Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024H Page 1
TE-KA TEAK WOOD CLEANER PART B
This product appears in the following stock number(s):
Last revised: 09/28/05
3024C 3024U 3026C 3026U 3028C 3028U
9/29/2005
Printed:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Tradename: TE-KA TEAK WOOD CLEANER PART B
A two component product. Carefully read MSDSs for both Part A & B.
General use:
Chemical family: Aqueous mineral acid
MANUFACTURER EMERGENCY INFORMATION
ITW Philadelphia Resins Emergency telephone number
130 Commerce Dr. (800) 424-9300
(CHEMTREC):
Montgomeryville, PA 18936
Other Calls: (215) 855-8450
2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure limits
HAZARDOUS CONSTITUENTS
Weight ACGIH OSHA Other
Constituent Abbr. CAS No.
percent TLV PEL Limits
Phosphoric Acid 7664382 1 mg/m3 1 mg/m3
1mg/m^3
20-30
(Canada)
"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American
Conference of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure
Limit."n/e" indicates that no exposure limit has been established. An asterisk (*) indicates a substance whose identity is a trade secret of our supplier
and unknown to us.
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance, form, odor: Light green liquid with slight odor.
WARNING! CONTAINS PHOSPHORIC ACID. CAUSES SEVERE EYE, SKIN AND RESPIRATORY TRACT
IRRITATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE IN WELL VENTILATED AREA. FIRST
AID: INGESTION - RINSE MOUTH WITH WATER. GIVE A GLASS OF MILK. DO NOT INDUCE VOMITING.
EYES - FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET SEEK MEDICAL ATTENTION. SKIN -
WASH THOROUGHLY WITH SOAP AND WATER. KEEP OUT OF REACH OF CHILDREN.
Potential health effects
Skin contact Skin absorption Eye contact Inhalation Ingestion
Primary routes of exposure:
Symptoms of acute overexposure:
Skin: Corrosive. May cause skin irritation and burns. Burning sensation may not be immediate, delaying the awareness
that contact has occurred.
Eyes: Corrosive. May cause burns and permanent eye damage.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024H Page 2
Inhalation:
Respiratory irritant. Can irritate the nose, throat and mucous membranes. Symptoms include headache, nausea,
vomiting, and dizziness.
Ingestion:
May cause burns in the mouth, throat and esophagus. Causing pains in the stomach, difficulty breathing, nausea,
vomiting, diarrhea and convulsions. In severe cases collapse and death may occur.
Effects of chronic overexposure:
Slightly toxic with repeated inhalation or ingestion. May cause upper respiratory disease. Dermatitis may occur from
prolonged or repeated skin contact.
Carcinogenicity -- OSHA regulated: No ACGIH: No National Toxicology Program: No
International Agency for Research on Cancer:No
Cancer-suspect constituent(s) : None
Medical conditions which may be aggravated by exposure:
Skin, eye and respiratory disorders.
4. FIRST AID MEASURES
First aid for eyes:
Immediately flush with large amounts of water for at least 15 minutes. See a physician.
First aid for skin:
Immediately remove contaminated clothing and wash with soap and water. If irritation persists, obtain medical
attention.
First aid for inhalation:
Remove patient to fresh air. Administer oxygen if breathing is difficult. Get medical attention.
First aid for ingestion:
Do NOT induce vomiting. Give patient 2-3 liters of water followed by one glass of milk. Do not give anything by mouth
to an unconscious person. Prevent aspiration of vomit. Immediately consult physician.
5. FIRE FIGHTING MEASURES
Extinguishing media:
Carbon dioxide Dry chemical Foam Alcohol foam
Water
Flash Point (掳F): n/a Method: n/a
Explosive limits in air (percent) -- Lower: n/a Upper: n/a
Special firefighting procedures:
Not combustible. Extinguish fire using agent suitable for surrounding fire.
Unusual fire and explosion hazards:
Evolves flammable/explosive hydrogen gas on contact with most metals.
Hazardous products of combustion:
Toxic fumes of phosphorous oxides during thermal decomposition. Small amounts of oxides of carbon
6. ACCIDENTAL RELEASE MEASURES
Spill control:
Eliminate all ignition sources. Ventilate area. Wear appropriate protective equipment and approved respirator.
Containment:
Dike and contain spill with absorbent material.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024H Page 3
Cleanup:
Contain spill with absorbent material. Sprinkle hydrated lime or soda ash on spill area. Scrape up and remove. Put
into proper containers for disposal.
Special procedures:
Prevent material from contacting any water sources or sewers leading to surface water.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before
eating, drinking, smoking, applying cosmetics, or using toilet facilities.
Launder contaminated clothing and protective gear before reuse. Discard contaminated leather articles. Oxides of
phosphorous are formed during thermal decomposition. Use caution when mixing with base.
Storage:
Store in a cool, dry place with adequate ventilation. Keep away from open flame and high temperatures, alkalies and
most metals. Do not store in direct sunlight. Store above freezing point. Keep containers closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
Ventilation :
Local exhaust ventilation is preferred although good general mechanical ventilation is usually adequate for most
industrial applications. Local exhaust is recommended for confined areas. Sufficient ventilation should be used to
keep concentrations below the established TLVs.
