===================== Product Identification =====================
MSDS NAME:COPO ELASTOMER, TYPE 1712
Status Code:A
MSDS Number: CKNLT
=== Responsible Party ===
Company:COPOLYMER RUBBER & CHEMICAL CORP
Address:5955 SCENIC HWY
Box:2691
City:BATON ROUGE
State:LA
ZIP:70821
Country:US
Info Phone Num:504-355-5655
Emergency Phone Num:504-355-5655
Resp. Party Other MSDS Num.:CR2280 (R 9/90)
CAGE:TO546
=== Contractor Identification ===
Company:COPOLYMER RUBBER & CHEMICAL CORPORATION
Address:5955 SCENIC HIGHWAY
Box:2591
City:BATON ROUGE
State:LA
ZIP:70805
Country:US
Phone:504-355-5655
CAGE:TO546
============= Composition/Information on Ingredients =============
Name:DISPROPORTIONATED TALL OIL
CAS:68152-92-1
< Wt:5.
Name:AROMATIC PETROLEUM OIL
CAS:64742-04-7
RTECS #:PY8042500
< Wt:29.
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Name:STYRENE-BUTADIENE RUBBER (1,3-BUTADIENE, POLYMER WITH
ETHENYLBENZENE)
CAS:9003-55-8
RTECS #:WL6478000
< Wt:73.
Name:OLEIC ACID. (COMPONENT OF DISPROPORTIONATED TALL OIL)
CAS:112-80-1
RTECS #:RG2275000
Minumum % Wt:1.5
Maxumum % Wt:2.5
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50=NE; LC50=NA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SPECIFIC HAZARDS: NO ACUTE HAZARDS OR
EFFECTS ARE KNOWN. THE AROMATIC PETROLEUM OIL COMPONENTS IN THIS
PRODUCT HAS BEEN SHOWN TO PRODUCE SKIN TUMORS IN LABORATORY
ANIMALS. EYE CONTACT: NOT A PROBABLE SOURCE OF EXPOSURE.
PARTICULATES MAY SCRATCH EYE SURFACE OR CAUSE IRRITATION. SKIN
CONTACT: A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN
MATERIAL BEING ABSORBED THROUGH THE SKIN IN A HARMFUL AMOUNT.
REPEATED PROLONGED EXPOSURES MAY CAUSE SKIN IRRITATION AND INCREASE
THE RISK OF SKIN CANCER. EXPOSURE TO HOT MATERIAL MAY CAUSE THERMAL
BURNS. INGESTION: NOT A PROBABLE SOURCE OF EXPOSURE. IN HALATION:
NOT A (SYMPTOMS OF OVEREXP)
Explanation of Carcinogenicity:THE AROMATIC PETROLEUM OIL COMPONENT IN
THIS PRODUCT IS A CARCINOGEN ACCORDING TO IARC. AROMATIC PETROLEUM
OILS HAVE CAUSED SKIN TUMORS IN LAB ANIMALS ACCORDING TO IARC. THEY
CONTAIN 5% (WT) OR MORE O F POLYNUCLEAR AROMATIC SUBSTANCES WHICH
HAVE CAUSE CANCER IN LAB ANIMALS. IT IS NOT KNOWN WHETHER OR NOT
THE REPEATED PROLONGED SKIN CONTACT (SUP SFTY & HLTH)
Effects of Overexposure:HEALTH HAZARDS (CONT): PROBABLE ROUTE OF
EXPOSURE UNDER CONDITIONS OF NORMAL USE. HOT FUMES OR VAPORS WHICH
MAY FORM DURING PROCESSING CAN CAUSE IRRITATION TO THE RESPIRATORY
TRACT.
Medical Cond Aggravated by Exposure:SOME INDIVS W/ SPECIFIC
SENSITIVITIES MAY EXHIBIT EYE, NOSE, THROAT OR THERMAL IRRIT W/
PROLONGED EXP TO PROCESSING FUMES OR VAPORS. INDIVS W/ PRE-EXISTING
SKIN DISORDERS SHOULD AVOID CONT W/ THIS MAT'L
======================= First Aid Measures =======================
First Aid:EYE CONTACT: REMOVE AS FOR ANY FOREIGN OBJECT. FLUSH WITH
CLEAN WATER FOR 15 MIN. OBTAIN MEDICAL ATTENTION IF IRRITATION
PERSISTS. SKIN CONTACT: WASH W/SOAP & WATER. REMOVE CONTAM
CLOTHING. IF THERMAL IRRIT, FLUSH AFFECTED AREA WITH COLD WATER TO
DISSIPATE HEAT THEN COVER WITH CLEAN COTTON SHEETING OR GAUZE AND
GET PROMPT MEDICAL ATTENTION. INHALATION: IF FUMES/VAPORS ARE
INHALED, MOVE TO FRESH AI R, AID BREATHING IF NECESSARY. OBTAIN
MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION:UNLIKELY TO
OCCUR.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=227.C, 440.6F
FOR OIL
Autoignition Temp:=388.C, 730.4F
Autoignition Temp Text:ESTIM
Extinguishing Media:MOST FIRE EXTINGUISHING MEDIA PERMITTED-WATER
RECOMMENDED; CARBON DIOXIDE NOT RECOMMENDED.
