===================== Product Identification =====================
MSDS NAME:PLCO2-3Y,PLASMA STANDARDS,10,000 PPM OF COBALT IN 5% NITRIC
Status Code:A
MSDS Number: CKNML
=== Responsible Party ===
Company:SPEX CERTIPREP INC
Address:203 NORCROSS AVE
City:METUCHEN
State:NJ
ZIP:08840
Country:US
Info Phone Num:732-549-7144
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:PLCO2/CLCO2
Preparer's Name:SUSHA RAMANO
Chemtrec Ind/Phone:(800)424-9300
CAGE:07977
=== Contractor Identification ===
Company:SPEX CERTIPREP INC
Address:203 NORCROSS AVE
Box:City:METUCHEN
State:NJ
ZIP:08840
Country:US
Phone:732-549-7144
CAGE:04XT3
Company:SPEX CERTIPREP INC
Address:203 NORCROSS AVE
Box:City:METUCHEN
State:NJ
ZIP:08840
Country:US
Phone:732-549-7144
CAGE:07977
Company:SPEX CHEMICAL
Address:203 NORCROSS AVE
Box:City:METUCHEN
State:NJ
ZIP:08840
Country:US
Phone:908-549-7144
CAGE:IO043
============= Composition/Information on Ingredients =============
Name:NITRIC ACID; (HNO*3) EINECS 231-714-2
CAS:7697-37-2
RTECS #:QU5775000
Minumum % Wt:2.
Maxumum % Wt:5.
OSHA PEL:5 MG/M3;2 PPM
ACGIH TLV:5.2 MG/M3;2 PPM
ACGIH STEL:10 MG/M3;4 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:COBALT CARBONATE; (COCO*3) LD50: (ORAL, RAT) 640 MG/KG
CAS:513-79-1
RTECS #:FF9450050
Code:F
Minumum % Wt:.2
Maxumum % Wt:2.
ACGIH TLV:1 MG/M3 (AS CO)
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:94.
Maxumum % Wt:97.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CORROSIVE. HARMFUL BY INGESTION.
IRRITATING TO THE EYES AND SKIN UPON CONTACT.
Explanation of Carcinogenicity:COBALT CARBONATE: IARC MONOGRAPHS, VOL
52, PG 363, 1991:GROUP 2B.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:GENERAL: REMOVE CONTAMINATED CLOTHING, WASH THOROUGHLY BEFORE
REUSE. EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER AND LOW EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING
AND FLUS H WITH WATER THOROUGHLY. INHALATION: MOVE TO FRESH AIR.
CONSULT DOCTOR IF SYMPTOMS PERSIST. INGESTION: GET IMMEDIATE
MEDICAL HELP. IF THE PATIENT IS CONSCIOUS, GIVE LARGE QUANTITIES OF
WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN CAN BE RELEASED IN
CASE OF FIRE. NOT EXPLOSIVE. NOT SELF IGNITING.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. DO
NOT ALLOW TO ENTER DRAINAGE SYSTEMS OR WATER WAYS. DILUTE SPILL
WITH WATER AND NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC. WIPE UP
AND PUT INTO A SEALED CO NTAINER FOR PROPER DISPOSAL. WASH SPILL
SITE WITH WATER AFTER MATERIAL PICK UP IS COMPLETE. WEAR CHEMICAL
RESISTANT GLASSES, GLOVES AND CLOTHING.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.
====================== Handling and Storage ======================
Handling and Storage Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT
WORK PLACE. HAVE AN IMMEDIATE AVAILABILITY OF AN EYE WASH IN CASE
OF EMERGENCY. STORE AT ROOM TEMPERATURE. KEEP THE CONTAINER TIGHTLY
CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN CASE OF BRIEF EXPOSURE, USE NIOSH APPROVED
RESPIRATOR.
Ventilation:USE UNDER FUME HOOD.
Protective Gloves:ACID RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR PROTECTIVE APRON.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:IN 5% NITRIC ACID.
================== Physical/Chemical Properties ==================
Boiling Pt:=100.C, 212.F
Spec Gravity:APPROXIMATELY 1
pH:1 TO 2
Solubility in Water:MISCIBLE
Appearance and Odor:TRANSPARENT LIQUID WITH AN ACRID ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ALKALI, VARIOUS METALS AND ORGANIC SUBSTANCES.
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE AND USE.
Hazardous Decomposition Products:TOXIC FUMES UNDER CONDITIONS OF FIRE.
=================== Toxicological Information ===================
Toxicological Information:MAY PRDCE CAUSTIC EFT ON SKIN, MUC MEMBS &
EYES. SWALLOWING WILL LEAD TO STRONG CAUSTIC EFFECT ON MOUTH AND
THROAT AND TO THE DANGER OF PERFORATION OF ESPHAGUS AND STOMACH.
COBALT CARBONATE IS MODERAT ELY TOXIC BY INGESTION. MAY CAUSE
ALLERGIC REACTIONS, MAY REDUCE THYROID ACTIVITY AND IMPAIR LIVER
FUNCTIONS. IARC CANCER REVIEW: GROUP 2B. TOXICITY DATA:
CONCENTRATED HNO*3 - RTECS #QU5775000 - ORL- HMN LDLO: 430 MG/KG.
UNK-MAN LDLO: 110 MG/KG. COCO*3 - GF9600000 - IPR-RAT LDLO: 2002
MG/KG. ORL-RAT: LD50: 640 MG/KG.
===================== Ecological Information =====================
Ecological:DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER BODIES OR
SEWAGE SYSTEM.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:AIR - CLASS 8. UN/ID #3264. PACKING GROUP: III.
PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(NITRIC ACID SOLUTION). GROUND - CLASS: 8. UN/ID #3264. PACKING
GROUP: III. PROPER SHI PPING NAME: CORROSIVE LIQUID, ACIDIC,
INORGANIC, N.O.S. (NITRIC ACID SOLUTION).
===================== Regulatory Information =====================
SARA Title III Information:SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF SARA TITLE III AND OF 40 CFR 372.
Federal Regulatory Information:COMPONENTS OF THIS SOLUTION ARE REPORTED
IN EPA TSCA INVENTORY LIST WHMIS CLASSIFICATION (CANADA): CLASS E.
EC GUIDELINES: C: CORROSIVE. RISK PHRASES: 34-CAUSES BURNS. SAFETY
PHRASES: 36/37/39 - WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND
EYE/FACE PROTECTION. 26 - IN CASE OF CONTACT WITH EYES, RINSE
IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ATTENTION. 45 -
IN CASE OF ACCIDENT OR YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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