Version: 1.1
CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
Lion Copolymer Geismar, LLC.urges the recipient of this Safety Data Sheet to study it carefully to become aware of hazards, if any, of the product involved. In
the interest of safety you should (1) notify your employees, agents and contractors of the information on this sheet,(2) furnish a copy to each of your customers for
the product, and (3) request your customers to inform their employees and customers as well.
1. PRODUCT AND COMPANY IDENTIFICATION
Azodicarbonamide with amorphous silica
Chemical name:
Foaming Agent
Use of substance/preparation:
Lion Copolymer Geismar, LLC.
Supplier:
36191 Louisiana Highway 30
Geismar, LA 70734 USA
Lion Copolymer Geismar, LLC.
Manufacturer:
36191 Louisiana Highway 30
Geismar, LA 70734 USA
CHEMTREC : 800-424-9300 (For USA, and Canada)
Emergency telephone
CHEMTREC: 703-527-3887 (For all other Countries)
number:
--
US-225-673-8871 or 225-267-3608
Environmental, Health and
-
Safety Department:
Supply Chain Date of Issue: 06/24/2007
Prepared by
(US) +1 800-535-9960
(Outside of the US) 1 + 225-267-3788
Email: CustomerService@Lioncopolymer.com
2. HAZARDS IDENTIFICATION
Main hazards and effects:
May cause sensitization by inhalation. Risk of explosion if heated under confinement. CLASSIFIED ACCORDING TO CRITERIA OF AUSTRALIAN
NOHSC.
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT HAZARD DANGER SYMBOL(S)
Azodicarbonamide > 99 R42 Xn
CAS# 123-77-3 R44
EINECS/ELINCS# 204-650-8
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Version: 1.1
CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
4. FIRST AID MEASURES
Swallowing
Do not induce vomiting. Rinse mouth and then drink water. Obtain medical attention.
Inhalation
Remove to fresh air. Obtain medical attention.
Skin contact
Remove contaminated clothing. Wash thoroughly with warm water using a mild soap. Obtain medical attention if irritation persists.
Eye contact
Immediately flush eyes with water and continue washing for several minutes. Obtain medical attention if irritation persists.
5. FIRE-FIGHTING MEASURES
Hazardous combustion products
Toxic fumes.
Ammonia.
Oxides of nitrogen.
Oxides of carbon.
Traces of incompletely burned carbon products.
Special fire fighting procedures
Evacuate all personnel from danger area.
Avoid dusting when handling and avoid all possible sources of ignition (spark or flame).
Use water spray to cool fire-exposed containers and structures.
Special protective equipment for firefighters
Self-contained breathing apparatus.
Full protective clothing
Extinguishing media
Suitable: - water spray
- dry chemical
Unusual fire and explosion hazards
Heated containers may explode., Once ignited, this product will burn vigorously and with acceleration.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid all contact.
Environmental precautions
Avoid discharge to sewers or natural waters.
Methods for cleaning up
Avoid dispersion of dust.
Eliminate sources of ignition.
Collect in a suitable container for disposal.
Dispose of waste material in compliance with all federal, state, and local regulations.
Sweep up using non-sparking equipment.
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Avoid dispersion of dust to reduce fire and explosion potential., Take precautionary measures against static discharges.
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CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
STORAGE
Storage requirements
Keep away from heat, sparks and flame., Store in a cool, dry and well-ventilated area., Keep container tightly closed.
Further information on storage
Maximum Storage Temperature:, 80掳 C (176掳 F)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
PERSONAL PROTECTION
Respiratory protection
In case of occurence of dust respiratory protective equipment required.
Hand protection / protective gloves
Chemical resistant protective gloves
Eye protection
Safety glasses with side shields.
Skin protection
Wear protective clothing, such as long sleeves to minimize skin contact.
ENGINEERING CONTROLS
Ventilation
Local exhaust suggested to prevent dust buildup.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Powder
Physical state
Orange-yellow
Color
Characteristic
Odor
Not available
Odor threshold
OTHER PROPERTIES
Not available
Boiling point
190 - 220 掳C
Melting point
374 - 428 掳F
Decomposes
Not available
Solidification
Not available
pH
Not available
Specific gravity (H2O=1)
1.66 g/cm3 at 25 掳C
Density
Vapor pressure
Slightly soluble, Decomposes in alkaline solution.
Solubility in water
No data available.
Solubility in organic solvents
Not available
Partitioning coefficient
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CELOGEN庐 AZ130 Date of Issue: 06/24/2007
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Flash point
Decomposes
Decomposes without ignition., Bulk quantities may self ignite if heated.
Thermal decomposition
Not available
Autoignition temperature
Not available
Upper explosion limits
Not available
Lower explosion limits
Not available
Percent volatiles
10. STABILITY AND REACTIVITY
Stability: This product is stable only when stored at, or below, the recommended maximum temperature.