Fire Fighting Procedures:TREAT AS HYDROCARBON FIRE. WEAR NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACESHIELD. PERSONNEL
NOT HAVING SUITABLE RESPIRATORY PROTECTION SHOULD LEAVE THE AREA TO
PREVENT EXPOSURE T O TOXIC COMBUSTION GASES.
Unusual Fire/Explosion Hazard:COMBUSTIBLE W/ THE PRESENCE OF AN
IGNITION SOURCE. IGNITION TEMP: 210C/410F. HAZARDOUS COMBUSTION
PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, PRODUCTS FROM INCOMPLETE
COMBUSTION, COMBUSTION PRODUCTS OF NITROGEN & SULFUR, ACRID FUMES
& TOXIC GASSES. SENSITIVITY TO IMPACT/SHOCK: NA. SENSITIVITY TO
STATIC DISCHARGE: NA.
================== Accidental Release Measures ==================
Spill Release Procedures:REPACKAGE UNCONTAMINATED RUBBER. REUSE OR
DIPOSE OF AS NOTED (IN WASTE DISPOSAL SECTION) IF CONTAMINATED.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE: STORE AT AMBIENT TEMPERATURE,
KEEP AWAY FROM EXCESSIVE HEAT & FLAMES & STORE IN ABSENCE OF
DIRECT, NATURAL OR ARTIFICIAL LIGHT. HANDLING: NO SPECIAL
REQUIREMENTS SPECIFIED BY MANUFACTURER (FP N).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED AT AMBIENT TEMPERATURES.
IF PROCESSING IN AREA WHERE VENTILATION IS INADEQUATE, WEAR A NIOSH
APPROVED ORGANIC VAPOR RESPIRATOR WITH MECHANICAL FILTRATION.
Ventilation:LOCAL EXHAUST VENTILATION ADEQUATE TO MEET PERMISSIBLE
CONCENTRATION IS RECOMMENDED DURING ALL HOT PROCESSING OPERATIONS.
Protective Gloves:USE GLOVES RESISTANT TO CHEMICALS AND PETROLEUM
DISTILLATES.
Eye Protection:WEAR (ANSI APPROVED - ) SAFETY GLASSES OR CHMICAL TYPE
GOGGLES.
Other Protective Equipment:EYEWASH & DELUGE SHOWER MTG ANSI DESIGN
CRITERIA . WEAR CLOTHING APPROP TO PREVENT SKIN CONTACT. WHERE CONT
MAY OCCUR W/ HOT MATERIAL. WERS THERMAL RSES GLOVES, ARM PROTECTION
& A FACE SHIELD.
Work Hygienic Practices:AVOID SKIN & EYE CONTACT. PRACTICE GOOD
PERSONAL HYGIENE. AVOID INHALATION OF FUMES OR VAPORS FROM HOT
RUBBERS, COMPOUNDS & VULCANIZATES. LAUNDER OR DRY CLEAN CLOTHING
WHEN SOILED.
Supplemental Safety and Health
ODOR THRESHOLD: NE. VOLATILES (% BY WT @ 100C): 0.75 MAX. COEFFICIENT
OF WATER/OIL DISTRIBUTION: NE. UPPER/LOWER FLAMMABLE LIMITS: NA.
UPPER/LOWER EXPLOSIVE LEVEL: NA. EXP OF CARCINOGENICITY (CON T):
OF THIS RUBBER CONTAINING THE AROMATIC PETROLEUM OIL PRESENTS A
SKIN CANCER RISK TO HUMANS.
================== Physical/Chemical Properties ==================
Spec Gravity:0.93
Solubility in Water:INSOLUBLE @ 20C
Appearance and Odor:SOLID BALES, DARK BROWNISH, SLIGHT ODOR.
Percent Volatiles by Volume:0.75 (WT)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:PRODUCT IS STABLE AT AMBIENT TEMPERATURE
AND PRESSURE. AVOID IGNITION SOURCE; PRODUCT IS COMBUSTIBLE.
