===================== Product Identification =====================
MSDS NAME:BLACK URETHANE SUB PART B, 13-911
NIIN:01-380-3280
Status Code:A
MSDS Number: CLQNV
=== Responsible Party ===
Company:FINNAREN & HALEY INC
Address:901 WASHINGTON ST
City:CONSHOHOCKEN
State:PA
ZIP:19428
Country:US
Info Phone Num:1-610-825-1900
Emergency Phone Num:800-424-9300
Preparer's Name:ERNEST CARTER
Chemtrec Ind/Phone:(800)424-9300
CAGE:9V982
=== Contractor Identification ===
Company:FINNAREN & HALEY INC
Address:901 WASHINGTON ST
Box:City:CONSHOHOCKEN
State:PA
ZIP:19428
Country:US
Phone:1-610-825-1900
CAGE:9V982
============= Composition/Information on Ingredients =============
Name:HOMOPOLYMER OF HDI
CAS:28182-81-2
Code:F
RTECS #:NQ9170000
= Wt:83.
Name:HEXAMETHYLENE DIISOCYANATE
CAS:822-06-0
RTECS #:MO1740000
< Wt:.15
ACGIH TLV:0.034 MG/M3;.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:AROMATIC 100
CAS:64742-95-6
Code:F
RTECS #:WF3400000
= Wt:4.6
Name:N-BUTYL ACETATE
CAS:123-86-4
RTECS #:AF7350000
= Wt:4.6
OSHA PEL:710 MG/M3;150 PPM
ACGIH TLV:713 MG/M3;150 PPM
ACGIH STEL:950 MG/M3;200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:INHALATION: HDI VAPORS OR MIST AT
CONCENTRATIONS ABOVE THE TLV CAN IRRITATE (BURNING SENSATION) THE
MUCOUS MEMBRANES IN THE RESPIRATORY TRACT (NOSE, THROAT, LUNGS)
CAUSING RUNNY NOSE, SORE, THROAT, CO UGHING, CHEST DISCOMFORT,
SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION (BREATHING
OBSTRUCTION). PERSONS WITH A PREEXISTING, NONSPECIFIC BRONCHIAL
HYPERREACTVITY CAN RESPOND TO CONCENTRATIONS BELOW TH E TLV WITH
SIMILAR SYMPTOMS AS WELL AS AN ASTHMA ATTACK.EXPOSURE WELL ABOVE
THE TLV MAY LEAD TO BRONCHITIS, BRONCHIAL SPASM AND POLMONARY EDEMA
(FLUID IN LUNGS). THESE EFFECTS ARE USUALLY REVERSIBLE. CHEMICAL
OR HYPERSENSITIVE PNEUMONITIS,
Effects of Overexposure:WITH FLU LIKE SYMPTOMS (E.G. FEVER, CHILLS) HAS
ALSO BEEN REPORTED. SOLVENT VAPORS MAY BE IRRITATING TO THE EYES,
NOSE AND THROAT. SYMPTOMS OF IRRITATION MAY INCLUDE:REDNESS,
BURNING AND ITCHING OF TH E EYES, DRYNESS OF THR THROAT AND
TIGHTNESS OF THE CHEST. OTHER POSSIBLE SYMPTOMS OF OVEREXPOSURE
INCLUDE: A CONCENTRATION OF 200 PPM BUTYL ACETATE CAN CAUSE EYE,
NOSE, AND THROAT IRRITATION. AT 300 PPM THESE EFFECTS CAN BECOME
SEVERE. CHRONIC INHALATION: AS A RESULT OF PREVIOUS REPEATED
OVEREXPOSURES OR A SINGLE LARGE DOSE, CERTAIN INDIVIDUALS WILL
DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL ASTH MA) WHICH WILL
CAUSE THEM TO REACT T
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERRACTIVITY), SKIN ALLERGIES,
ECZEMA.
