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MSDS Material Safety Data Sheet
CAS

123-42-2
111-76-2
64742-95-6
98-55-5
9016-45-9
67-68-5
628-63-7
8002-09-3
138-86-3
67-63-0

File Name: frontiersd_mb_ca---Presto_Grafitti_Remover_1280.asp
                                                                                                                                                       Material Safety Data Sheet
AVMOR
950 MICHELIN
LAVAL QC H7L 5C1


Section I. Product Identification and Uses
HMIS (HFRP)
3
Health Hazard
2
Fire Hazard
0
Reactivity
h
Personal Protection
PRESTO Graffiti Remover Class 3(6.1)
Common / Trade name TDG
UN1992 FLAMMABLE LIQUID, TOXIC, N.O.S. (Isopropanol)
WHMIS PIN
B3, D1A, D2B
1280 III
Code PG
Grafitti remover.
Material uses


Section II. Hazardous Ingredients
Name CAS # % by weight TLV/PEL LC50/LD50
Diacetone alcohol 123-42-2 10 - 30 Not available. ORAL (LD50): Acute: 4000 mg/kg [Rat]. 3959
mg/kg [Mouse]. DERMAL (LD50): Acute: 13600
mg/kg [Rabbit].
Ethylene glycol monobutyl ether 111-76-2 10 - 30 Not available. ORAL (LD50): Acute: 1480 mg/kg [Rat.]. 1230
mg/kg [Mouse]. 320 mg/kg [Rabbit]. DERMAL
(LD50): Acute: 400 mg/kg [Rabbit]. VAPOR
(LC50): Acute: 450 ppm 4 hour(s) [Rat]. 927 ppm 4
hour(s) [Mouse].
Light aromatic solvent naphtha 64742-95-6 5 - 10 Not available. ORAL (LD50): Acute: 8400 mg/kg [Rat].
(petroleum)
3-cyclohexene-1-methanol,alpha,alpha,4- 98-55-5 5 - 10 Not available. ORAL (LD50): Acute: 4300 mg/kg [Rat].
trimethyl DERMAL (LD50): Acute: 3000 mg/kg [Rabbit].
Nonyl phenol ethoxylate 9016-45-9 1-5 Not available. Not available.
Dimethyl sulfoxide 67-68-5 1-5 Not available. ORAL (LD50): Acute: 17500 mg/kg [Rat]. 14500
mg/kg [Rat]. 16500 mg/kg [Mouse].
Acetate d'amyle normal 628-63-7 1-5 Not available. ORAL (LD50): Acute: 16550 mg/kg [Rat].
Pine oil 8002-09-3 1-5 Not available. Not available.
Limonene 138-86-3 1-5 Not available. ORAL (LD50): Acute: 4800 mg/kg [Rat].
DERMAL (LD50): Acute: > 5000 mg/kg [Rabbit].
Isopropyl alcohol 67-63-0 1-5 Not available. ORAL (LD50): Acute: 3600 mg/kg [Mouse.]. >
4720 mg/kg [Rat].


Section III. First Aid Measures
IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention.
Eye
contact
If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible. Thoroughly wash the contaminated skin with
Skin
running water and non-abrasive soap.
contact
Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Oxygen may be administered if breathing is difficult.
Ingestion DO NOT induce vomiting. Have conscious person drink several glasses of water. Seek immediate medical attention. NEVER give an unconscious person anything
to ingest.


Section IV. Physical Data
Liquid. Hazy liquid. Amber.
Physical state and apperance Colour
Acidic. Sweetish.
pH (1% soln/water) Odour
Not applicable 96% (v/v).
pH (concentrate) Volatility
85掳C (185掳F) Weighted average: 3.75 (Air = 1)
Boiling point Vapour density
0.91 to 0.93 (Water = 1) Weighted average: 71.19 mm of Hg (@ 20掳C)
Specific gravity Vapour pressure
Easily soluble in cold water, hot water, methanol. Soluble in diethyl ether. Very slightly soluble in n-octanol.
Solubility


Section V. Fire and Explosion Data
Combustible.
The product is
Auto-ignition temperature 215掳C (419掳F) (Dimethyl sulfoxide).
Closed cup: 41.9掳C (107.4掳F).
Flash points
These products are carbon oxides (CO, CO2).
Degradation products
SMALL FIRE: Use DRY chemicals, CO2, water spray or foam. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Extinguising media


1280 PRESTO Graffiti Remover 1/2
Section VI. Reactivity data
The product is stable.
Stability
See fire degradation products.
Decomp. products
Reactive with oxidizing agents, acids. Very slightly reactive with reducing agents, organic materials, alkalis.
Reactivity


Section VII. Toxicological properties
Eye contact. Ingestion. Skin contact. Inhalation.
Route of
entry
Toxicity for Acute oral toxicity (LD50): 2200 mg/kg (Rat.) (Calculated value for the mixture). Acute dermal toxicity (LD50): 490 mg/kg (Rabbit.) (Ethylene glycol monobutyl
ether). Acute toxicity of the gas (LC50): 700 ppm (Mouse) (Ethylene glycol monobutyl ether).
animals
Very hazardous in case of ingestion. Hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of inhalation.Hazardous in case of
Acute
skin contact (sensitizer). Harmful by inhalation, in contact with skin and if swallowed.
effects
CARCINOGENIC EFFECTS:Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL
Chronic
TOXICITY:Contains ingredients that are known to affect foetal development.
effects


Section VIII. Preventive measure
Dispose of material according to regional, provincial and federal regulations. Consult your local or regional authorities.
Waste
disposal
Keep container dry, tightly closed. Keep in a cool, well-ventilated place.
Storage
Precautions Keep locked up and out of reach of children. . In case of contact with eyes, rinse immediately with plenty of water.In case of contact, immediately flush skin with
plenty of water while removing contaminated clothing and shoes.Wear suitable protective clothing, gloves and eye/face protection.
Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal container.
Spill and
leak


Section IX. Personal protective equipment
Gloves (impervious).
Gloves
Respiratory Wear appropriate respirator when ventilation is inadequate.
Splash goggles.
Eyes
Vapor respirator, full suit, boots, gloves, plastic apron, face shield: are recommended under exceptional circumstances such as fire, spill or for prolonged contact
Other
with bulk quantities.
Provide exhaust ventilation or other engeneering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that
Eng.
eyewash stations and safety showers are proximal to the work-station location.
controls


Section X. Preparation and other Information
Validated by the Regulatory Affairs Department on 27 aug. 2004 Printed 30 aug. 2004

CANUTEC : (613) 996-6666
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsability of the user. All
materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.


Annex A. Legend
Hazardous Materials Identification System
HMIS
WHMIS Workplace Hazardous Materials Information System
WHMIS
Transport Dangerous Goods
TDG
Product Identification Number
PIN
Packaging Group
PG




1280 PRESTO Graffiti Remover 2/2

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