Hazardous Decomposition Products:COMBUSTION PRODUCTS WILL BE CARBON
MONOXIDE, CARBON DIOXIDE, PRODUCTS FROM INCOMPLETE COMBUSTION,
COMBUSTION PRODUCTS OF NITROGEN AND SULFUR AND PRODUCTS FROM
INCOMPLETE COMBUSTION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:OLEIC ACID: LD 50 = 74 GM/KG (ORAL, RAT); LC
50 = UNKNOWN. AROMATIC OIL: LD 50 = 5 - 15 GK/KG (RAT, ORAL); LC
50 = UNKNOWN. EXPOSURE GUIDELINES: AROMATIC PETROLEUM OIL AS: OIL
MIST: OSHA PEL = 5 MG/M 3, ACGIH TLV = 5 MG/M3. PPAH & CTPV: OSHA
PEL = 0.2 MG/M3, ACGIH TLV = 0.2 MG/M3. NOTE: SPECIFIC EXPOSURE
STANDARDS FOR THIS PRODUCT AND ITS COMPONENTS HAS NOT BEEN
ESTABLISHED. THE LIMITS SHOWN ABOV E ARE SUGGESTED AS MINIMUM
CONTROL GUIDELINES. THE STANDARDS FOR PARTICULATE POLYCYCLIC
AROMATIC HYDROCARBONS (PPAH) & COAL TAR PITCH VOLATILES (CTPV) AS
BENZENE SOLUABLES ARE BASED ON COAL COKING & N OT UPON THE SPECIFIC
(ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:N/P. TOXICOLOGICAL INFO (CONT): PETROLEUM EXTRACT OIL.
THESE EXPOSURE LIMITS APPLY ONLY IF AEROSOLS ARE EMITTED FROM THIS
PRODUCT. REPRODUCTIVE EFFECTS: NONE REPORTED. TERATOGENICITY:
NONE REPORTED . MUTAGENICITY: NONE REPORTED. OTHERS: SKIN
IRRITANT. OLEIC ACID - 15 MG/3D-I (HUMAN) MODERATE, AROMATIC
PETROLEUM OIL - 3.5/8.0 (RABBIT) MODERATE.
==================== Disposal Considerations ====================
Waste Disposal Methods:REUSE IF POSSIBLE. DISPOSE OF IAW LOCAL, STATE &
FEDERAL REGULATIONS & APPLICABLE ENVIRONMENTAL REGULATIONS.
MATERIAL AS SUPPLIED IS NOT CHARACTERIZED UNDER RCRA.
=================== MSDS Transport Information ===================
Transport Information:DOT: UNITED STATES: DESIGNATION AND LABELING NOT
APPLICABLE AS PRODUCT IS NOT DEFINED OR DESIGNATED AS A HAZARDOUS
MATL BY U.S. DEPT OF TRANSPORTATION UNDER TITLE 49 OF CFR. CANADA:
NOT REGULATED UNDE R THE CANADIAN TRANSPORTATION OF DANGEROUS GOODS
REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302/304: EXTREMELY HAZARDOUS
SUBSTANCES - NONE. SECTION 311: HAZARDOUS SUBSTANCES - NOT
APPLICABLE. SECTION 313: THIS PRODUCT IS NOT SUBJECT TO REPORTING
REQUIREMENTS (SEE 40 CFR372).
Federal Regulatory Information:OSHA: AROMATIC PETROLEUM OIL, A
COMPONENT IN THIS PRODUCT, IS CARCINOGENIC ACCORDING TO HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. NOTE: OSHA 29 CFR
1910.1200 AND WHMIS (CANADA) AND MANY U.S. S TATE 'RIGHT-TO-KNOW"
LEGISLATION CONSIDERS PRODUCTS CONTAINING 0.1% BY WEIGHT OR MORE OF
AN INGREDIENT KNOWN TO BE CARCINOGENIC AS A CARCINOGEN, IF NO TEST
DATA ON THE MIXTURE IS AVAILABLE. TSCA: COM PONENTS OF THIS
PRODUCT ARE LISTED UNDER THE TSCA CHEMICAL SUBSTANCE INVENTORY.
FDA: NOT APPROVED FO R FOOD OR DIRECT FOOD CONTACT. WHMIS: THIS
PRODUCT IS CONSIDERED A CONTROLLED PRODUCT UNDER CANADA'S WORKPLACE
HAZARDOUS (STATE REGS)
State Regulatory Information:N/P. FEDERAL REGULATIONS (CONT): MATERIAL
INFORMATION SYSTEM BECAUSE IT CONTAINS OLEIC ACID AND AROMATIC
PETROLEUM OIL, COMPONENTS OF WHICH ARE KNOWN CARCINOGENS. CEPA:
COMPONENTS OF THIS PRODUCT AR E INCLUDED IN CANADA'S DSL. EEC:
AROMATIC PETROLEUM OILS ARE CONSIDERED CARCINOGENS BY EUROPEAN
ECONOMIC COMMUNITY.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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