===================== Product Identification =====================
MSDS NAME:TRI-FLOW LUBRICANT-LIQUID
NIIN:01-433-0041
Status Code:A
MSDS Number: CJMYZ
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:31500 SOLON ROAD
City:SOLON
State:OH
ZIP:44139
Country:US
Info Phone Num:800-832-2541
Emergency Phone Num:216-566-2917
Resp. Party Other MSDS Num.:218-00116
Preparer's Name:JEOLO ROWONHERST
CAGE:09800
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800
============= Composition/Information on Ingredients =============
Name:PETROLEUM DISTILLATES MIXTURE (PEL & TLV AS STODDARD
SOLVENT)
Minumum % Wt:80.
Maxumum % Wt:90.
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Name:N-AMYL ACETATE
CAS:628-63-7
RTECS #:AJ1925000
Minumum % Wt:2.
Maxumum % Wt:3.
OSHA PEL:525 MG/M3;100 PPM
ACGIH TLV:532 MG/M3;100 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SULFONIC ACIDS, PETROLEUM, BARIUM SALTS
CAS:61790-48-5
Minumum % Wt:2.
Maxumum % Wt:3.
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3
Name:DIPROPYLENE GLYCOL MONOMETHYL ETHER
CAS:34590-94-8
RTECS #:JM1575000
Minumum % Wt:2.
Maxumum % Wt:3.
OSHA PEL:600 MG/M3;100 PPM
ACGIH TLV:606 MG/M3;100 PPM
ACGIH STEL:909 MG/M3;150 PPM
Name:ZINC DICYANIDE; (DIALKYPNOSPHORODIMIOIC ACID)
CAS:557-21-1
RTECS #:ZH1575000
Minumum % Wt:1.
Maxumum % Wt:2.
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: LOCAL EFFECTS (EYES, SKIN,
NOSE, THROAT, STOMACH, ETC.). MAY CAUSE SKIN IRRIT. INGEST MAY
CAUSE VOMITING, ABDOMINAL CRAMPING & DIARRHEA. SYSTEMIC EFFCTS:
ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS.
ABSORPTION OF LARGE AMOUNTS THROUGH INGESTION, INHALATION/DERMAL
CONTACT MAY CAUSE CNS DEPRESSION. SUB-CHRONIC EFFECTS: IRRITANT
CONTACT DERMATITIS. NON-CARCINOGENIC CHRONI C EFFECTS: REPORTS HAVE
ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL OVEREXP TOSOLVENT
W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS M AY BE
HARMFUL/FATAL. (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS: THIS PRODUCT CONFORMS TO CALFORNIA'S SAFE DRINKING WATER
AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65). CANCER: THIS
PRODUCT CONFORMS TO 29 CFR 19 100.1200(G)(2)(VII). THIS PRODUCT
CONFORMS TO CALIFORNIA'S SAFE DRINKING WATER AND TOXIC ENFORCEMENT
ACT OF 1986 (PROPOSITION 65). POSSIBLE TARGET ORGANS: LUNGS.
CENTRAL NERVOUS SYSTEM.
Medical Cond Aggravated by Exposure:PULMONARY DISORDERS. NEUROLOGICAL
DISORDERS.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH W/PLENTY OF WATER. REMOVE CONTACT
LENSES & CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ATTENTION IF IRRITATION DEVELOPS & PERSISTS. SKIN: REMOVE
CONTAMINATED CLOTHIN G. FLUSH AFFECTED AREA W/WATER THEN WASHW/MILD
SOAP & WATER. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS &
PERSISTS. INGESTION: IMMEDIATELY RINSE MOUTH OUT W/PLENTY OF WATER.
DO NOT INDUCE VOMITING. CALL PHYSICIAN/POISON CONTROL CENTER
IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL
ATTENTION IF BREATHING DIFFICULTY DEVELOPS. NOTES TO PHYSICIAN: FOR
ASSISTANCE W/ MEDICAL EMERGENCIES C ONTACT (210) 506-2917.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>65.6C, 150.F
Lower Limits:1.1%
Extinguishing Media:USE WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . DO NOT DIRECT A SOLID SPRAY OF WATER AT BURNING POOLS
AS SPLATTERING MAY OCCUR.
Unusual Fire/Explosion Hazard:GENERAL HAZARD: COMBUSTIBLE. KEEP AWAY
FROM ALL SOURCES OF IGNITION INCLUDING SPARKS, HEAT AND OPEN FLAME.
