===================== Product Identification =====================
MSDS NAME:SIGMAGUARD BT AQUA GREEN BASE, 5411-5674A
NIIN:01-434-2105
Status Code:A
MSDS Number: CKNLX
=== Responsible Party ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Info Phone Num:504-347-4321
Emergency Phone Num:(800)424-9300
Preparer's Name:JAY FOLSE
Chemtrec Ind/Phone:(800)424-9300
CAGE:1K005
=== Contractor Identification ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
Box:City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Phone:504-347-4321
CAGE:1K005
============= Composition/Information on Ingredients =============
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:10.
Maxumum % Wt:25.
OSHA PEL:10 MG/M3 TWA FINAL
ACGIH TLV:10 MG/M3
Name:NONYLPHENOL
CAS:25154-52-3
RTECS #:SM5600000
Minumum % Wt:1.
Maxumum % Wt:10.
Name:THIXOTROPIC AGENT
RTECS #:TS1003232
Minumum % Wt:1.
Maxumum % Wt:10.
Name:CRYSTALLINE SILICA
CAS:14808-60-7
RTECS #:VV7330000
= Wt:.43
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.1 G/M3
Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Minumum % Wt:25.
Maxumum % Wt:50.
OSHA PEL:15MG/M3
ACGIH TLV:10 MG/M3
Name:MAGNESIUM SILICATE
CAS:14807-96-6
RTECS #:WW2710000
Minumum % Wt:1.
Maxumum % Wt:10.
OSHA PEL:2 MG/M3 RESP. DUST
ACGIH TLV:2 MG/M3 RESP. DUST
Name:DIBUTYL PHTHALATE
CAS:84-74-2
RTECS #:TI0875000
= Wt:9.5
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
ACGIH STEL:2 PPM-17 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:BPA/EPH EPOXY RESIN
CAS:25068-38-6
RTECS #:CE6880000
Minumum % Wt:25.
Maxumum % Wt:50.
Name:GLYCODYL NOODECONATE
CAS:26761-45-5
RTECS #:QO7800000
Minumum % Wt:1.
Maxumum % Wt:10.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:THIS PRODUCT CAN BE IRRITATING TO THE
EYES. THIS PRODUCT MAY CAUSE IRRITATION TO THE UPPER RESPIRATORY
TRACT. THIS PRODUCT MAY CAUSE SKIN IRRITATION, ALERGIC REACTION AND
SENSITIZATION. THIS PRODUCT I S CORROSIVE TO THE EYE SKIN NOSE AND
THROAT. THIS PRODUCT CONTAINS CRYSTALLINE SILICA, WHICH IS
CONCIDERED A HAZARD BY INHALATION. CS CAN CAUSE SILICOSIS, A
NONCANCEROUS LUNG DICEASE. CRYSTALLINE SILI CA HAS NOT BEEN
CLASSIFIED A CARCINOGER, BY NTP OR OSHA.
Explanation of Carcinogenicity:IARC HAS CLASSIFIED CS AS PROVBBLY
CASCINOGENIC FOR HUMANS (2A) EPIDEMIOLOGICAL STUDIES THAT WERE
CONSIDERED LIMITED FOR CARCINOGENICITY. THIS PRODUCT CONTAINS ONE
OFRMORE REPORTED CARCINOGENS OR SUSP ECTED CARCINOGENS WHICH ARE
NOTER NTP, IARC, OR OSHA-Z IN THE OTHER LIMITS RECOMMENDED COLLUMN.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. SEEK A
PHYSICIAN IMMEDIATELY. SKIN CONTACT: FLUSH WASH WITH COPEOUS
AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. CONTACT A
PHYSICIAN IMMEDIAT ELY. INHALATION: REMOVE EXPOSED INFDVIDUAL TO
FRESH AIR. RESTORE VREATHING IF REQUIRED. CONTACT A PHYSICIAN
IMMEDIATELY. INGESTION: RINSE MOUTH IMMEDIATELY. GIVE EXPOSED
INDIVIDUAL 6-8 OUNCES OF LIQUI D. (NEVER GIVE NAYTHING BY MOUTH TO
AN UNCOUSCIOUS PERSON.) DO NOT INDUCE VOMITING UNLESS ADVICED BY A
PHYSCIAN. CONTACT A PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:=137.8C, 280.F
280F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, ALCOHOL FOAM, OR WATER
FOG.
