===================== Product Identification =====================
MSDS NAME:C26666, LAYOUT DYE, BLUE (SEE SUPPL)
NIIN:01-015-0834
Status Code:A
MSDS Number: CLQPY
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVENUE N.W.
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:800-832-2541
Emergency Phone Num:216-566-2917
Preparer's Name:NOT PROVIDED
CAGE:1LBR4
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVENUE N.W.
Box:City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:216-566-2917; 216-566-2902
CAGE:1LBR4
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
Contract Num:SP0414-02-M-1495
CAGE:09800
============= Composition/Information on Ingredients =============
Name:ETHYL 3-ETHOXYPROPIONATE
CAS:763-69-9
RTECS #:UF3325000
= Wt:2.
Other REC Limits:NOT PROVIDED
Name:METHYL ISOBUTYL KETONE
CAS:108-10-1
RTECS #:SA9275000
= Wt:5.
Other REC Limits:NOT PROVIDED
OSHA PEL:50 PPM
OSHA STEL:75 PPM
ACGIH TLV:205 MG/M3;50 PPM
ACGIH STEL:307 MG/M3;75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2-PROPANOL
CAS:67-63-0
RTECS #:NT8050000
= Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:980 MG/M3;400 PPM
OSHA STEL:500 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
Name:ETHYLBENZENE
CAS:100-41-4
RTECS #:DA0700000
= Wt:.5
Other REC Limits:NOT PROVIDED
OSHA PEL:435 MG/M3;100 PPM
OSHA STEL:125 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:543 MG/M3;125 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENE
CAS:1330-20-7
RTECS #:ZE2100000
= Wt:3.
Other REC Limits:NOT PROVIDED
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
= Wt:18.
Other REC Limits:NOT PROVIDED
OSHA PEL:1800 MG/M3;1000 PPM
ACGIH TLV:2500 PPM
Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:14.
Other REC Limits:NOT PROVIDED
OSHA PEL:100 PPM (SKIN)
OSHA STEL:150 PPM (SKIN)
ACGIH TLV:50 PPM (SKIN)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:1-BUTANOL
CAS:71-36-3
RTECS #:EO1400000
= Wt:2.
Other REC Limits:NOT PROVIDED
OSHA PEL:50 PPM(SKIN)CEILING
ACGIH TLV:50 PPM (SKIN)CEILING
ACGIH STEL:C152 MG/M3;C50 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 48%
Other REC Limits:NOT PROVIDED
OSHA PEL:590 MG/M3;200 PPM
OSHA STEL:300 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: IRRITATION OF
EYES, SKIN, AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM
DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND
POSSIBLY DEATH.
Explanation of Carcinogenicity:ETHYLBENZENE IS CLASSIFIED BY IARC AS
POSSIBLE CARCINOGENIC TO HUMANS (2B) BASED ON INADEQUATE EVIDENCE
IN HUMANS AND SUFFICIENT EVIDENCE IN LABORATORY ANIMALS. THERE IS
NO EVIDENCE THAT ETHYLBENZENE CAUSES CANCER IN HUMANS.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION ARE INDICTIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN CONTACT: WASH AFFECTED AREA
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. GET
MEDICAL ATTENTION. INGESTION: IF SWALLOWED DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:=-17.6C, 0.F
PROPELLANT
Lower Limits:1.0
Upper Limits:12.7
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF
CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE
INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS, FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. APPLICATION TO HOT SURFACE REQUIRES SPECIAL
PRECAUTIONS. DURING EMERGENCIES OVEREXP OSURE TO DECOMPOSITION
PRODUCTS MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY
APPARENT, GET MEDICAL ATTENTION
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID HEAT, SPARKS, FLAMES. VAPORS
WILL ACCUMULATE AND IGNITE EXPLOSIVELY. DURING USE AND UNTIL ALL
VAPORS ARE GONE: KEEP AREA VENTILATED, DO NOT SMOKE, EXTINGUISH ALL
FLAMES, PILOT LIGHTS, HEATERS. TURN OFF STOVES, ELECTRIC TOOLS AND
APPLIANCES, OTHER IGNITION SOURCES.
Other Precautions:CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING
PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE,
OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS,
STOVES, HOT WATER, AND OTHER SOURCES COULD CAUSE CONTAINER TO
BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH O F CHILDREN
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION; WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST MATERIALS IN I NGREDIENTS.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE IS BELOW EXPOSURE LIMITS.
Protective Gloves:NONE REQUIRED FOR NORMAL USE. WEAR CHEMICAL RESISTANT
GLOVES FOR LONG CONTACT.
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Other Protective Equipment:USE ONLY WITH ADEQUATE VENTILATION. WASH
HANDS AFTER USING.
Work Hygienic Practices:INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING CONTENTS CAN BE HARMFUL OR FATAL. USE
ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY
MIST.AVOID CONTACT WITH SKIN AND EYES.
Supplemental Safety and Health
PART NUMBER FOR CONTRACTOR: 51969. ABBREVIATION: N/A = NOT
APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT
PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT
ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM.
================== Physical/Chemical Properties ==================
HCC:V3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:<-17.6C, 0.F
B.P. Text:<0- 342F;<-18- 172C
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:NOT PROVIDED
Vapor Density:>AIR
Spec Gravity:0.76 (6.28 LB/GAL)
VOC Grams/Liter:5.94
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:FASTER THAN ETHER.
Solubility in Water:NOT AVAILABLE
Appearance and Odor:NOT PROVIDED
Percent Volatiles by Volume:97
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
=================== Toxicological Information ===================
Toxicological Information:LIFETIME INHALATION EXPOSURE OF RATS AND MICE
TO HIGH ETHYLBENZENE CONCENTRATIONS RESULTING IN INCREASES IN
CERTAIN TYPES OF CANCER, INCLUDING KIDNEY TUMORS IN RATS AND LUNG
AND LIVER TUMORS IN MICE. THESE EFFECTS WERE NOT OBSERVED IN
ANIMALS EXPOSED TO LOWER CONCENTRATIONS. METHYL ETHYL KETONE MAY
INCREASE THE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. PROLONGED
OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO
THE LIVER, URINARY, CARDIOVASCULAR AND REPRODUCTIVE SYSTEMS.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYST EM DAMAGE.(
===================== Ecological Information =====================
Ecological:ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSEVATION AND RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE
APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STA
TE, AND LOCAL REGULATIONS REGARDING POLLUTION.
=================== MSDS Transport Information ===================
Transport Information:NO DATA AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: TOLUENE, 108-88-3, 14% WT; ETHYLBENZENE, 100-41-4,
0.5% WT; XYLENE, 1330-20-7, 3% WT; 1-BUTANOL, 71-36-3, 2 % WT;
METHYL ETHYL KETONE, 78-93-3, 48% WT; METHYL ISOBUTYL KETONE,
108-10-1, 5% WT.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED , OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING : THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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