DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
MATERIAL SAFETY DATA SHEET
According to 93/112/EC
1. IDENTIFICATION OF SUBSTANCE/PREPARATION AND
OF COMPANY/UNDERTAKING:
� Trade name: ZHONGBANG PL PIGMENTS
Glow-in-dark pigment
� Manufacturer/Supplier: DALIAN ZHONGBANG CHEMICAL INDUSTRY
CO., LTD.
NO. 36 XINYI ST., GANJINGZI DIST.,
DALIAN 116039, CHINA
� Phone: +86�411�86311792
� Fax: +86�411�86311793
� E-mail: sales1@glow-phosphor.com
2. COMPOSITION/DATA ON COMPONENTS:
� Chemical characterization:
- C.A.S. No. Designation: n.a.
- EINECS No.: n.a.
� Formula: MAl2O4.nB2O3:Eu3+.Dy3+
� Content: Sr, Ca, Ba, Al, Eu, B, Dy, etc.
1 HAZARD IDENTIFICATION:
� Hazard destination: -----
� Information pertaining to particular dangers for man and environment:
Experience in use of the product shows that it is not a known hazard to human
and environment.
� Classification system:
The classification is in line with current EC list. It is expanded, however, by
information from technical literature and by information furnished by supplier
companies.
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DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
4. FIRST AID MEASURES:
� General advice: none
� If inhaled: remove to fresh air. Call physician.
� On skin contact: wash with simple water.
� On contact with eyes: wash with mild soap solution.
� On ingestion: seek medical aid immediately.
� Note to physician: nothing particular ; consult physician for
prolonged effect.
5. FIRE FIGHTING MEASURES:
� Suitable extinguishing media: water fog, foam, carbone dioxide, dry chemical.
� Unsuitable extinguishing media
for safety reasons: none
� The following can be given off
in a fire: not required as not flammable.
� Special protective equipment: none
� Further information: none
6. ACCIDENTAL RELEASE MEASURES :
� Personal precautions: not required as not hazardous; in case of spillage sweep
and collect contents and wash out area with water.
� Environmental precautions: ----
� Methods for cleaning up: sweep and place in a closable container for disposal.
7. HANDLING AND STORAGE:
� Handling: keep in a tightly closed containers, stored in a
cool, dry, ventilated area, keep away from water.
� Protection against fire and
explosion: not explosive ; no special precaution is
necessary even then due to carring effect. To be
kept away from fire.
� Storage: remove with suitable packing.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:
� Additional information on the lay-out of technical plant: ----
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DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
PERSONAL PROTECTIVE EQUIPMENT :
� Respiratory protection: cover with cloth veil
� Hand protection: gloves
� Eye protection: goggles
� Body protection: wear protective clothing to avoid body contact
� General safety and hygiene
measures: use a respiratory if necessary with suitable filter recommemded.
9. PHYSICAL AND CHEMICAL PROPERTIES:
� Form: powder
� Odour: odourless
Change in physical stage:
� Melting point/melting range: 1745 °C DIN
� Boiling point/boiling range: n.a. °C DIN
� Flash point: n.a. °C DIN
Combustibility: free of combustibility
Explosion limits: n.a.
- lower Vol% - upper Vol%
� Ignition temperature: n.a. °C DIN
� Self ignition temperature: n.a. °C DIN
� Self ignition: n.a.
� Explosion hazard: n.a.
� Fire promoting properties: none
� Vapour pressure: n.a. °C DIN
� Density: 3.6 g/cm3
� Bulk density: n.a. Kg/m3
� Solubility in water: decompose in water
� Solubility in other solvents: n.a.
� PH value: 6-8 at g/1 °C
� Octanol/water partition
coefficient (log POW):
� Viscosity: n.a. °C
� Other information: ------
10. STABILITY AND REACTIVITY:
� Condition to avoid: Avoid contacting with water and acids.
� Substances to avoid: Acids.
