===================== Product Identification =====================
MSDS NAME:8023370 4166 BLACK/WHITE
Status Code:A
MSDS Number: CJMXC
=== Responsible Party ===
Company:MARKEM CORPORATION
Address:150 CONGRESS STREET
City:KEENE
State:NH
ZIP:03431
Country:US
Info Phone Num:603-352-1130/800-424-9300
Emergency Phone Num:603-352-1130
CAGE:38360
=== Contractor Identification ===
Company:MARKEM CORPORATION
Address:150 CONGRESS STREET
Box:City:KEENE
State:NH
ZIP:03431
Country:US
Phone:603-352-1130
CAGE:38360
============= Composition/Information on Ingredients =============
Name:CASTOR OIL, HYDROGENATED
CAS:8001-78-3
RTECS #:FI4130000
Minumum % Wt:1.
Maxumum % Wt:5.
Name:GAMMA-GLYCIDOXYPROPYLTRIMETHOXYSILANE
CAS:2530-83-8
RTECS #:VV4025000
Minumum % Wt:.5
Maxumum % Wt:1.5
Name:HEXAHYDROPHTHALIC ANHYDRIDE
CAS:85-42-7
Minumum % Wt:1.
Maxumum % Wt:5.
Name:N-BUTYL ALCOHOL
CAS:71-36-3
RTECS #:EO1400000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:300 MG/M3;100 PPM
ACGIH STEL:C152 MG/M3;C50 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TRIBUTYL PHOSPHATE
CAS:126-73-8
RTECS #:TC7700000
Minumum % Wt:.5
Maxumum % Wt:1.5
OSHA PEL:5 MG/M3
ACGIH TLV:2.2 MG/M3;0.2 PPM
Name:TRIETHYL PHOSPHATE
CAS:78-40-0
RTECS #:TC7900000
Minumum % Wt:15.
Maxumum % Wt:40.
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 800-4400 MG/KG
Health Hazards Acute and Chronic:EYES: SEVERE IRRITANT.TEMPORARY VISION
IMPAIRMENT. SKIN: SEVERE IRRITATION/DERMATITIS. SENSITIZER.
INHALATION: RESPIRATORY IRRITATION. INGESTION: TOXIC. LARGE
QUANTITY OF THIS MATERIAL INGESTED MAY CA USE VISUAL DISTURBANCES.
OVEREXPOSURE MAY AFFECT THE NERVOUS SYSTEM, RESPIRATORY TRACT,
HEART, LIVER, KIDNEYS, EYES & BLADDER.
Effects of Overexposure:IRRITATION, TEARING, REDDENING OF EYES,
CLOUDY/BLURRED VISION, DEFATTING OF SKIN, DIZZINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, SHORTNESS OF BREATH,
VISUAL DISTURBANCES, ABDOMINAL D ISCOMFORT, VOMITING, DIARRHEA,
SYSTEMIC POISONING
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 20 MINS. SKIN:
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE
CPR/OXYGEN IF NECESSARY. INGESTION: EMERGENCY PERSONNEL SHOULD BE
CONTACTED IMME DIATELY & BE PROVIDED W/THIS MSDS. DRINK 2 GLASSES
OF WATER. STOMACH EVACUATION MAY BE APPROPRIATE, AS RECOMMENDED BY
MEDICAL PROFESSIONALS, ONLY IF A SIGNIFICANT QUANTITY OF THE
MATERIALS HAS BEEN IN GESTED. STOMACH EVACUATION SHOULD ONLY BE
CARRIED OUT BY TRAINED & PROPERLY EQUIPPED MEDICAL PERSONNEL.OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:=98.9C, 210.F
Autoignition Temp:=410.C, 770.F
Lower Limits:1.7
Upper Limits:10
Extinguishing Media:SMALL: DRY CHEMICALS, CO2, WATER SPRAY,
ALCOHOL-RESISTANT FOAM. LARGE: WATERSPRAY, FOG/ALCOHOL-RESISTANT
FOAM
Fire Fighting Procedures:MOVE CONTAINERS FROM FIRE AREA SAFELY W/O
RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS UNTIL FIRE IS OUT.
DON'T ENTER AREA W/O SCBA & FULL PROTECTIVE EQUIPMENT. FIGHT FIRE
FROM A SAFE & PROTECTED DISTANCE. USE WATER SPRAY/FOG FOR COOLING.
NOTIFY AUTHORITIES IF LIQUID ENTERS SEWERS/OTHER PUBLIC WATERS.
Unusual Fire/Explosion Hazard:HEAT MAY BUILD PRESSURE & RUPTURE CLOSED
CONTAINERS, SPREADING FIRE & INCREASING RISK OF BURNS/INJURIES.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNITION SOURCES;
SMOKING/FLAMES/OTHER SOURCES OF IGNITION MUST NOT BE PERMITTED IN
THE AREA. SMALL: TAKE UP W/SAND/ABSORBENT MATERIAL & PUT INTO
PROPERLY LABELED CONTAINERS FOR DISPOSAL. LAR GE: DIKE AHEAD OF
AREA TO MINIMIZE MIGRATION & VAPOR GENERATION. VENTILATE AREA.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. ISOLATE
FROM INCOMPATIBLE MATERIALS. USE ONLY IN A WELL VENTILATED AREA.
