES CHEM BURNS. METHANOL - CAN CAUSE CNS DEPRESS. SIGNS &
SYMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT, UNCO N & ASPHY. RPTS ASSOC
RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS SYS
DMG. RESORCINOL - MATL MAY PENETRATE SKIN & MAY CAUSE SYSTEMIC TOX.
INGEST COULD PRDCE DIZZ, WEAK, COLLAPSE & RESP FAILURE. (EFTS OF
OVEREXP)
Effects of Overexposure:HLTH HAZS: PHENOL - CAN CAUSE CNS DEPRESS.
SIGNS & SYMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT, UNCON & EVEN ASPHY.
DELAYED HAZS: FORMALDEHYDE - POTNTL CANCER HAZ. RATS CHRONICALLY
EXPOS TO 14 PPM FORMALDE HYDE CONTRACTED NASAL CANCERS. BASED
ONANIMAL DATA & LIMITED EPIDEMIOLOGICAL EVID, NTP & IARC HAVE
LISTED FORMALDEHYDE AS PROBABLE HUMAN CARCIN. OSHA REGULATES
FORMALDEHYDE AS POTNTL HUMAN CARCIN. MAY CAUSE ALLERGIC SKIN RXN.
SOME RPTS SUGGEST IT MAY CAUSE RESP SENSIT, SUCH AS ASTHMA. OSHA
HAS IDENTIFIED 0.5 PPM AS "ACTION LEVEL," 29 CFR 1910.1048. PLEASE
REFER TO OSHA STD FOR GUIDANCE APPLIC TO Y OUR SPECIFIC (SUPDAT)
Medical Cond Aggravated by Exposure:SOME REPORTS SUGGEST THAT
FORMALDEHYDE MAY AGGRAVATE PRE-EXISTING RESPIRATORY AND SKIN
DISORDERS. PRE-EXISTING HEART OR CIRCULATORY DISORDERS MAY BE
AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
First Aid:INGEST: IF ACCIDENTLY SWALLOWED, DILUTE BY DRINKING LARGE
QUANTITIES OF WATER. IMMEDIATELY CONTACT POISON CONTROL CENTER OR
HOSPITAL EMERGENCY ROOM FOR ANY OTHER ADDITIONAL TREATMENT
DIRECTIONS. INHAL : REMOVE TO FRESH AIR. SKIN: IN CASE OF
IRRITATION , FLUSH WITH WATER. EYES: IMMED FLUSH EYES W/PLENTY OF
WATER FOR AT LEAST 15 MINUTES. EYELIDS SHOULD BE HELD APART DURING
IRRIGATION TO INSURE WATER CONTACT WITH ENTIRE SURFACE OF EYES AND
LIDS. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=59.C, 138.2F
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE, USE WATER SPRAY, DRY CHEMICAL,
"ALCOHOL" FOAM OR CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. KEEP AWAY FROM HEAT AND
FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. LARGE
QUANTITIES: ENCLOSE WITH DIKING MATERIAL TO PREVENT SCOOPAGE INT
NATURAL BODIES OF WATER. THE CONSULT BORDEN, INC. SMALL QUANTITIES:
SOAK UP WITH ABSORBENT MATERI AL AND REMOVE TO A CHEMICAL DISPOSAL
AREA.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A
COOL, DRY PLACE. NOT HARMED BY FREEZING. IF FROZEN, RESIN SHOULD BE
THAWED SLOWLY AT ROOM TEMPERATURE AND AGITATED THOROUGHLY BEFORE
USE. STORAGE LIFE IS 4 MONTHS AT 70F, LESS AT HIGHER TEMPERATURES.
Other Precautions:INHALATION: AVOID PROLONGED OR REPEATED BREATHING OF
VAPOR. SKIN: AVOID PROLONGED OR REPEATED CONTACT WITH SKIN AND
CLOTHING. EYES: DO NOT GET IN EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE
CRITERIA, USE NIOSH APPRVD RESPIRATORY PROTECTION EQUIPMENT.
RESPIRATORS SHOULD BE SELECTED BASED ON FORM & CONCENTRATION OF
CONTAMINANTS IN AIR I/A/W OSHA LAWS AND REGULATIONS OR OTHER
APPLICABLE STANDARDS OR GUIDELINES, INCLUDING ANSI STANDARDS
REGARDING RESPIRATORY PROTECTION.
