===================== Product Identification =====================
MSDS NAME:MANGANESE DIOXIDE LITHIUM PRIMARY BATTERIES (SEE SUPPL DATA)
NIIN:01-454-9408
Status Code:A
MSDS Number: CLQNP
=== Responsible Party ===
Company:SANYO BATTERIES/SANYO ENERGY
Address:2055 SANYO AVE
City:SAN DIEGO
State:CA
ZIP:92173
Country:US
Info Phone Num:619-661-4888
Emergency Phone Num:619 661-6620
CAGE:00JU0
=== Contractor Identification ===
Company:SANYO ENERGY(U.S.A.) CORP.
Address:2001 SANYO AVE
Box:City:SAN DIEGO
State:CA
ZIP:92173
Country:US
Phone:619-661-6620
CAGE:00JU0
Company:TNR TECHNICAL INC
Address:301 CENTRAL PARK DR
Box:City:SANFORD
State:FL
ZIP:32771
Country:US
Phone:407-321-3011
CAGE:1HJ92
============= Composition/Information on Ingredients =============
Name:DIMETHOXYETHANE (DME)
CAS:110-71-4
RTECS #:KI1451000
Name:LITHIUM PERCHLORATE
CAS:7791-03-9
Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
OSHA PEL:C5 MG/M3
ACGIH TLV:5 MG/M3
Name:LITHIUM
CAS:7439-93-2
RTECS #:OJ5540000
Name:PROPYLENE CARBONATE
CAS:108-32-7
RTECS #:FF9650000
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS ARE CONTAINED IN A
SEALED CAN. RISK OF EXPOSURE OCCURS ONLY IF THE BATTERY IS
MECHANICALLY OR ELECTRICALLY ABUSED. THE MOST LIKELY RISK IS ACUTE
EXPOSURE WHEN A CELL VENTS. DME IS BELI EVED TO BE SLIGHTLY TO
MODERATELY TOXIC, AND PROPYLENE CARBONATE IS CONSIDERED TO BE
NON-TOXIC BUT MODERATELY IRRITATING TO THE EYES. LIC104 IS
IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES. CONTACT O F
ELECTROLYTE AND EXTRUDED LITHIUM WITH SKIN AND EYES SHOULD BE
AVOIDED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:DME MAY BE A REPRODUCTIVE HAZARD. LITHIUM CAN
CAUSE THERMAL AND CHEMICAL BURNS UPON CONTACT WITH SKIN.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL CONDITION.
======================= First Aid Measures =======================
First Aid:IN CASE OF SKIN CONTACT WITH CONTENTS OF BATTERY, FLUSH
IMMEDIATELY WITH WATER. FOR EYE CONTACT, FLUSH WITH COPIOUS AMOUNT
OF WATER OF 15 MINUTES. DO NOT INHALE VENTED MATERIAL. IF
IRRITATION PERSIST, GET MEDICAL HELP.
===================== Fire Fighting Measures =====================
Flash Point:DME=-1 C
Extinguishing Media:WATER
Fire Fighting Procedures:IN CASE OF FIRE IN AN ADJACENT AREA, USE
WATER, CO2, OR DRY CHEMICAL EXTINGUISHERS IF CELL ARE PACKED IN
THEIR ORIGINAL CONTAINERS SINCE THE FUEL OF THE FIRE IS BASICALLY
PAPER PRODUCTS. FOR BULK QUAN TITIES OF UNPACKAGED CELL USE LITH-X
(GRAPHITE BASE). IN THIS CASE, USE NO WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:THE PREFERRED RESPONSE IS TO LEAVE THE AREA
AND ALLOW BATTERIES TO COOL AND VAPORS TO DISSIPATE. AVOID SKIN AND
EYE CONTACT OR INHALATION OF VAPORS. REMOVE SPILLED LIQUID WITH
ABSORBENT AND INCINERATE .
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID MECHANICAL OR ELECTRICAL ABUSE.
Other Precautions:BATTERIES MAY EXPLODE OR CAUSE BURN, IF DISASSEMBLED,
CRUSHED, RECHARGED OR EXPOSED TO FIRE OR HIGH TEMPERATURE. DO NOT
SHORT NOR INSTALL WITH INCORRECT POLARITY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECESSARY UNDER CONDITIONS OF NORMAL USE.
Ventilation:NOT NECESSARY UNDER CONDITIONS OF NORMAL USE
Protective Gloves:NOT NECESSARY UNDER CONDITIONS OF NORMAL USE.
Eye Protection:NOT NECESSARY UNDER CONDITIONS OFNORMAL USE.
Other Protective Equipment:NOT NECESSARY UNDER CONDITIONS OF NORMAL
USE.
Supplemental Safety and Health
(P/N TRADE NAME) CONT'D: COIN AND CYLINDRICAL (SE) TYPE.
================== Physical/Chemical Properties ==================
HCC:Z6
Boiling Pt:B.P. Text:PC-242,DME-85
Vapor Pres:PC-0.03,DME-61
Vapor Density:DME-3.1
Solubility in Water:DME-COMPLETE,PC MODERATE
Appearance and Odor:LITHIUM IS A SOFT SILVERY METAL,DME IS A COLORLESS
LIQUID WITH A SWEET ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:STABLE. DO NOT HEAT, DISASSEMBLE, OR
RECHARGE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPROPRIATE
REGULATIONS. OPEN CELLS SHOULD BE TREATED AS HAZARDOUS WASTES.
=================== MSDS Transport Information ===================
Transport Information:DOT DESCRIPTION (US ONLY): PROPER SHIPPING NAME:
NITROUS OXIDE. HAZARD CLASS: 2.2 (NONFLAMMABLE). IDENTIFICATION
NUMBER: UN1070. REPORTABLE QUANTITIES: NOT APPLICABLE. LABELING:
NONFLAMMABLE GAS, OXID IZER. ADR/RID (EU ONLY): CLASS 2, 2 O.
SPECIAL PRECUTIONS: CYLINDERS SHOULD BE TRANSPORTED IN A SECURE
UPRIGHT POSITION IN A WELL VENTILATED TRUCK.
===================== Regulatory Information =====================
SARA Title III Information:SARA: THE THREASHOLD PLANNING QUANTITY FOR
MATERIAL IS 10,000 LBS.
Federal Regulatory Information:TSCA; MATERIAL IS LISTED IN TSCA
INVENTORY. OSHA PROCESS AFETY MANAGEMENT: MATERIALS ARE NOT LISTED
IN APPENDIX A OF 29 CFR 1910.119 AS HIGHLY HAZARDOUS CHEMICALS.
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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