===================== Product Identification =====================
MSDS NAME:MS-222N AERO-DUSTER
NIIN:01-346-9144
Status Code:A
MSDS Number: CJMZF
=== Responsible Party ===
Company:MILLER-STEPHENSON CHEMICAL CO, INC
Address:GEORGE WASHINGTON HIGHWAY
City:DANBURY
State:CT
ZIP:06810
Country:US
Info Phone Num:203-743-4447
Emergency Phone Num:203-797-2212
Preparer's Name:MOURAD FAHMI
Chemtrec Ind/Phone:(800)424-9300
CAGE:18598
=== Contractor Identification ===
Company:MILLER-STEPHENSON CHEMICAL CO INC
Address:55 BACKUS AVE/GEORGE WASHINGTON HWY
Box:950
City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-743-4447
CAGE:18598
============= Composition/Information on Ingredients =============
Name:ETHANE, 1,1,1,2-TETRAFLUORO-; (HFC-134*A). AEL (DUPONT):
1000 PPM (8 & 12 HOUR TWA).
CAS:811-97-2
RTECS #:KI8842500
= Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS OF
VAPOR IS HARMFUL AND MAY CAUSE HEART IRREGULARITIES,
UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE CAN BE FATAL. VAPOR
REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR.
LIQUID CONTACT CAN CAUSE FROSTBITE. HUMAN HEALTH EFFECTS: HUMAN
HEALTH EFFECTS OF OVEREXPOSURE BY INHALATION OF VERY HIGH
CONCENTRATIONS MAY CAUSE TEMPORARY ALTERATION OF THE HEART' S
ELECTRICAL ACTIVITY WITH IRREGULAR PULSE, PALPITATIONS, OR
INADEQUATE CIRCULATION. SKIN CONTACT WITH THE LIQUID MAY CAUSE
FROSTBITE.
Explanation of Carcinogenicity:HFC-134*A IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP, OSHA OR ACGIH.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY
HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHAL:IMMED REMOVE TO FRESH AIR. KEEP PERSONS CALM. IF NOT
BREATHING GIVE ARTF RESP. IF BREATHING IS DIFFICULT GIVE OXYGEN.
CALL MD. EYES:IMMED FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. CALL MD. SKIN:FLUSH WITH WATER AFTER EXCESSIVE CONTACT.
WASH CONTAMINATED CLOTHING BEFORE REUSE. TREAT FOR FROSTBITE IF
NECESSARY BY GENTLY WARMING AFFECTED AREA. INGEST:CALL MD IMMED .
INGEST IS NO T CONSIDERED A POTENTIAL RTE OF EXPOS. NOTE TO
MD:BECAUSE OF POSSIBLE DISTURBANCES OF CARDIAC RHYTHM,
CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD BE CONSIDERED ONLY
AS A LAST RESORT TO LIFE THREA TENING EMERGENCIES.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:WILL NOT BURN
Autoignition Temp:>750.C, 1382.F
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL CANS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CANS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR. NPCA-HMIS RATINGS: HEALTH - 1;
FLAMMABILITY - 0; REACTIVITY - 1 (PERSONAL PROTECTION RATING TO BE
SUPPLIED BY USER DEPENDING ON USE CON DITIONS).
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA - ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR SOURCES OF HEAT, IN
DIRECT SUNLIGHT OR WHERE TEMPERATURES EXCEED 120F. DO NOT PUNCTURE
OR DAMAGE CONTAINERS. ROTATE STOCK TO SHELF LIFE OF ONE YEAR.
Other Precautions:USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS. HFC-134*A SHOULD NOT BE MIXED
WITH AIR FOR ANY OTHER PURPOSE ABOVE ATMOSPHERIC PRESSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL CONDITIONS, NIOSH APPROVED
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
Ventilation:NORMAL VENTILATION FOR STANDARD MANUFACTURING PROCEDURES IS
GENERALLY ADEQUATE.
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Supplemental Safety and Health
PHYSICAL/CHEMICAL DATA: VAPOR DENSITY: 3.18 (AIR=1). SOL IN H*2O: 0.15%
BY WT @ 77F & 14.7 PSIA.
================== Physical/Chemical Properties ==================
Boiling Pt:=-26.5C, -15.6F
B.P. Text:@ 736 MM HG
Vapor Pres:96 PSIA @ 77F/25C
Vapor Density:SUPP DATA
Spec Gravity:1.21 G/CC @ 77F/25C
Evaporation Rate & Reference:N/P (CC14=1)
Solubility in Water:SUPP DATA
Appearance and Odor:CLEAR, COLORLESS, LIQUIFIED GAS; SLIGHT ETHEREAL
ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:MATERIAL IS STABLE, HOWEVER, AVOID OPEN
FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:MS-222N CAN BE DECOMPOSED BY HIGH
TEMPERATURES (OPEN FLAMES, GLOWING METAL SURFACES) FORMING
HYDROFLUORIC ACID AND POSSIBLY CARBONYL FLUORINE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ANIMAL DATA: INHAL 4-HR ALC: 567,000 PPM IN
RATS. COMPOUND IS UNTESTED FOR SKIN & EYE IRRITANCY, AND IS
UNTESTED FOR ANIMAL SENSIT. NO TOXIC EFTS WERE SEEN IN ANIMALS FROM
EXPOSURES BY INHAL TO CONCS UP TO 81,000 PPM. LETHARGY & RAPID
RESPIRATION WERE OBSERVED AT VAP CONC OF 205,000 PPM & PULM
CONGESTION, EDEMA & CNS EFTS OCCURRED AT VAP CONC OF 750,000 PPM.
CARDIAC SENSIT OCCURRED IN DOGS AT 75,0 00 PPM FROM ACTION OF
EXOGENOUS EPINEPHRINE. ADVERSE EFTS WERE OBSERVED IN MALE & FEMALE
RATS FED 300 MG/KG/DAY OF HFC-134*A FOR 52 WEEKS. ANIMAL TESTING
INDICATES THAT THIS COMPOUND DOES NOT HAVE CAR CINOGENIC OR
MUTAGENIC (OTHER INFO)
===================== Ecological Information =====================
Ecological:AQUATIC TOXICITY: NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (DOT): SHIPPING INFORMATION: PROPER
SHIPPING NAME: CONSUMER COMMODITY ORM-D. DOMESTIC AIR: SHIPPING
INFORMATION: PROPER SHIPPING NAME: REFRIGERANT GAS R 134*A. HAZARD
CLASS: NON-FLAMMABLE GAS , 2.2. UN#: 3159, PKG INST 200. DOT/IATA
LABEL: NON-FLAMMABLE GAS (AUTHORIZATION - DOT-E-10232).
===================== Regulatory Information =====================
SARA Title III Information:SARA/TITLE III STATUS: REPORTED. SARA/TITLE
III HAZARD CATEGORIES AND LIST: PRODUCT HAZARD CATAGORIES: ACUTE
HEALTH - YES; CHRONIC HEALTH - NO; FIRE HAZARD - NO; REACTIVITY
HAZARD - NO; PRESSURE HAZAR D - YES. LISTS: EXTREMELY HAZARDOUS
SUBSTANCE - NO; CERCLA HAZARDOUS SUBSTANCE - NO; TOXIC CHEMICALS -
NO.
Federal Regulatory Information:TSCA INVENTORY STATUS:
REPORTED/INCLUDED.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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