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Procter & Gamble
Fabric and Home Care Division
Sharon Woods Technical Center
11530 Reed Hartman Highway
Cincinnati, OH 45241-2422
MATERIAL SAFETY DATA SHEET
MSDS #: H02MMR Issue Date: 04/12/02
Supersedes: HO1MMR Issue Date: 12/03/01
SECTION I - CHEMICAL PRODUCT
Identity: Liquid Cleaner
Brands: MR. CLEAN (Seasons鈥? Freshness Summer Citrus, Spring Garden, Invigorating Breeze, Sparkling
Apple)
Hazard Rating: 1 Health: 1 4=EXTREME
Flammability: 0 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: 24hr P&G Operator - 1-800-8-MR CLEAN (1-800-867-2532) or call Local Poison
Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Cleaning agents (nonionic and anionic surfactants), quality control agents, perfume,
colorant and water.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS No. Recommended Limits Composition LD50/LC50
Chemical
Name Range
Name
Nonionic Confidential N/A 0.1-1% N/A
Alcohol
Ethoxylates Surfactants
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May be harmful if swallowed.
Eye Contact: Mild eye irritant.
Inhalation: N/A
Skin: Mild skin irritant.
Signs and Symptoms of Exposure:
Ingestion: Oral ingestion may result in transient nervous system effects (ataxia and muscle weakness)
and/or gastrointestinal irritation with nausea, vomiting or diarrhea. This product contains
alcohol ethoxylates. Large ingestions (>2ml/kg) may also cause symptoms of alcohol-like
intoxication, incoordination, drowsiness, inarticulateness or ataxia. Alcohol ethoxylates
may contribute to central nervous system symptoms.
Eye Contact: Instillation into the eye may result in transient superficial effects similar to those produced
by mild toilet soaps and detergents.
Skin: Use on irritated or extremely dry skin may aggravate the existing condition.
Inhalation: N/A
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MR. CLEAN LIQUID CLEANER MSDS (Continued) Page 2 of 4
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion: Dilute with fluids and call a physician.
Eye Contact: Immediately flush with water thoroughly, lifting upper and lower lids occasionally.
Skin: Thoroughly wash exposed area with soap and water and discontinue use. Remove
contaminated clothing. If irritation persists, consult a physician.
Inhalation: Remove to fresh air.
Other: Consumer product package has a caution statement: CAUTION: EYE IRRITANT. KEEP OUT OF
REACH OF CHILDREN.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): over 200掳 F (cc) Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: CO2, water, dry chemical or "alcohol" foam.
Special Fire Fighting Procedures: Use water to keep fire exposed container cool.
Unusual Fire Hazards: None known.
Conditions to Avoid: None known
Stability Unstable:
Stable: X
Incompatibility (Materials to Avoid): None known
Hazardous Decomposition/By Products: None known
Conditions to Avoid: None known
Hazardous Polymerization: May Occur:
Will Not Occur: X
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE AND LOCAL REGULATIONS. Do not landfill. Small (household) quantities may be disposed of via
sewer with large quantities of water. Incineration is preferred where permitted.
Steps To Be Taken in Case Material is Released or Spilled: Use water spray to dilute and/or wash away spills
to avoid exposure and to protect persons working to stop/repair leak. Absorb spilled product onto absorbent
material.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Handling and storage must be well ventilated, cool, and
dry.
Other Precautions: None known.
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MR. CLEAN LIQUID CLEANER MSDS (Continued) Page 3 of 4
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use.
Ventilation Local Exhaust: None required with normal consumer use. Special: None
Mechanical (General): Acceptable. Other: None
Eye Protection: None required with normal consumer use.
Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is desirable.
Protective Gloves: None required with normal use.
Other Protective Equipment: None required with normal use.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 掳 F: N/A Specific Gravity (H2O=1): 1.023 q/cc
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): N/A
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (neat): 10.5
Scooped Density: N/A Solubility in Water: Completely
Appearance and Odor: Green liquid. Reserve Alkalinity: N/A
Product is perfumed (herbal fragrance).
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: None
Hazardous Decomposition Products: None known
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): >5 ml/kg
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Do not landfill. Small (household) quantities may be disposed of via sewer with large
quantities of water. Incineration is preferred where permitted. DISPOSAL IS TO BE PERFORMED IN
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
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MR. CLEAN LIQUID CLEANER MSDS (Continued) Page 4 of 4
SECTION XIV - TRANSPORT INFORMATION
DOT Classification: Mr. Clean Liquid Cleaner is not DOT hazardous and is not regulated under the DOT
Hazardous Materials Regulations (49 CFR, parts 171-180) which govern the safe transport of hazardous materials.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURS) under TSCA 搂 5
No components of Mr. Clean are subject to California Proposition 65.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information
required by the Canadian Products Regulation.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage
to any property resulting from misuse of the controlled product.
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