===================== Product Identification =====================
MSDS NAME:CONATHANE CE-1164 URETHANE PREPOLYMER
NIIN:00-935-4941
Status Code:A
MSDS Number: CLQPP
=== Responsible Party ===
Company:CYTEC INDUSTRIES INC
Address:FIVE GARRET MOUNTAIN PLAZA
City:WEST PATERSON
State:NJ
ZIP:07424
Country:US
Info Phone Num:800-652-6013
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:MSDS NO: 06152
Preparer's Name:RANDY DESKIN, PHD, DABT
Chemtrec Ind/Phone:(800)424-9300
CAGE:0V7G8
=== Contractor Identification ===
Company:CYTEC INDUSTRIES INC
Address:FIVE GARRET MOUNTAIN PLAZA
Box:City:WEST PATERSON
State:NJ
ZIP:07424
Country:US
Phone:800-652-6013
CAGE:0V7G8
Company:THE SMITH GROUP INC.
Address:811 E. CAYUGA STREET
Box:City:PHILADELPHIA
State:PA
ZIP:19124-3893
Country:US
Phone:215-743-8200
Contract Num:SP0430-02-M-Q109
CAGE:2B613
============= Composition/Information on Ingredients =============
Name:1-METHOXY-2-PROPANOL ACETATE (2-PROPANOL, 1-METHOXY-,
ACETATE)
CAS:108-65-6
RTECS #:AI8925000
< Wt:25.
Other REC Limits:NOT PROVIDED
Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
< Wt:13.
Other REC Limits:NOT PROVIDED
OSHA PEL:200 PPM
OSHA STEL:C 300 PPM
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENE
CAS:1330-20-7
RTECS #:ZE2100000
< Wt:10.
Other REC Limits:NOT PROVIDED
OSHA PEL:100 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYLBENZENE
CAS:100-41-4
RTECS #:DA0700000
< Wt:3.
Other REC Limits:NOT PROVIDED
OSHA PEL:435 MG/M3;100 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:543 MG/M3;125 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TOLUENE DIISOCYANATE
CAS:26471-62-5
RTECS #:NQ9490000
< Wt:3.
Other REC Limits:NOT PROVIDED
OSHA PEL:CEILING 0.02 PPM
ACGIH TLV:0.005 PPM
ACGIH STEL:0.02 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:EST. ORAL RAT LD50: > 4,000 MG/KG
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:DIRECT CONTACT WITH THIS MATERIAL MAY
CAUSE MODERATE EYE AND SKIN IRRITATION. INHALATION OVEREXPOSURE MAY
CAUSE IRRITATION OF THE RESPIRATORY TRACT AND EYES. MAY CAUSE
ALLERGIC RESPIRATORY REACTION. R EPEATED OR PROLONGED DERMAL
CONTACT WITH THIS MATERIAL MAY CAUSE ALLERGIC SKIN REACTIONS.
CHRONIC HAZARD WARNING: CHRONIC TOXICITY HAZARD. CONTAINS TDI WHICH
MAY CAUSE RESPIRATORY SYSTEM DAMAGE.
Explanation of Carcinogenicity:IARC -2B: TOLUENE DIISOCYANATE : THE
AGENT IS POSSIBLY CANCINOGENIC TO HUMANS. NTP-2: TOLUENE
DIISOCYANATE: THE SUBSTANCE MAY REASONABLY BE ANTICIPATED TO BE
CARCINOGENS.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, ALERGIC
SKIN REACTION. INHALATION: ALLERGIC RESPIRATORY REACTION,
IRRITATION OF RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IRRIGATE WITH WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION IF IRRITATION PERSISTS. SKIN CONTACT: WASH AFFECTED
AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
OBTAIN ME DICAL ATTENTION. DESTROY OR THOROUGHLY CLEAN SHOES AND
LAUNDER CLOTHING BEFORE REUSE. INHALATION: MOVE FROM EXPOSURE. GIVE
OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF
PERSON NOT B REATHING. GET MEDICAL ATTENTION. INGESTION: IF
SWALLOWED, CALL PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITING AS
DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>7.2C, 45.F
Autoignition Temp:Autoignition Temp Text:N/AV
Lower Limits:N/AV
Upper Limits:N/AV
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY, OR
ALCOHOL FOAM TO EXTINGUISH FIRES. IF WATER SPRAY OR ALCOHOL FOAM IS
USED, IT SHOULD BE IN LARGE QUANTITIES.