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON, BARIUM
COMPOUNDS, ZINC COMPOUNDS.
================== Accidental Release Measures ==================
Spill Release Procedures:FOR ASSISTANCE W/ACCIDENTAL RELS CNTCT: (216)
566-2917. GEN: DO NOT ATTEMPT TO CLEAN UP CHEM SPILLS W/OUT APPROP
PERS PROT EQUIP (SEE SECTION 8). EXTING/ REMOVE ALL IGNIT SOURCES.
USE SPARK-PROOF EQUI P. COLLECT SPILLED PROD & TRANSFER TO SEALABLE
CNTNR FOR REUSE/DISPOSAL. RINSE AREA & COLLECT W/H*2O FOR DISP.
KEEP WASTE OUT OF SEWERS, WATERSHEDS, & WATERWAYS. (SUPDAT)
====================== Handling and Storage ======================
Handling and Storage Precautions:GENERAL: KEEP AWAY FROM SPARKS, HEAT,
AND OPEN FLAME. CLOSE CONTAINER AFTER EACH USE. STORE IN A COOL
LOCATION OUT OF DIRECT SUNLIGHT. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10). USE WITH PROPER PERSONAL PROTECTIVE
EQUIPMENT (SEE SECTION 8). KEEP CONTAINERS TIGHTLY CLOSED AT ALL
TIMES.
Other Precautions:EMPTY CONTAINERS MAY RETAIN HAZARDOUS PROPERTIES,
FOLLOW ALL MSDS/LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DO
NOT REUSE EMPTY CONTAINER FOR FOOD, CLOTHING, OR PRODUCTS FOR HUMAN
OR ANIMAL CONSU MPTION. KEEP THIS AND ALL CHEMICALS OUTOF REACH OF
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL USE CNDTNS & IN PRESENCE OF ADEQ
VENT, NO RESP PROT IS NEC. IF VENT IS INADEQUATE, USE OF A NIOSH
APPRVD AIR PURIFYING RESP MAY BE NEC. SEEK PROFESSIONAL ADVICE
PRIOR TO RESP SECTIONS & U SE. FOLLOW OSHA RESP REG (20 CFR
1910.134). IF THERE IS POTENTIAL FOR AN UNCONTROLLED
RELEASE/SITUATIONS WHERE EXPOS LEVELS ARE NOT (SUPDAT).
Ventilation:ASSURE THAT VENTILATION IS ADEQUATE. USE EXPLOSION PROOF
EQUIPMENT. ASSURE THAT ALL ELECTRICAL EQUIPMENT IS GROUNDED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:USE GOOD PERS & INDUSTRIAL HYGIENE PRACTICES.
WASH THOROUGHLY AFTER USING PROD. KEEP PRODT OFF CLTHG & EQUIP.
LAUNDER CONTAMD CLTHG BEFORE RE-USE. DO NOT EAT, DRINK/SMOKE IN ANY
WORK AREA. (OTHER INFO)
Supplemental Safety and Health
SPILL PROC: SEE SECTION 13 FOR INFO ON DISP OF RECOVERY MATL.
REPORTABLE QUANTITY (RQ): N-AMY ACETATE (628-63-7); 5,000 LBS (2270
KG). RESP PROT: KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION, USE A
NIOSH POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NO DATA AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NO DATA AVAILABLE
Vapor Pres:NO DATA AVAILABLE
Volatile Org Content %:35
Spec Gravity:0.88
Viscosity:48 +/- 5.0 CPS
Solubility in Water:INSOLUBLE
Appearance and Odor:LIQUID BROWN; FRUITY ODOR.
Percent Volatiles by Volume:61.64
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. DO NOT MIX WITH OTHER MATERIALS UNLESS
SPECIFIED ON THE LABEL.
Hazardous Decomposition Products:OXIDES OF CARBON, BARIUM COMPOUNDS,
ZINC COMPOUNDS.
Conditions to Avoid Polymerization:THIS PRODUCT WILL NOT POLYMERIZE.
=================== Toxicological Information ===================
Toxicological Information:THIS SECTION PROVIDES RELEVANT INFO W/REGARD
TO TOX STUDIES PERFORMED ON EITHER PROD/"PURE" FORM OF
COMPONENT(S). THIS INFO CAN BE SUBJECT TO MISINTERPRETATION.