Incompatible materials:
Metallic compounds
Acids.
Bases.
Strong oxidizing agents.
Hazardous reactions: Keep away from heat.
Hazardous combustion products:
Toxic fumes.
Ammonia.
Oxides of nitrogen.
Oxides of carbon.
Traces of incompletely burned carbon products.
Hazardous polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Component data LD50 - Rat
Azodicarbonamide Result: 6,800 mg/kg
Acute toxicity - Swallowing:
Component data LD50 - Rabbit
Azodicarbonamide Result: > 2,000 mg/kg
Acute toxicity - Skin absorption:
Component data LC50 - Rat
Azodicarbonamide Result: > 200 mg/l
Acute toxicity - Inhalation:
Component data Species: Rabbit
Azodicarbonamide Result: Non irritating.
Skin irritation - Skin contact:
Component data Species: Rabbit
Azodicarbonamide Result: Slight
Eye irritation - Eye contact:
Component data Species: Guinea pigs
Azodicarbonamide Result: Negative
Sensitization:
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CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
Component data Species: Human
Azodicarbonamide Result: Positive
Sensitization:
MUTAGENICITY
Component data Test type: Ames bacterial assay
Azodicarbonamide Result: Positive
Genetic toxicity in vitro - Mutagenicity:
MUTAGENICITY
Component data Test type: Unscheduled DNA synthesis (UDS)
Azodicarbonamide Result: Negative
Genetic toxicity in vitro - Mutagenicity:
MUTAGENICITY
Component data Test type: Chinese Hamster Ovary (CHO)
Azodicarbonamide Result: Negative
Genetic toxicity in vitro - Mutagenicity:
12. ECOLOGICAL INFORMATION
Component ecotoxicology EC50 - Fathead minnow (Pimephales promelas)
Azodicarbonamide Result: > 50 mg/l
Acute toxicity fish: Exposure time: 48 h
Component ecotoxicology EC50 - Water flea (Daphnia magna)
Azodicarbonamide Result: 11 mg/l
Acute toxicity to aquatic invertebrates: Exposure time: 48 h
13. DISPOSAL CONSIDERATIONS
Avoid discharge to sewers and natural waters., Incinerate in a furnace where permitted under national and local
General:
regulations.
14. TRANSPORT INFORMATION
IMDG Classification
Azodicarbonamide
Proper shipping name:
4.1
Class:
UN 3242
UN ID #:
II
Packing group:
ICAO Classification
FORBIDDEN BY AIR.
ADG Classification
Proper shipping name: Azodicarbonamide
Class: 4.1
UN ID #: UN 3242
Packing group: II
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CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
15. REGULATORY INFORMATION
Danger symbol(s) :
Xn Harmful
Risk phrases : CLASSIFIED ACCORDING TO CRITERIA OF AUSTRALIAN
NOHSC.
R42, R44 May cause sensitization by inhalation., Risk of explosion if
heated under confinement.
Safety phrases :
S22, S24, S37 Do not breathe dust., Avoid contact with skin., Wear suitable
gloves.
CHEMICAL INVENTORY
Canada: This product is on the DSL.
Europe: The ingredients of this mixture are on the EINECS inventory.
United States: This product is on the TSCA inventory.
USA: This product is on the AICS inventory.
China: This product is on the IECSC Inventory.
Japan: This product is on the ENCS inventory.
Korea: This product is listed on the Existing Chemicals List (ECL).
Philippines: This product is on the PICCS.
16. OTHER INFORMATION
List of R-phrases used in data sheet. See section 15 for classification details.
Risk phrases : R42 May cause sensitization by inhalation.
R44 Risk of explosion if heated under confinement.
CHEMTREC
Emergency Telephone Numbers
Europe: All European Countries (00) +(1)703 527 3887
Asia Pacific: Australia (0011)+(1)703 527 3887
China, India, Malaysia, New Zealand, North and South Korea,
Philippines, Thailand, Vietnam
Japan (001) (0041) + (1)703 527 3887
Indonesia (001) (008) + (1)703 527 3887
(002)+(1)703 527 3887
(001)(009)+(1)703 527 3887
(001)(002)+(1)03 527 3887
Middle East: (00) + (1) 703 527 3887
Africa: 00) + (1) 703 527 3887
Latin America: All (00) + (1) 703 527 3887
Mexico: All (00) + (1) 703 527 3887
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Version: 1.1
CELOGEN庐 AZ130 Date of Issue: 06/24/2007
Date printed: 06/24/2007
STP Standard temperature and pressure
W/W Weight/Weight
Copyright 2007
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN LION COPOLYMER GEISMAR, LLC.. WE BELIEVE THAT THE INFORMATION CONTAINED
HEREIN IS CURRENT AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE OF THIS
PRODUCT ARE NOT WITHIN THE CONTROL OF LION COPOLYMER GEISMAR, LLC., IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE
PRODUCTS.
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