===================== Product Identification =====================
MSDS NAME:TYPE 1, ALIPHATIC ISOCYANATE
NIIN:01-397-3944
Status Code:A
MSDS Number: CLQQV
=== Responsible Party ===
Company:DEFT, INC.
Address:17451 VON KARMAN AVE
City:IRVINE
State:CA
ZIP:92614
Country:US
Info Phone Num:949-474-0400
Emergency Phone Num:800-424-9300
Preparer's Name:ERNEST CARTER
Chemtrec Ind/Phone:(800)424-9300
CAGE:33461
=== Contractor Identification ===
Company:DEFT, INC.
Address:17451 VON KARMAN AVE
City:IRVINE
State:CA
ZIP:92614
Country:US
Phone:949-474-0400
CAGE:33461
============= Composition/Information on Ingredients =============
Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:15.
OSHA PEL:SEE TABLE Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL ISOBUTYL KETONE
CAS:108-10-1
RTECS #:SA9275000
= Wt:40.
OSHA PEL:410 MG/M3;100 PPM
ACGIH TLV:205 MG/M3;50 PPM
ACGIH STEL:307 MG/M3;75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:1,3,5-TRIS(6-HYDROXYHEXYL)BIURET TRIISOCYANATE
CAS:4035-89-6
RTECS #:NR0195000
= Wt:45.
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPORS ARE IRRITATION TO EYES, NOSE
AND THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING AND
LOSS OF CONSCIOUSNESS. AS A RESULT OF PREVIOUS REPEATED
OVEREXPOSURE OR A SINGLE LARGE DOSE, CER TAIN INDIVIDUALS WILL
DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO
A LATER EXPOSURE OF ISOCYANATE LEVELS WELL BELOW THE TLV VALUE OF
ISOCYANATES.
Effects of Overexposure:INHALATION: IRRITATION OF THE RESPIRATORY TRACT
& ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE FOLLOWING
PROGRESSIVE STEPS: HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION,
UNCONSCIOUSNESS OR COMA. SKIN: ISOCYANATES REACT WITH SKIN PROTEIN
AND MOISTURE AND CAN CAUSE IRRITATION. SYMPTOMS MAY BE SWELLING,
REDNESS, AND RASH. EYES: LIQUID, AEROSOLS, OR VAPORS ARE IRRITATING
AND MAY CAUSE TEARI NG, REDNESS, AND SWELLING ACCOMPANIED BY A
STINGING SENSATION. INGESTION: ACUTE: CAN RESULT IN IRRITATION AND
POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE AND
DIGESTIVE TRACT. VOMITING MAY C AUSE ASPIRATION OF THE SOLVENT,
RESULT
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS, SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISOCYANATE
SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO AN AREA FREE FROM RISK OF FURTHER
EXPOSURE. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP
AND MAY BE IMMEDIATE OR DELAYED BY SEVERAL HOURS. OBTAIN MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS
THOROUGHLY WITH SOAP AND WATER, WASH CONTAMINATED CLOTHING
THOROUGHLY BEFORE REUSE. EYES: FLUSH WITH LUKE WARM WATER (LOW
PRESSURE) FOR AT LEAST 15 M INUTES, OCCASIONALLY LIFTING EYELIDS,
OBTAIN MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. DO NOT
GIVE ANYTHING TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=7.2C, 45.F
Lower Limits:1.00%
Upper Limits:8.00%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG,
WATER SPRAY.
Fire Fighting Procedures:FULL FIRE FIGHTING EQUIPMENT WITH SELF
CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD
BE WORN BY FIRE FIGHTERS. WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD UP, AUTO IGNITION OR
EXPLOSION. DURING A FIRE HDI VAPORS AND OTHER IRRITATING VAPORS MAY
BE GENERATED BY COMBUSTION OR
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO
HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY
CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A
HEALTH HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN BUILDINGS DESIGNED TO COMPLY
WITH OSHA 1910.106 AVOID STORING NEAR HIGH TEMPERATURES, FIRE, OPEN
FLAMES, AND SPARK SOURCES. STORE IN TIGHTLY CLOSED CONTAINERS.
STORE IN WELL VENTILATED AREAS.
Other Precautions:KEEP CONTAINERS TIGHT AND UPRIGHT TO PREVENT LEAKAGE.
PREVENT PROLONGED BREATHING OF VAPORS OR SPRAY MISTS. PROLONGED
OVEREXPOSURE MAY CAUSE AN ALLERGIC REACTIO. AVOID CONTACT WITH SKIN
AND EYES. DO N OT TAKE INTERNALLY. DO NOT HANDLE UNTIL THE
MANUFACTURERS SAFETY PRECAUTIONS HAVE BEEN READ AND UNDE RSTOOD.
WASH HANDS B
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN AN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING OR FRESH AIR
SUPPLIED) IS NECESSARY. OBSERVE OSHA REGULATIONS FOR RESPIRATOR
USE. VENTILATION SHOULD BE APPROVED TO KEEP EXPOSURE LEVELS BELOW
THE OSHA PERMISSIBLE LIMITS.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF SOLVENT, HDI AND POLYISOCYANATES BELOW THEIR
RESPECTIVE TLV'S MUST BE UTILIZED.
Protective Gloves:PROTECTIVE GLOVES ARE RECOMMENDED (COTTON, NEOPRENE,
RUBBER, POLYETHYLENE) TO P
Eye Protection:SPLASH GUARDS OR SIDE SHIELDS, CHEMICAL GOGGLES OR FACE
SHIELDS.
Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING
IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:230-428 DEG.F
Vapor Density:HEAVIER
VOC Pounds/Gallon:495
VOC Grams/Liter:7.78
Viscosity:THIN LIQUID TO HEAVY
Evaporation Rate & Reference:1.39
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:61.2%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OXIDES OF NITROGEN, TRACES OF HCN AND HDI.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORADNCE WITH
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS MUST BE HANDLED WITH CARE, DUE TO PRODUCT RESIDUE AND
FLAMMABLE VAPOR DO NOT INCINERATE CLOSED CONTAINERS.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
THE EMERGENCY PLANNING AND COMMUNITY TO KNOW 1986 AND 40 CFR 372:
108-83-3 TOLUENE, 108-20-3 METHYL ISOBUTYL KETONE
State Regulatory Information:THIS PRODUCT CONTAINS A CHEMICAL KNOWN BY
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. 108-83-3.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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