===================== Product Identification =====================
MSDS NAME:SIGMAGUARD BT GRAY BASE, 5411A
NIIN:01-434-2085
Status Code:A
MSDS Number: CKNLV
=== Responsible Party ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Info Phone Num:504-347-4321
Emergency Phone Num:(800)424-9300
Preparer's Name:JAY FOLSE
Chemtrec Ind/Phone:(800)424-9300
CAGE:1K005
=== Contractor Identification ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
Box:City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Phone:504-347-4321
CAGE:1K005
============= Composition/Information on Ingredients =============
Name:NONYLPHENOL
CAS:25154-52-3
RTECS #:SM5600000
Minumum % Wt:1.
Maxumum % Wt:10.
Name:TRADE SECRET THIXOTROPIC AGENT
RTECS #:TS1003232
Minumum % Wt:1.
Maxumum % Wt:10.
Name:CRYSTALITE VX-S 2
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 0.616%
OSHA PEL:0.05 MG
ACGIH TLV:0.1 MG/M3
Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Minumum % Wt:25.
Maxumum % Wt:50.
OSHA PEL:5 MG
ACGIH TLV:10 MG
Name:MAGNESIUM SILICATE
CAS:14807-96-6
RTECS #:WW2710000
Minumum % Wt:1.
Maxumum % Wt:10.
OSHA PEL:2 MG
ACGIH TLV:2 MG
Name:DIBUTYL PHTHALATE
CAS:84-74-2
RTECS #:TI0875000
= Wt:9.43
OSHA PEL:5 MG
ACGIH TLV:5 MG
ACGIH STEL:2 PPM - 17 MG
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:BPA/EPH EPOXY RESIN
CAS:25068-38-6
RTECS #:CE6880000
Minumum % Wt:25.
Maxumum % Wt:50.
Name:GLYCIDYL NEODECANOATE
CAS:26761-45-5
RTECS #:QO7800000
Minumum % Wt:1.
Maxumum % Wt:10.
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:THIS PRODUCT CAN BE IRRITATING TO THE
EYES.THIS PRODUCT MAY CAUSE IRRITATION TO THE UPPER RESPIRATORY
TRACT.THIS PRODUCT MAY CAUSE SKIN IRRITATION,ALLERGIC
REACTION&SENSITIZATION.THIS PRODUCT IS CORRO SIVE TO THE
EYE,SKIN,NOSE&THROAT.THIS PRODUCT CONTAINS CRYSTALLINE SILICA,WHICH
IS CONSIDERED A HAZARD BY INHALATION.IARC HAS CLASSIFIED CS AS
PROBABLY CARCINOGENIC FOR HUMANS (2A).THIS CLASSIFICATION ON
FINDINGS OF LABORATORY ANIMAL STUDIES&DATA FROM EPIDEMIOLOGICAL
STUDIES THAT WERE CONSIDERED LIMITED FOR CARCINOGENICITY.CS CAN
CAUSE SILICOSIS,A NONCANCEROUS LUNG DISEASE.CS HAS NOT BEEN
CLASSIFI ED A CARCINOGEN BY NTP OR OSHA.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS ONE OR MORE
REPORTED CARCINOGENS OR SUSPECTED CARCINOGENS WHICH ARE NOTED NTP,
IARC OR OSHA-Z IN THE OTHER LIMITS RECOMMENDED COLUMN.
Medical Cond Aggravated by Exposure:
======================= First Aid Measures =======================
First Aid:EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. SEEK PHYSICIAN
IMMEDIATELY. SKIN CONTACT: FLUSH WASH WITH COPIOUS AMOUNTS OF
WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. CONTACT A PHYSICIAN
IMMEADE ATLY. INHALATION: REMOVE EXPOSED INDIVIDUAL TO FRESH AIR.
RESTORE BREATHING IF REQUIRED. CONTACT A PHYSICIAN IMMEDIATELY.
INGESTION: RINSE MOUTH IMMEDIATELY. GIVE EXPOSED INDIVIDUAL 6 TO 8
OUNCES OF LIQUID. (NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.) DO NOT INDUCE VOMITING UNLESS ADVISED BY A PHYSICIAN.
