===================== Product Identification =====================
MSDS NAME:HYDROCHLORIC ACID 33-40%, 9544, 9548
Status Code:A
MSDS Number: CKNMD
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151
Resp. Party Other MSDS Num.:H3880
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:HYDROGEN CHLORIDE
CAS:7647-01-0
RTECS #:MW4025000
Minumum % Wt:33.
Maxumum % Wt:40.
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:60.
Maxumum % Wt:67.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: CORROSIVE! INHALATION OF
VAPORS CAN CAUSE COUGHING, CHOKING, INFLAMMATION OF THE NOSE,
THROAT AND UPPER RESPIRATORY TRACT, AND IN SEVERE CASES, PULMONARY
EDEMA, CIRCULATORY FAILURE, AND DE ATH. INGESTION: CORROSIVE!
SWALLOWING HYDROCHLORIC ACID CAN CAUSE IMMEDIATE PAIN AND BURNS OF
THE MOUTH, THROAT, ESOPHAGUS AND GI TRACT. MAY CAUSE NAUSEA,
VOMITING AND DIARRHEA. SWALLOWING MAY BE FATA L. SKIN CONTACT:
CORROSIVE! CAN CAUSE REDNESS, PAIN AND SEVERE SKIN BURNS.
CONCENTRATED SOLUTIONS CAUSE DEEP ULCERS AND DISCOLOR SKIN. EYE
CONTACT: CORROSIVE! VAPORS ARE IRRITATING AND MAY CAUSE DAMAG E TO
THE EYES. (EFFECTS OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: CONTACT MAY CAUSE SEVERE BURNS
AND PERMANENT EYE DAMAGE. CHRONIC EXPOSURE: LONG-TERM EXPOSURE TO
CONCENTRATED VAPORS MAY CAUSE EROSION OF TEETH. LONG TERM EXPOSURES
SELDOM OCCUR DUE TO THE CORROSIVE PROPERTIES OF THE ACID.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF
THIS SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED ATTN
IMMED. INGEST: DO NOT INDUCE VOMITING! GIVE LARGE QUANTITIES OF
WATER OR MILK IF AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCON PERSON. GET MED ATTN IMMED. SKIN CONTACT: IN CASE OF CONTACT,
IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CON TAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. THOROUGHLY
CLEAN SHOES BEFORE REUSE. GET MED ATTN IMMED. EYE CONTACT: IMMED
FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER
AND UPPER EY ELIDS OCCASIONALLY. GET MED ATTN IMMED.
===================== Fire Fighting Measures =====================
Extinguishing Media:IF INVOLVED IN A FIRE, USE WATER SPRAY. NEUTRALIZE
WITH SODA ASH OR SLAKED LIME.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . STRUCTURAL FIREFIGHTER'S PROTECTIVE CLOTHING IS
INEFFECTIVE FOR FIRES INVOLVING HYDROCHLORIC ACID. STAY AWAY FROM
ENDS OF TANKS. COOL TANK S WITH WATER SPRAY UNTIL WELL AFTER FIRE
IS OUT.
Unusual Fire/Explosion Hazard:EXTREME HEAT OR CONTACT WITH METALS CAN
RELEASE FLAMMABLE HYDROGEN GAS. NOT CONSIDERED TO BE AN EXPLOSION
HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA OF LEAK OR SPILL. WEAR APPROP
PERSONAL PROT EQUIP AS SPECIFIED IN EXPOS CTLS/PERSONAL PROT.
ISOLATE HAZ AREA. KEEP UNNECESSARY & UNPROTECTED PERS FROM
ENTERING. CONTAIN & RECOVER LIQ WHEN PO SSIBLE. NEUT W/ALKALINE
MATL (SODA ASH, LIME), THEN ABSORB W/INERT MATL (EG, VERMICULITE,
DRY SAND, EARTH), & PLACE IN A CHEM WASTE CNTNR. DO NOT USE COMBUST
MATLS, SUCH AS SAWDUST. (SUPDAT)
Neutralizing Agent:NEUTRALIZE WITH ALKALINE MATERIAL (SODA ASH, LIME),
THEN ABSORB WITH AN INERT MATERIAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, VENTD STORAGE
AREA W/ACID RESISTANT FLOORS & GOOD DRAINAGE. PROTECT FROM PHYSICAL
DMG. KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT, WATER & INCOMPAT
MATLS. DO NOT WASH OUT CNTNR & USE IT FOR OTHER PURPOSES. WHEN
DILUTING, ACID SHOULD ALWAYS BE ADDED (TOXICOLOGICAL INFO)
Other Precautions:WHEN OPENING METAL CONTAINERS, USE NON-SPARKING TOOLS
BECAUSE OF THE POSSIBILITY OF HYDROGEN GAS BEING PRESENT.
CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY
RETAIN PRODUCT RESIDU ES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND
PRECAUTIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD
FULL FACEPIECE RESP W/AN ACID GAS CARTRIDGE MAY BE WORN UP TO 50
TIMES THE EXPOS LIMIT OR MAXIMUM USE CONCENTRATION SPECIFIED BY THE
APPROP REGULATORY AG ENCY OR RESP SUPPLIER, WHICHEVER IS LOWEST.
FOR EMERGENCIES OR INSTANCES WHERE THE EXPOS LEVELS ARE NOT KNOWN,
USE A NIOSH APPRVD (ECOLOGICAL INFO)
Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOM TO KEEP
EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOCAL EXHAUST VENT IS
GENERALLY PREFERRED (ECOLOGICAL INFO)
Protective Gloves:RUBBER OR NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . ADDITIONAL PROTECTION INCLUDING IMPERVIOUS BOOTS, APRON
OR COVERALLS, AS NEEDED IN AREA OF UNUSUAL EXPOSURE TO PREVENT SKIN
CONTACT.
Supplemental Safety and Health
SPILL PROC: DO NOT FLUSH TO SEWER! US REGS (CERCLA) REQUIRE REPORTING
SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF REPORTABLE
QTYS. TOLL FREE NUMBER FOR US COAST GUARD NRC IS 1-800-424-8802. JT
BAKER NEUTRASORB(TM) OR TEAM(TM) 'LOW NA+' ACID NEUTRALIZERS ARE
RECOM FOR SPILLS OF THIS PRODUCT.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:(TRANSPORT INFO)
Melt/Freeze Pt:=-74.C, -101.2F
Vapor Pres:190 @ 25C(77F)
Spec Gravity:1.18
pH:(TRANSPORT INF)
Evaporation Rate & Reference:NO INFO FOUND
Solubility in Water:(TRANSPORT INFO)
Appearance and Odor:COLORLESS, FUMING LIQUID; PUNGENT ODOR OF HYDROGEN
CHLORIDE.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACID, CONC HYDROCHLORIC ACID IS INCOMPAT W/MANY
SUBSTANCES & HIGHLY REACTIVE W/STRONG BASES, METALS, METAL OXIDES,
HYDROXIDES, AMINES, CARBONATES & OTHER ALKALINE MATLS. INCOMPAT
W/MATLS SUCH AS CYANIDES,SULF
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. CONTAINERS MAY BURST WHEN HEATED.
Hazardous Decomposition Products:WHEN HEATED TO DECOMP, EMITS TOX
HYDROGEN CHLORIDE FUMES & WILL REACT W/WATER OR STEAM TO PRDCE HEAT
& TOX & CORR FUMES. THERMAL OXIDATIVE DECOMP PRODUCES TOXIC
CHLORINE FUMES & EXPLOSIVE HYDROGEN GAS.
=================== Toxicological Information ===================
Toxicological Information:INHAL RAT LC50: 3124 PPM/1H; ORAL RABBIT
LD50: 900 MG/KG (HYDROCHLORIC ACID CONCENTRATED); INVESTIGATED AS A
TUMORIGEN, MUTAGEN, REPRODUCTIVE EFFECTOR. CANCER LISTS - HYDROGEN
CHLORIDE (7647-01-0) NTP CARCINOGEN - KNOWN: NO, ANTICIPATED: NO;
IARC CATEGORY: 3. WATER (7732-18-5) NTP CARCINOGEN - KNOWN: NO,
ANTICIPATED: NO; IARC CATEGORY: NONE. HNDLG/STOR PRECS: SLOWLY TO
WATER & IN SMALL AMTS. NEVER USE HOT WATER & NEVER ADD WATER TO
ACID. WATER ADDED TO ACID CAN CAUSE UNCONTROLLED BOILING &
SPLASHING.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO THE SOIL, THIS MATL
IS NOT EXPECTED TO BIODEGRADE. WHEN RELEASED INTO THE SOIL, THIS
MATL MAY LEACH INTO GROUNDWATER. ENVIRONMENTAL TOXICITY: THIS MATL
IS EXPECT ED TO BE TOXIC TO AQUATIC LIFE. RESP PROT:
FULL-FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESP. WARNING: AIR
PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT
ATMOSPHERES. VENT: BECAUSE IT C AN CONTROL EMISSIONS OF CONTAMINANT
AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA.
PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF
RECOMMENDED PRACTICES, MOST RECEN T EDITION, FOR DETAILS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD
WASTE FACILITY. PROCESSING, USE OR CONTAIM OF PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISP REGS MAY DIFFER FROM FED
DISP REGS. DISPOSE OF CNTNR & UNUSED CONTENTS I/A/W FED, STATE &
LOCAL REQS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC (LAND, DOT) - PROPER SHIPPING NAME:
HYDROCHLORIC ACID. HAZ CLASS: 8. UN/NA: UN1789. PACKING GROUP: II.
INFO REPORTED FOR PROD/SIZE: 475LB. INTERNATIONAL (WATER, IMO) -
PROPER SHIPPING NAME: H YDROCHLORIC ACID. HAZ CLASS: 8. UN/NA:
UN1789. PACKING GROUP: II. INFO REPORTED FOR PROD/SIZE: 475LB.
PHYSICAL DATA - BP: 53C(127F) AZEOTROPE (20.2%) BOILS AT
109C(228F). PH: FOR HCL SOLUTIONS: 0.1 (1 .0N), 1.1 (0.1N), 2.02
(0.01 N). SOLUBILITY IN H*2O: INFINITE IN WATER W/SLIGHT EVOLUTION
OF HEAT.
===================== Regulatory Information =====================
SARA Title III Information:FEDERAL, STATE & INTERNATIONAL REGULATIONS -
PART 1- SARA 302: HYDROGEN CHLORIDE (7647-01-0): RQ 5000; TPQ 500.
SARA 313: LIST-YES; CHEMICAL CATG-NO. SARA 313: WATER (7732-18-5):
RQ-NO; TPQ-NO. SARA 3 13: LIST-NO; CHEMICAL CATG-NO. SARA 311/312;
ACUTE: YES. CHRONIC: YES. FIRE: NO. PRESSURE: NO. REACTIVITY: NO.
(MIXTURE/LIQUID). FED REG INFO: WHMIS: THIS MSDS HAS BEEN PREPARED
ACCORDING TO HAZARD CR ITERIAL OF THE CONTROLLED PRODS REGS (CPR) &
THE MSDS CONTAINS ALL OF THE INFO REQUIRED BY THE CPR.
Federal Regulatory Information:CHEMICAL INVENTORY STATUS - PART 1 -
HYDROGEN CHLORIDE (7647-01-0): TSCA-YES. EC-YES. JAPAN-YES.
AUSTRALIA-YES. WATER (7732-18-1): TSCA-YES. EC-YES. JAPAN-YES.
AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2 - HYDROGEN
CHLORIDE (7647-01-0): KOREA-YES. DSL-YES. NDSL-YES. PHIL-YES. WATER
(7732-18-5): KOREA-YES. DSL-YES. NDSL-NO. PHIL-YES. FED, STATE &
INTERNATL REGS - PART 2 - HYDROGEN CHLORIDE: C ERCLA-5000. RCRA
261.33-NO. TSCA 8(D)-NO. WATER: CERCLA-NO. RCRA 261.33-NO. TSCA
8(D)-NO. CHEM WEAPO NS CONVENTION:NO. TSCA 12(B): NO. CDTA: YES.
ASUTRALIAN HAZCHEM CODE: 24. POISON SCHEDULE: NO INFO FOUND. (SARA
REG INFO)
State Regulatory Information:N/P. OTHER INFO: GIVE ANYTHING BY MOUTH TO
AN UNCON PERSON. IF INHALED, REMOVE TO FRESH AIR. IF NOT BRTHG,
GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. IN ALL CASES GET
MED ATTN IMMED. PROD USE: LA BORATORY REAGENT. REVISION INFO: NEW
16 SECTION MSDS FORMAT, ALL SECTIONS HAVE BEEN REVISED. JT BAKER
SAF-T-DATA RATINGS (PROVIDED FOR YOUR CONVENIENCE) - HEALTH RATING:
3 - SEVERE (POISON). FLAMMABIL ITY RATING: 0 - NONE. REACTIVITY
RATING: 2 - MODERATE. CONTACT RATING: 3 - SEVERE (CORROSIVE). LAB P
ROT EQUIP: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER
GLOVES. STORAGE COLOR CODE: WHITE (CORROSIVE).
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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