Fire Fighting Procedures:USE WATER TO KEEP FIRE-EXPOSED CONTAINERS
COOL. WEAR SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS
AND FULL FIREFIGHTING PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:WATER OR ALCOHOL FOAM MAY REACT
VIGOROUSLY WITH HOT ISOCYANATE RELEASING CARBON DIOXIDE. DO NOT
RESEAL CONTAMINATED CONTAINERS SINCE PRESSURE BUILD-UP MAY CAUSE
RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. IF EXPOSURE LEVEL
NOT KNOWN, WEAR NIOSH APPROVED, POSITIVE PRESSURE, SELF-CONTAINED
RESPIRATOR. IF EXPOSURE LEVEL KNOWN, WEAR NIOSH APPROVED RESPIRATOR
SUITABLE FOR LEVEL O F EXPOSURE. IN ADDITION TO PROTECTIVE
CLOTHING/EQUIPMENT, WEAR IMPERVIOUS BOOTS. COVER SPILLS WITH INERT
ABSORBENT MATERIAL; SWEEP UP AND PLACE IN WASTE DISPOSAL CONTAINER.
FLUSH AREA WITH WATER.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND FLAME.
AVOID BREATHING VAPOR. AVOID PROLONGED OR REPEATED CONTACT WITH
SKIN. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. DO NOT ALLOW WATER OR OTHER LIQUIDS TO
GET INTO CONTAINER.
Other Precautions:AREAS CONTAINING THIS MATERIAL SHOULD HAVE FIRE-SAFE
PRACTICES AND ELECTRICAL EQUIPMENT IN ACCORDANCE WITH ELECTRICAL
AND FIRE PROTECTION CODES (NFPA-30) GOVERNING CLASS 1 FLAMMABLE
LIQUIDS AND OSHA I NSTRUCTION STD 1-5.14A AND STATE AND LOCAL
REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE EXPOSURES EXCEED THE PEL, USE RESPIRATOR
APPROVED BY NIOSH FOR THE MATERIAL AND LEVEL OF EXPOSURE. WHERE
EXPOSURES ARE BELOW THE PERMISSIBLE EXPOSURE LIMIT (PEL), NO
RESPIRATORY PROTECTION IS RE QUIRED.
Ventilation:WHERE THIS MATERIAL IS NOT USED IN A CLOSED SYSTEM, GOOD
ENCLOSED EXHAUST VENTILATION SHOULD BE PROVIDED TO CONTROL
EXPOSURE.
Protective Gloves:IMPERVIOUS GLOVES ARE RECOMMENDED TO PREVENT SKIN
CONTACT.
Eye Protection:WEAR CHEMICAL SPLASH PROOF GOGGLES OR FACE-SHIELD FOR
SPLASHING OPERATIONS.
Other Protective Equipment:EYEWASH AND SAFETY SHOWER SHOULD BE
PROVIDED. PROTECTIVE CLOTHING SUCH AS IMPERVIOUS GLOVES, APRON,
WORKPANTS, LONG SLEEVE WORK SHIRT, OR DISPOSABLE COVERALLS
RECOMMENDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:FOOD, BEVERAGES, AND TOBACCO PRODUCTS SHOULD
NOT BE CARRIED, STORED, OR CONSUMED WHERE THIS MATERIAL IS IN USE.
BEFORE EATING, DRINKING, OR SMOKING, WASH FACE AND HANDS WITH SOAP
AND WATER.
Supplemental Safety and Health
AVOID SKIN CONTACT. RECOMMENDED THAT SHOWER BE TAKEN AFTER COMPLETION
OF WORKSHIFT ESPECIALLY IF SIGNIFICANT CONTACT HAS OCCURRED.
LAUNDER WORK CLOTHING PRIOR TO REUSE. STREET CLOTHING SHOULD BE
STORE D SEPARATELY FROM WORK CLOTHING AND PROTECTIVE EQUIPMENT.
WORK CLOTHING AND SHOES SHOULD NOT BE TAKEN HOME.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:NOT AVAILABLE
Vapor Density:N/AV
Spec Gravity:1.03
pH:NOT AVAILABLE
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:< 1
Solubility in Water:REACTS WITH WATER.
Appearance and Odor:LOW VISCOSITY AMBER LIQUID, CHARACTERISTIC ODOR.
Percent Volatiles by Volume:50% BY WT.
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, OR AMINES, OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CYANIDE,
OXIDES OF NITROGEN, AND/OR TDI.
Conditions to Avoid Polymerization:AVOID CONTACT WITH OXIDIZING AGENTS.