CONTACT A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:=137.8C, 280.F
Extinguishing Media:USE CO2, DRY CHEMICAL, FOAM, OR WATER FOG
Fire Fighting Procedures:CLEAR FIRE AREA OF UNPROTECTED PERSONNEL. DO
NOT ENTER CONFINED SPACE WITHOUT HELMET, FACE SHIELD, BUNKER COAT,
GLOVES, RUBBER BOOTS, AND A POSITIVE PRESSURE NIOSH- APPROVED SELF
CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS CLOSED.ISOLATE FROM
HEAT,ELECTRICAL EQUIPMENT,SPARKS,&OPEN FLAME.VAPORS MAY BE >AIR&MAY
TRAVEL ALONG THE GROUND BEFOR IGNITION/FLASHING BACK TO VAPOR
SOURCE.KEEP WELDING/CUTTING EQUIPM ENT AWAY FROM PRODUCT.A WATER
STREAM CAN SCATTER FLAMES.A SPRAY OF WATER MAY BE USED TO COOL FIRE
EXPOSED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:BE UPWIND&AWAY FROM SPILL UNLESS WEARING
PROTECTIVE EQUIPMENT.STOP&/OR CONTAIN DISCHARGE IF IT MAY BE DONE
SAFELY.KEEP SOURCES OF IGNITION AWAY.VENTILATE AREA OF SPILL.USE
NONSPARKING TOOLS FOR CLEANU P.COVER W/ INERT MATERIAL TO REDUCE
FUMES.KEEP OUT OF DRAINS,SEWERS,OR WATERWAYS.CONTACT FIRE
AUTHORITIES.NOTIFY LOCAL HEALTH AND POLLUTION CONTROL AGENCIES.CALL
SPILL RESPONSE TEAMS IF LARGE SPILL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OUTDOOR OR OPEN AREAS USE (NIOSH/MSHA
APPROVED) MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE
PARTICLES OF OVERSPRAY DURING SPRAY APPLICATION. IN RESTRICTED
VENTILATION AREAS USE (NIOSH/MS HA APPROVED) CHEMICAL-MECHANICAL
FILTERS DESIGNED TO REMOVE A COMBINATION OF PARTICCULATE AND GASZ
VAPOR.
Ventilation:IN CONFINED AREAS USE (NIOSH/MSHA APPROVED) AIR LINE TYPE
RESPIRATORS OR HOODS.
Protective Gloves:NATURAL RUBBER, NEOPRENE, BUNA N OR NITRILE. AN
APRON
Eye Protection:SAFETY GOGGLES
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND USING
WASHROOM.
Supplemental Safety and Health
PERSONNEL SHOULD AVOID INHALATION OF VAPORS. PERSONAL CONTACT WITH THE
PRODUCT SHOULD BE AVOIDED. SHOULD CONTACT BE MADE, REMOVE
SATURATED CLOTHING AND FLUSH AFFECTED SKIN AREAS WITH WATER.
================== Physical/Chemical Properties ==================
Boiling Pt:=340.C, 644.F
B.P. Text:644F
Vapor Pres:1
Vapor Density:9.600
Spec Gravity:1.390
VOC Grams/Liter:.51
Evaporation Rate & Reference:0.000
Appearance and Odor:THICK LIQUID/ SLIGHT ODOR
Percent Volatiles by Volume:0.953
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
THIS PRODUCT CAN REACT WITH OXIDIZING AGENTS, STRONG LEWIS ACIDS,
MINERAL ACIDS, ORGANIC BASES AND PRIMARY AND SECONDARY AMINES.
Stability Condition to Avoid:TEMPERATURES OVER 500 DG F.
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES, ACIDS AND
OTHER ORGANIC SUBSTANCES.
=================== Toxicological Information ===================
Toxicological Information:BPA/EPH EPOXY RESIN LD 50 5000MG/KG DIBUTYL
PHTHALATE LD 50 8G/KG THIXOTROPIC AGENT LD50 1.62G/KG NONYLPHENOL
LD 50 5G/KG REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED
OCCUPATIONAL OVEREXPOSURE TO SO LVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
===================== Ecological Information =====================
Ecological:THIS SUBSTANCE IS CLASSIFIED AS A HAZARDOUS AIR POLLUTANT.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS
WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS
SHEET MUST BE OBSERVED. DISPOSE OF PRODUCT IN ACCORDANCE WITH
APPLICABLE LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT: NOT REGULATED. TDG: THIS PRODUCT IS NOT FOR
SALE OR USE IN CANADA.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING
SUBSTANCES SUBJECT TO THE REPORTING REQUIRMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIXATION ACT OF
1986 AND 40 CFR PART 372: DIBUTYL PHTHALATE.
State Regulatory Information:CALIFORNIA PROPOSITION 65 REQUIRES
MANUFACTURERS TO WARN USERS OF THE PRESENCE OF CHEMICALS WHICH MAY
CAUSE A "SIGNIFICANT RISK". BASED UPON THE POSSIBILITY OF THE
PRESENCE OF MINUTE AMOUNTS OF CONTA MINANTS IN ANY PAINT, SIGMA
COATINGS GIBES THE FOLLOWING WARNINGS: THIS PRODUCT CONTAINS A
CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE ST ATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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