THEREFORE, IT IS ESSENTIAL THAT FOLLOWI NG INFO BE INTERPRETED BY
INDIVIDUALS TRAINED IN ITS EVALUATION. FOR ASSISTANCE
W/INTERPRETING THIS INFO, CNTCT (216) 566-2917. PRODUCT BASED: THIS
PROD DID NOT PRODUCE EYE IRRIT IN EXPERIMENTAL STUDI ES. SKIN
TESTING SHOWED POTENTIAL FOR SLIGHT, YET REVERSIBLE SKIN IRRIT
(PRIMARY IRRIT INDEX. 2.5) THIS PROD WAS NOT FOUND TO BE ORALLY TOX
(LD50 > 5.0 GRAM/KG) /DERMALLY TOX (LD50)>2.0 GRAMS/KG). (EC
OLOGICAL)
===================== Ecological Information =====================
Ecological:NO DATA AVAIL. TOX INFO: INGRED BASED: SKIN & EYE CNTCT
W/PETRO DISTILLATES MIX IS EXPECTED TO CAUSE MIN IRRIT W/RED &
SWELLING. INHAL OF VAPS OF PETRO DISTILLATES MIX CAN CAUSE IRRIT TO
NOSE & THROAT & NAUS. INHAL OF VERY HIGH CONC MAY CAUSE CNS
DEPRESS INCLUDING DROW, HDCHS, CONFUSN, DIZZ & INCOORD. GENERALLY;
SMALL INGEST OF PETRO DISTILLATES MIX ARE NON-TOX & PROD ONLY MIN
GI IRRIT INCL NAUS & DIARR. ASPIR OF MATL INTO LUNGS MAY CAUSE
CHEMI PNEUM WHICH IS CHARACT BY COUGHING, CHOKING, DFCLT
BREATHING, PULM EDEMA AND HEMORRHAGE. FOR MORE INFORMATION ON
TOXICOLOGICAL INFORMATION CONTACT NEC H .
==================== Disposal Considerations ====================
Waste Disposal Methods:GENERAL: CONSULT A LOCAL EXPERT FOR ADVICE ON
THE DISPOSAL OF THIS MATERIAL. CHARACTERISTICS OF RECOVERED
MATERIAL MAY DIFFER FROM THOSE OF ORGINAL MATERIAL. ENSURE THAT
DISPOSAL IS IN COMPLIANCE WITH LOCAL, STATE, AND FEDERAL
REGULATION.
=================== MSDS Transport Information ===================
Transport Information:DOT PROPER SHIPPING NAME: FLAMMABLE LIQUID,
N.O.S. (PETROLEUM DISTILLATES), 5. UN1003. III
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III (SUPERFUND AMMENDMENT AND
REAUTHORIZATION ACT): 302 EXTREMELY HAZARDOUS MATERIALS: NONE. 304:
NOTIFICATION OF ACCIDENTAL RELEASE: N-AMYL ACETATE (628-83-7).
SULFONIC ACIDS, (PETROLEUM, BARIUM SALTS (61790-48-5). ZINC
DIALKYLPHOSPHORODITHIOIC ACID (68649-42-3). 311/312 HAZARD
CATEGORIES: IMMMEDIATE (ACUTE) HEALTH EFFECTS: YES. DELAYED
(CHRONIC) HEALTH EFFECTS: YES. FIRE HAZARD: YES. SUDDEN RELEASE OF
PROCEDURE HAZARD: NO. REACTIVITLY HAZARD: NO. 313 TOXIC CHEMICAL
RELEASE REPROTING : SULFONIC ACIDS, PETROLEUM, BARIUM SALTS
(61790-48-5). ZINC DIALKYLPHOSPHORODITHIOIC ACID(68649-42 -3).
Federal Regulatory Information:CHEMICAL INVENTORIES: ALL COMPONENTS OF
THIS PRODUCT ARE INCLUDED ON THE TSCA INVENTORY LIST THE DSL/NDSL
AND EINECS. REPORTABLE QUANTITIES (RQ) N -AMYL ACETATE (628-63-7)
5.000 LBS (22/O KG).
State Regulatory Information:SINCE EACH STATE HAS THE AUTHORITY TO
PROMULGATE STANDARDS MORE STRINGENT THAN THE FEDERALGOVERN, THIS
SECTION CANNOT PROVIDE AN INCLUSIVE THAT OF ALL STATE REGULATIONS
WHICH APPLY TO THIS PRODUCT. QU ESTIONS RELATED TO STATE
REGULATIONS SHOULD BE DIRECTED TOWARD LOCAL OFFICIALS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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