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DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
� Hazardous reactions: n.a.
� Hazardous decomposition
products: this product is boric-aluminate product and
can be worked at temperature between -20~500°C. No hazardous products to
human and environment after decomposing in water.
11. TOXICOLOGICAL INFORMATION:
� LD50 oral / rat: >5000 mg/Kg
� LC50 inhall. / rat: n.a. mg/l
� Primary skin irritation/rabbit: not irritant
� Primary mucous membrane
irritation / rabbit’s eyes: not irritant
� Sensitizing: n.a.
� Subacut-chronic toxicity: n.a.
� Experience in humans: n.a.
� Additional information: n.a.
12. ECOLOGICAL INFORMATION:
� Elimination information: clean and sweep and wash the area with water.
Product decomposing in water yes. But TPG series.
� Water hazard class: WGK (dangerous class for water in RFT) = 0
not dangerous (self assessment)
13. DISPOSAL CONSIDERATIONS:
� Product: In accordance with federal, state and local regulations.
� -----
Contaminated packaging:
14. TRANSPORT INFORMATION:
No special information for transport.
15. REGULATORY INFORMATION:
88/379/ECC (Classification and labelling):
� Classification & labelling: none. The product doesn’t need any label.
� Symbols: none.
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DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
� FDA Status: this product does not have FDA approval as a
food additive.
� USDA Status: this product has not been evaluated by USDA
for use in packaging material in direct contact
with meat or poultry food product prepared
under federal inspection.
16. OTHER INFORMATION:
� Department issuing data specification sheet: Quality Control Laboratory.
� Contact: Quality Control Laboratory
� Heavy metals:
The possible content of soluble heavy metals are microcontaminants are tipically
below 25 ppm for each of the following:
Antimony Arsenic Zinc
Lead Cadmium Chromium
Mercury Nickel Selenium
� Polychlorinated biphenyls (PCB’s):
From a theoretical assessment the product does not contains PCB.
� Inventories :
Australia: the components of the product are included in the AICS.
Canada: the components of the product are included in the DSL.
EU: the components of the product are included in the EINECS.
USA: the components of the product are included in the TSCA.
� FDA and BGVV Approvals for food packaging :
In common with most other pigments/pigment preparations the product is not
specially approved by FDA and BGVV , but to the best of our knowledge there is
no reason for any hesitations as to use the product for food packaging if no
migration or peeling.
� Aromatic amines : n.a.
� CONEG: The heavy metal levels referred above for cadmium, lead,mercury and
chromium (hexavalent) are to be in full compliance with the U.S. CONEG’s
permitted maximum concentration of 100 ppm in packaging materials.
� EU Packaging Directive 94/62/EU:
� The heavy metal levels referred above for cadmium, lead,mercury and chromium
(hexavalent) are to be in full compliance with the EU Packaging Directive
94/62/EU permitted maximum concentration of 100 ppm in packaging
materials.
The information contained in this safety profile is based on our pesent knowledge
and must not be considered as a guarantee of specific properties. The standards
and legal disposition in force must be respected by the consignee of our products
under his own responsibility.
This MSDS cancels and replaces any preceding release.
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DALIAN ZHONGBANG CHEMICAL INDUSTRY CO., LTD.
List of all Glow-in-dark pigments referred to the present MSDS:
TPY-9B ZHONGBANG YELLOW-GREEN TPY-9B
TPY-9C ZHONGBANG YELLOW-GREEN TPY-9C
TPY-8D ZHONGBANG YELLOW-GREEN TPY-8D
TPY-8E ZHONGBANG YELLOW-GREEN TPY-8E
TPG-9C ZHONGBANG BLUE-GREEN TPG-9C
TPG-9D ZHONGBANG BLUE-GREEN TPG-9D
TPB-9D ZHONGBANG SKY-BLUE TPB-9D
TPP-9D ZHONGBANG BLUE-PURPLE TPP-9D
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