Ventilation:IF AIRBORNE CONTAMINANTS ARE GENERATED WHEN MATL IS HEATED
OR HANDLED, SUFFICIENT VENT IN VOL & AIR FLOW PATTERNS SHOULD BE
PROVIDED TO (STATE REG INFO)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL
HYGIENE AND SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING
UNNECESSARY EXPOSURE AND REMOVAL OF THE MATERIAL FROM EYES, SKIN
AND CLOTHING.
Supplemental Safety and Health
EFTS OF OVEREXP: OPERATIONS. METHANOL: POSS REPRO DISORDERS FROM PRLNGD
EXPOS. MAY CAUSE LUNG DMG BASED ON ANIMAL DATA. MAY CAUSE LIVER DMG
& KIDNEY DMG BASED ON ANIMAL DATA. MAY CAUSE BLINDNESS IF (S
WALLOWED. RESORCINOL: ANIMAL STUDIES INDICATED EXPOS TO HIGH DOSES
CAN RSLT IN REVERSIBLE (ECOLOGICAL INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:=79.C, 174.2F
Melt/Freeze Pt:<0.C, 32.F
Vapor Pres:20-50 MM HG @ 25C
Vapor Density:>1(AIR=1)
Spec Gravity:1.1
pH:8.8-9.2
Viscosity:360-430 CPS
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:PURPLE-BROWN LIQUID; ALCOHOLIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS.
Stability Condition to Avoid:NORMALLY STABLE, BUT MAY BECOME UNSTABLE
AT HIGH TEMPERATURES OR MAY REACT WITH WATER.
Hazardous Decomposition Products:CO, CO*2, ALDEHYDES (INCLUDING
FORMALDEHYDE), PARTICULATE MATTER AND OTHER ORGANIC COMPOUNDS.
=================== Toxicological Information ===================
Toxicological Information:INHAL:SIMILAR PROD FOUND TO BE NON-TOX BY
INHAL WHEN TESTED AS IN 16 CFR 1500.3(C)(1) & (2). SKIN ABSPR[TOPM:
SIMILAR PROD FOUND NON-TOX DERMALLY WHEN TESTED AS IN 16 CFR
1500.3(C)(1) & (2). SKIN:SIMI LAR PROD NOT PRIMARY IRRITANT
(PRIMARY SKIN IRRIT INDEX <5/8) WHEN TESTED AS IN 16 CFR 1500.41.
EYES:SIMILAR PROD SEV IRRIT WHEN TESTED AS 16 CFR 1500.42.
FORMALDEHYDE: LC50: RAT=203 MG/KG (RTECS). LD 50: SKIN-RBT=0.27
G/KG (SAX). METHANOL: LC50: RAT=62000 PPM/4H (SAX). LD50:
SKIN-RBT=20 G/KG (SAX). RESORCINOL: LC50:NOT AVAIL. LD50:
SKN-RBT=3360 MG/KG (SAX). PHENOL: LD50: RAT=316 MG/M3 (RTECS). LD5
0: SKIN-RBT=850 MG/KG (SAX).
===================== Ecological Information =====================
Ecological:NOT DETERMINED. SUPDAT: DMG TO THYROID GLAND. SEE FOOTNOTE
C. PHENOL: POSS BIRTH DEFECT HAZ. MAY CAUSE BIRTH DEFECTS BASED ON
ANIMAL DATA. HAS BEEN TOX TO FETUS IN LAB ANIMALS AT DOSES NON-TOX
TO MOTH ER. INCREASED INCIDENCE OF CLEFT PALATE REPORTED IN MICE AT
MATERNALLY LETHAL DOSES & MAY BE DUE TO CNDTNS OF STRESS. AT
EXCESSIVE LEVELS TOX TO MATERNAL ANIMAL, TOXICITY & LETHALITY TO
NEWBORN ANIMAL WERE OBSERVED. CAN CAUSE LIVER DMG, KIDNEY DMG,
CARD DMG, BLADDER DMG. SEE FOOTNOTE C. FOOTNOTE C: AS OF DATE OF
DOCUMENT ISSUANCE, THIS MATL HAS NOT BEEN LISTED BY NTP, CLASSIFIED
BY IARC NOR REGULA TED BY OSHA AS CARCIN.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVER FREE LIQUID. ABSORB RESIDUE AND DISPOSE
OF ACCORDING TO LOCAL, STATE/PROVINCIAL AND FEDERAL REQUIREMENTS.
EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE
OR WELD ON OR NEAR BY.
=================== MSDS Transport Information ===================
Transport Information:THE DATA PROVIDED IN THIS SECTION IS FOR
INFORMATION ONLY AND MAY NOT BE SPECIFIC TO YOUR PACKAGE SIZE. YOU
WILL NEED TO APPLY THE APPROPRIATE REGULATIONS TO PROPERLY CLASSIFY
YOUR SHIPMENT FOR TRANSP ORTATION. COMBUSTIBLE LIQUID, N.O.S.,
NA1993, III, NA ERG (1996): 127. CANADIAN TRANSPORTATION OF
DANGEROUS GOODS (TDG): RESIN COLUTION: CLASS 3. UN 866. PK GR III.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III: SECTION 311/312: FIRE HAZ.
REACTIVITY HAZ. IMMED HEALTH HAZ. DELAYED HEALTH HAZ. THIS PROD
CNTNS FOLLOWING TOX CHEM(S) SUBJECT TO REPORTING REQS OF SECTION
313 OF TITLE III OF SUPERFUN D AMENDMENTS & REAUTHORIZATION ACT OF
1986 & SUBPART C-SUPPLIER NOTIFICATION REQUIREMENT OF 40 CFR PART
372: METHANOL 67-56-1 3.53%, PHENOL 108-95-2 9.49%. STATE REG INFO:
NOTIFICATION REQS. PROD CNTN S FOLLOWING CHEM(S) SUBJECT TO
REPORTING REQS OF CEPA SUBSECTION 16(1), NATIONAL POLLUTANT RELEASE
INVENTORY (NPRI): METHANOL 67-56-1 3.35%, PHENOL (& ITS SALTS)
108-95-2 9.49%.
Federal Regulatory Information:THIS MATL IS "HEALTH HAZ" &/OR "PHYSICAL
HAZ" AS DETERMINED WHEN REVIEWED ACCRDG TO REQS OF OCCUP SFTY &
HLTH ADMIN 29 CFR 29 1910.1200 "HAZ COMMUNICATION" STD. TSCA
SECTION 8(B) INVENTORY: ALL REPORT ABLE CHEM SUBSTANCES ARE LISTED
ON TSCA INVENTORY. WE RELY ON CERTIFICATIONS OF COMPLIANCE FROM OUR
SUPPLIERS FOR CHEM SUBSTANCES NOT MANUFACTURER BY BORDEN. CANADIAN
REGS - WORKPLACE HAZ MATLS INFO S YS (WHMIS): PROD HAS BEEN
CLASSIFIED I/A/W HAZ CRITERIA OF CONTROLLED PRODS REG (CPR) & MSDS
CNTNS A LL INFO REQD BY CPR. CLASS D, DIV 21, 2B. CLASS B, DIV 3.
CANADIAN ENVIRONMENTAL PROT ACT (CEPA): ALL REPORTABLE ( (STATE REG
INFO)
State Regulatory Information:N/P. VENT: KEEP AIR CONTAMINANT CONC
LEVELS BELOW ACCEPTABLE CRITERIA. ENGINEERING CTLS: FOLLOWING EXPOS
CTL TECHNIQUES MAY BE USED TO EFTIVELY MINIMIZE EMPLOYEE EXPOS: LOC
EXHST VENT, ENCLOSED SYS DE SIGN, PROCESS ISOLATION & REMOVE CTL
INCOMBINATION W/APPROP USE OF PPE & PRUDENT WORK PRACTS. THESE
TECHNIQUES MAY NOT NECESSARILY ADDRESS ALL ISSUES PERTAINING TO
YOUR OPERATIONS. WE, THEREFORE, RECO M YOU CONSULT W/EXPERTS OF
YOUR CHOICE TO DETERM WHETHER OR NOT YOUR PROGRAMS ARE ADEQ. FED
REGS INF O: CHEM SUBSTANCES ARE LISTED ON DOMESTIC SUBSTANCES LIST
(DSL) OR OTHERWISE COMPLY W/CEPA NEW SUBSTANCE (SARA INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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