======================= First Aid Measures =======================
First Aid:FOR EYES: FLUSH WITH CLEAN, LIKE WARM WATER (LOW PRESSURE)
FORE AT LEAST 15 MINUTES, WHILE LIFTING EYELIDS. REFER TO
PHYSICIAN. FOR SKIN: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. GET MEDICA L ATTENTION. FOR INHALATION: MOVE TO AN AREA FREE
FROM RISK OF FURTHER EXPOSURE. OBTAIN MEDICAL ATTENTION. FOR
INGESTION: DO NOT INDUCE VOMITING. GIVE 1-2 CUPS OF MILK OR WATER
TO DRINK. CONSULT PHYS ICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=48.3C, 119.F
Lower Limits:1.2%
Upper Limits:7.5%
Extinguishing Media:DRY CHEMICAL; CARBON DIOXIDE; FOAM; WATER SPRAY FOR
LARGE FIRES.
Fire Fighting Procedures:FULL EMERGENCY EQUIPMENT WITH SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD BE WORN BY
FIRE FIGHTERS. DURING A FIRE, HDI VAPORS AND OTHER IRRITATING;
HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR BURST WHEN CONTAMINATED WITH WATER (CO2
EVOLVED). SOLVENT VAPORS MAY BE HEAVIER THAN AIR. STAGNANT AIR MAY
CAUSE VAPORS TO ACCUMULATE AND TRAVEL ALONG THE GROUND TO AN
IGNITION SOURCE WHICH MAY RESULT IN A FLASHBACK TO THE SOURCE OF
THE VAPOR.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE OR IMPOUND SPILLED MATERIAL AND CONTROL
FURTHER SPILLAGE IF FEASIBLE. COVER THE SPILL WITH SAWDUST,
VERMICULITE, FULLER'S EARTH OR OTHER ABSORBENT MATERIAL. POUR
DECONTAMINATION SOLUTION OVER SPI LL AREA AND ALLOW TO REACT FOR AT
LEAST 10 MINUTES. COLLECT MATERIAL IN OPEN CONTAINERS AND ADD
FURTHER AMOUNTS OF DECONTAMINATION SOLUTION. REMOVE CONTAINERS TO A
SAFE PLACE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS TO
PREVENT MOISTURE CONTAMINATION. DO NOT RESEAL IF CONTAMINATION IS
SUSPECTED. AVOID CONTACT WITH SKIN AND EYES. EMPLOYEE EDUCATION AND
TRAINING IN THE SAFE USE AN D HANDLING OF THIS PRODUCT ARE REQUIRED
UNDER THE OSHA HAZARD COMMUNICATION STANDARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN ISOCYANATE CONTAINING ENVIRONMENTS (AIR PURIFYING OR FRESH
AIR SUPPLIED) MAY BE NECESSARY, CONSIDER TYPE OF APPLICATION AND
ENVIRONMENTAL USE (2 9 CFR 1910.134).
Protective Gloves:PERMEATION RESISTANT GLOVES. COVER AS MUCH OF THE
EXPOSED SKIN AREA AS POSSIBLE
Eye Protection:SAFETY GLASSES, SPLASH GOGGLES OR FACE SHIELD. CONTACT
LENSES SHOULD NOT BE WOR
Work Hygienic Practices:PRECAUTIONS MUST BE TAKEN SO THAT PERSONS
HANDLING THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT CONTACT
THE EYES OR SKIN. IN SPRAY OPERATIONS, PROTECTION MUST BE AFFORDED
AGAINST EXPOSURE TO BOTH
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:260-392 F
Vapor Pres:7.5X10-5 MM HG
Spec Gravity:1.1@68 F (20 C)
VOC Grams/Liter:9.2
Solubility in Water:REACTS SLOWLY WITH WATER
Appearance and Odor:LIQUID CLEAR/PALE YELLOW OF SOLVENT.
Percent Volatiles by Volume:21.4%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, HCN, HDI.
Conditions to Avoid Polymerization:MAY OCCUR; CONTACT WITH MOISTURE OR
OTHER MATERIALS WHICH REACT WITH ISOCYANATES OR TEMPERATURE OVER
400 F (204 C) MAY CAUSE
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
===================== Regulatory Information =====================
State Regulatory Information:TO THE BEST OF OUR KNOWLEDGE, THIS PRODUCT
CONTAINS NO LEVELS OF LISTED SUBSTANCES, WHICH THE
STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER,
BIRTH DEFECTS OR OTHER REPRODUCTIVE EFFECTS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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