Other Precautions:AVOID CONTACT W/MATERIAL, AVOID BREATHING OF VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIR MONITORING INDICATES AIRBORNE
CONCENTRATIONS AT/ABOVE THE PEL/TLV, A RESPIRATORY PROTECTION
PROGRAM IS REQUIRED IAW/OSHA STANDARD. USE OF A RESPIRATOR MAYB E
REQUIRED WHEN USING THIS PRODUCT AT ELEVATED TEMPERATURES &
ENGINEERING CONTROLS ARE NOT ADEQUATE TO AVOID OVEREXPOSURE.
Ventilation:LOCAL EXHAUST/OTHER ENGINEERING CONTROLS ARE NORMALLY
REQUIRED WHEN HANDLING/USING THIS PRODUCT TO KEEP EXPOSURE BELOW
TLV/PEL.
Protective Gloves:SHOULD BE INSPECTED FOR CHEMICAL BREAK-THROUGH &
REPLACED IF DETECTED.
Eye Protection:RESISTANT SAFETY GLASSES W/SIDE SHIELDS/CHEMICAL SPLASH
GOGGLES/FACESHIELD
Other Protective Equipment:APRON, BOOTS, EYEWASH & SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
PERSONAL PROTECTED EQUIPMENT MUST BE EVALUATED & CIRCUMSTANCES CREATED
BY: MATERIAL SPILLED, QUANTITY, AREA IN WHICH IT OCCURED & THE
EXPERTISE OF EMPLOYEES RESPONDING. NEVER EXCEED THE OCCUPATIONAL
EXPOSURE LIMITS & CONSIDER THAT THE EVAPORATION OF SOLVENTS CAN
LEAD TO THE DISPLACEMENT OF AIR CREATING ASPHYXIATION.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:284-408F
Vapor Pres:0.1-1
Vapor Density:>1
Spec Gravity:1.1
Appearance and Odor:BLACK LIQUID W/NO ODOR
Percent Volatiles by Volume:39
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, CAUSTICS, BASES, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:ELEVATED TEMPERATURES, SPARKS, OPEN
FLAMES, OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CO, CO2, SILICON DIOXIDE,
FORMALDEHYDE, PHOSPHORUS COMPOUNDS
=================== Toxicological Information ===================
Toxicological Information:ORAL LD50 INFORMATION IS FOR N-BUTYL ALCOHOL.
===================== Ecological Information =====================
Ecological:TRIETHYL PHOSPHATE: IF RELEASED ON SOIL IT IS LIKELY TO
LEACH INTO GROUNDWATER. TRIETHYL PHOSPHATE RELEASED TO WATER WILL
NOT EVAPORATE, ABSORB STRONGLY TO SEDIMENTS/HYDROLIZE.
==================== Disposal Considerations ====================
Waste Disposal Methods:PERFORM A HAZARDOUS WASTE DETERMINATION TO
CONFIRM IF DISCARDED/SPENT PRODUCT IS LIKELY TO BE A HAZARDOUS
WASTE. DISPOSE IN A LINED LANDFILL, INCINERATE/OTHERWISE TREAT
WASTE MATERIAL. DISPOSE OF IN A CCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT & IATA: NOT RESTRICTED.
===================== Regulatory Information =====================
SARA Title III Information:THOSE INGREDIENTS APPEARING ON THE FOLLOWING
LIST THAT DO NOT APPEAR IN SECTION 2 ARE PRESENT AT <0.1% FOR
CARCINOGENS, <1% FOR OTHER HAZARDOUS SUBSTANCES/ARE NOT CONSIDERED
HAZARDOUS IN THIS PRODUCT. CERCLA REPORTABLE QUANTITIES:
FORMALDEHYDE, METHYL ALCOHOL, BIS(TRIBUTYLTIN)OXIDE. THE FOLLOWING
COMPONENTS ARE LISTED UNDER SECTION 313: FORMALDEHYDE & N-BUTYL
ALCOHOL. THE FOLLOWING COMPONENTS AR E W/HMIS WORKPLACE HAZARDOUS
MATERIALS: BIS(TRIBUTYLTIN)OXIDE, FORMALDEHYDE, METHYL ALCOHOL,
N-BUTYL ALCOHOL, TRIBUTYL PHOSPHATE.
Federal Regulatory Information:TSCA: ALL CHEMICALS IN THIS PRODUCT ARE
ON THE USEPA TSCA 8(B) INVENTORY. N-BUTYL ALCOHOL, TRIBUTYL
PHOSPHATE. RCRA: THE FOLLOWING COMPONENTS ARE SUBJECT TO RCRA LAND
DISPOSAL RESTRICTIONS: FORMALDE HYDE, METHYL ALCOHOL, N-BUTYL
ALCOHOL.
State Regulatory Information:N/P:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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