=================== Toxicological Information ===================
Toxicological Information:1-METHOXY-2-PROPANOL ACETATE HAS ACUTE ORAL
(RAT) AND DERMAL (RABBIT) LD50 VALUES OF 8532 MG/KG AND >5000
MG/KG, RESPECTIVELY. TOLUENE HAS ACUTE ORAL (RAT) AND DERMAL
(RABBIT) LD50 VALUES OF 5580 MG/K G AND 12124 MG/KG, RESPECTIVELY.
THE ACUTE 4-HOUR INHALATION (RAT, FEMALE) LC50 VALUE IS 5060 PPM
(19.7 MG/L). XYLENE HAS AN ACUTE ORAL (RAT) OF 4.3 G/KG AND AN
ACUTE 4-HOUR LC50 (RAT) OF 21.7 MG/L. E THYLBENZENE HAS ORAL (RAT)
AND DERMAL (RABBIT) LD50 VALUES OF 3500 MG/KG AND 5000 MG/KG,
RESPECTIVELY. THE 4-HOUR INH LC50 IN RATS IS 4000 PPM (17.36 MG/L).
ORAL LD50 OF TOLUENE DIISOCYANATE IN RAT IS 5.8-6.2 G/KG AND LC50
4-HR IS 14PPM.
===================== Ecological Information =====================
Ecological:NO AQUATIC LC50, BOD, OR COD DATA AVAILABLE. THE FOLLOWING
COMPONENTS MAY BE SUBJECT TO REPORTING REQUIREMENTS PURSUANT TO SEC
313 OF CERCLA (40 CFR 372), SECTION 12(B) OF TSCA, OR MAY BE
SUBJECT TO R ELEASE REPORTING REQUIREMENTS (40 CF R 307, 40 CFR
311, ETC). SEE SECTION 13 OF MSDS FOR INFORMATION ON WASTE
CLASSIFICATION AND WASTE DISPOSAL OF THIS PRODUCT. TOLUENE:
TPQ(LBS)= NONE; RQ(LBS)= 1,000 ; S313 = YES; TSCA 12B= NO. XYLENE:
TPQ= NONE; RQ(LBS)= 100; S 313= YES; TSCA 12B= NO. ETHYLBENZENE:
TPQ=NONE; RQ= 1,000; S313= YES; TSCA 12B= NO.TOLUENE
DIISOCYANATE: TPQ= 500 LBS; RQ= 100 LBS; S31 3= YES; TSCA 12B= N
==================== Disposal Considerations ====================
Waste Disposal Methods:CYTEC ENCOURAGES RECYCLE, RECOVERY, AND REUSE OF
MATERIALS, AS AN ALTERNATE TO DISPOSAL AS A WASTE. CYTEC RECOMMENDS
THAT ORGANIC MATERIALS CLASSIFIED AS RCRA HAZARDOUS WASTES BE
DISPOSED OF BY THERMA L TREATMENT OR INCINERATION AT EPA APPROVED
FACILITIES. PERSON GENERATING THE WASTE IS RESPONSIBLE F OR
DETERMINING DISPOSAL METHOD.
=================== MSDS Transport Information ===================
Transport Information:D.O.T. PSN: FLAMMABLE LIQUID, N.O.S(TOLUENE &
XYLENE).; CLASS: 3; PKG: I I; UN 1993; REPORTABLE QUANTITY: TOLUENE
DIISOCYANATE = 3,333 LBS, ETHYL BENZENE= 33,333 LBS,
TOLUENE/XYLENE= 7,692/1,000 LBS; LABEL: FLAMMABLE LIQUID. IMO:
PSN:FLAMMABLE LIQUID, N.O .S., CLASS: 3.2; PKG:II; UN 1993; IMDG
PAGE 3230; LABEL:FLAMMABLE LIQUID. ICAO/IATA: PSN: FLAMMABLE
LIQUID, N.O.S.; CLASS: 3; UN 1993; PKG: I I; LABEL: FLAMMABLE
LIQUID; PACKING INSTR: PASS.= 305, CARGO= 307; MAX NET QTY: PASS.=
5L, CARG O= 60L.
===================== Regulatory Information =====================
SARA Title III Information:PRODUCT CLASSIFICATION UNDER SECTION 311 OF
SARA: ACUTE: YES; CHRONIC: YES; FIRE: YES; REACTIVE: NO; PRESSURE:
NO. ALL COMPONENTS OF THIS PRODUCT ARE SUBJECT TO THE REPORTING
REQUIREMENTS PUSUENT TO S EC 313 OF CERCLA (40 CFR 372). TPQ OF
TDI= 500 LBS.
Federal Regulatory Information:TSCA INVENTORY: ALL OF THE INGREDIENTS
ARE LISTED ON THE TSCA INVENTORY.
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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