Fire Fighting Procedures:CLEAR FIRE AREA OF UNPROTECTED PERSONELLE. DO
NOT ENTER CONFINED SPACE WITHOUT HELMET, CACE SHEILD, BUNKER COAT,
GLOVES, RUBBER BOOTS, AND A POSITIVE PRESSURE NIOSH-APPROVED
SELF-CONTAINED BREATHING A PARATUS. FIREFIGHTERS SHOULD USE
SELF-CONTAINED BREATHING APARATUS WITH FULL FACE PIECE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS CLOSED.ISOLATE FROM
HEAT,ELECTRICAL EQUIPMENT,SPARKS,&OPEN FLAMES,VAPORS MAY BE
>AIR&MAY TRAVEL ALONG THE GROUND BEFORE INGITION/FLASHING BACK TO
VAPOR SOURCE.KEEP WELDING OR CUTTING E QUIPMENT AWAY FROM PRODUCT.A
WATER STREAM CAN SCATTER FLAMES.WATER SPRAY MAY BE USED TO COOL
FIRE EXP.ED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:BE UPWIND&AWAY FROM SPILL UNLESS WEARING
APPROPRIATE PROTECTIVE EQUIPMENT.STOP&/OR CONTAIN DISCHARGE IF IT
MAY BE DONE SAFELY.KEEP ALL SOURCES OF IGNITION AWAY.VENTELATE AREA
OF SPILL.USE NONSPARKING TOOLS FOR CLEANUP.COVER W/ INERT MATERIAL
TO LOWER FUMES.KEEP OUT OF DRAINS,SEWERS&WATERWAYS.CONTACT FIRE
AUTHORIES.NOTIFY LOCAL HEALTH&POLUTION AUTHORITIES.CALL SPILL
RESPONSE TEAMS IF LARGE SPILL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OUTDOOR OR OPEN AREAS, USE (NIOSH/MSHA
APPROVED) MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID ARBORN
PARTICLAS OF OVERSPRAY DURING SPRAY APPLICATION. RESPIRATORY
PROGECTION MAY ALSO BE NECESSARY I N ANY LATER MANUFACTURING
OPPERAITONS IN WHICH THE PRODUCT MAY BECOME AIRBONN IN THE FORM OF
VAPOR OR DUST.*
Protective Gloves:GLOVES REQURESISTANT GLOVES SUCH AS NATURAL RUBBER,
NEOPTINE, BUNA-N OR NIPRIL.
Eye Protection:USE SAFETY GLASSES. AVOID CONTACT WITH EYES. WEAR
GOGGLES IF CONTACT IS POSSIBL
Work Hygienic Practices:AVOID SKIN CONTACT.
Supplemental Safety and Health
IN RESTRICTED VELTELATION ARAS, USE (NIOSH/MSHA APPOOVED)
CHEMICAL-MECHANICAL FILTERS DESIGNED TO REMO E A COMBINATION OF
PARTICULATE AND GAS VAPOR. IN FONFINED AREAS, USE (NIOSH/MSHA
APPROVED) AIRLIN E TYPE RESPIRATRS OR HOODS.
================== Physical/Chemical Properties ==================
Boiling Pt:=340.C, 644.F
B.P. Text:644F
Vapor Pres:1.0
Vapor Density:9.6
Spec Gravity:1.39
VOC Grams/Liter:.93
Viscosity:THICK LIQUID
Evaporation Rate & Reference:0.00 ETHER=1
Appearance and Odor:THICK LIQUID WITH SLIGHT ODOR.
Percent Volatiles by Volume:1.613
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
THS PRODUCT CAN REACT WITH OXIDIZING AGENTS STRONG LUOUS ACIDS
MIINIERAL ACIDS, ORGANIC BASES AND PRIMARY AND SECONDARY AMINES.
Stability Condition to Avoid:THIS PRODUCT IS STABLE BUT MAY DECOMPOSE
AT TEMPERATURES OFVR 500F YEALDING CARBON MONOXIDE, ALDEHIDES,
ACIDS, AND OTHER ORGANIC SUBASANCES.
=================== Toxicological Information ===================
Toxicological Information:LD50.. TITANIUM DIOXIDE, LD50 OVER 10000MG/KG
VIA SKIN,/RABBIT. NONYLPHENOL LD50 1.62 G/KG ORAL/RAT. THIXOTROPIC
AGENT LD50 9OVER 5 G/KG/RATS. DIBUTYL PHTHALATE LD50 8 G/KG
ORAL/RAT. BPA/EPH EPOXY RES IN LD50 5000MG/KG ORAL/RAT. NOTICE:
REPORTS HAVE A SOCIATED REPEATED AND PROLONGD OCCUPATIONAL
OXEREXPOSURE TO SOLVANTS WITH PERMANTNT BRAIN DAMAGE AND NERVOUS
SYSTEM DAMAGE. INTENTIONSA MISUSE BY DEL IBERATELY CONCENTRATING
AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
===================== Ecological Information =====================
Ecological:THIS SUBSTANCE IS CLASSIFIED AS A HAZARDOUS AIR POLUTANT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN CCORDANCE WITH APPPLICAL
LOCAL, COUNTY, AND FEDERAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS TH4E FOLLOWING
SUBATANDES SUBJECT TO THE REPORTING REQIREMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMANDMENTS AND REAUTHORIZATION ACT OF
1986 AND 40CRF PART 372: DIBUTYL PHTHALATE.
State Regulatory Information:CALIFORNIA PROPOSITION 65 REQUIRES
MANUFACTURERES TO WARN USERS OF THE PRESENCT OF CHEICALS WHICH MAY
CAUSE A "SIGNIFICANT RISK". BASED UPON THE POSSIBILITY OF THE
PRESENCE OF MINUTE AMOUNTS OF CONTAM INANTS IN ANY PAINT, SIGMA
CCOATINGS GIVES THE FOLLOWING WARNINGS: WARNING. THES PRODUCT
CINTAINS THCHEMICAL KNOWN OT THE CTATE OF CALIVORNIA TO CAUSE
CANCER. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE
CSATE OF CALIFORNI TPO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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