Other engineering controls :
Have emergency shower and eye wash available.
Personal protective equipment
Eye and face protection:
Chemical safety goggles or face shield.
Skin protection:
Chemical resistant rubber gloves and other protective gear as required to prevent skin contact.
Respiratory protection:
Avoid breathing of vapor or spray mist. Use NIOSH approved organic vapor/acid/P100 cartridge mask if vapor/mist is
generated.
9. PHYSICAL AND CHEMICAL PROPERTIES
212
1.5
Specific gravity: Boiling point (掳F):
n/d >1
Vapor density (air = 1):
Melting point (掳F):
Evaporation rate (butyl acetate = 1): < 1
2 at 68 掳F
Vapor pressure (mmHg):
0 Completely
VOC (grams/liter): Solubility in water:
Percent volatile by volume: 0 pH (5% solution or slurry in water): 1.5 - 2.0
100
Percent solids by weight:
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10. STABILITY AND REACTIVITY
This material is chemically stable. Hazardous polymerization will not occur.
Conditions to avoid :
Direct sunlight. Excess heat, or freezing temperatures.
Incompatible materials:
Alkaline mat'l (base, lye, caustic); nitromethane. Fluorides, silicides, carbides, strong oxidizing & reducing agents.
Metals. Sulfides, phosphides, cyanides, acetylides, sulfites.
Hazardous products of decomposition:
Toxic fumes of phosphorous oxides during thermal decomposition. Small amounts of oxides of carbon
Conditions under which hazardous polymerization may occur:
None
11. TOXICOLOGICAL INFORMATION
Acute oral effects: LD50 (rat): Not available.
Acute dermal effects: LD50 (rabbit): Not available.
Not corrosive per DOT test criteria (49 CFR).
Acute inhalation effects: Exposure: 0 hours.
LC50 (rat): Not available.
Eye irritation:
Not available.
Subchronic effects:
Not available.
Carcinogenicity, teratogenicity, and mutagenicity:
Not available.
Other chronic effects:
Not available.
Toxicological information on hazardous chemical constituents of this product:
Oral LD50 Dermal LD50 Inhalation LC50
Constituent
(rat) (rabbit) 4hr, (rat)
Phosphoric Acid 1530 mg/kg 2740 mg/kg n/d
'n/d' = 'not determined'
12 ECOLOGICAL INFORMATION
Ecotoxicity:
No data available.
Mobility and persistence:
No data available.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024H Page 5
Environmental fate:
No data available.
13. DISPOSAL CONSIDERATIONS Please see also Section 15, Regulatory Information.
Waste management recommendations:
Dispose of in accordance with applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
ORM-D : N/A
Non-regulated
Proper shipping name:
N/A
Technical name : LtdQty : N/A
N/A
Hazard class :
N/A
UN number:
N/A
Packing group:
N/A
Emergency Response Guide no.:
N/A
IMDG page number:
Not corrosive per 49 CFR test criteria.
Other:
15. REGULATORY INFORMATION
U.S. Federal Regulations
TSCA
:
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
The following RCRA code(s) applies to this material if it becomes waste:
D002
Regulatory status of hazardous chemical constituents of this product:
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
Phosphoric Acid No No 5000.0 Not required
*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301
Extremely Hazardous Substance list.
**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of
Toxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations .
For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard
classes apply to this material: - Immediate health hazard -- Delayed health hazard -
Canadian regulations
WHMIS hazard class(es) : D2B
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Material Safety Data Sheet
ITW Philadelphia Resins
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16. OTHER INFORMATION
Hazardous Materials Health Flammability Reactivity
Identification System (HMIS)
2* 0 0
ratings:
The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no
other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024R Page 1
TE-KA TEAK CLEANER PART A
This product appears in the following stock number(s):
Last revised: 09/27/05
3024C 3024U 3026C 3026U 3028C 3028U
9/29/2005
Printed:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Tradename: TE-KA TEAK CLEANER PART A
A two component product. Carefully read MSDSs for both Part A & B.
General use:
Chemical family: Aqueous Caustic Solution
MANUFACTURER EMERGENCY INFORMATION
ITW Philadelphia Resins Emergency telephone number
130 Commerce Dr. (800) 424-9300
(CHEMTREC):
Montgomeryville, PA 18936
Other Calls: (215) 855-8450
2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure limits
HAZARDOUS CONSTITUENTS
Weight ACGIH OSHA Other
Constituent Abbr. CAS No.
percent TLV PEL Limits
Sodium Hydroxide 1310732 n/e
2mg/m^3
5-10
"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American
Conference of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure
Limit."n/e" indicates that no exposure limit has been established. An asterisk (*) indicates a substance whose identity is a trade secret of our supplier
and unknown to us.
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance, form, odor: Clear liquid with mild odor.
DANGER! EXTREMELY CORROSIVE. CONTAINS SODIUM HYDROXIDE. CAUSES SEVERE EYE AND SKIN
BURNS. RESPIRATORY TRACT IRRITANT. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT
TAKE INTERNALLY. FIRST AID: INGESTION - RINSE MOUTH WITH WATER. GIVE A GLASS OF MILK. DO NOT
INDUCE VOMITING. EYES - FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET SEEK MEDICAL
ATTENTION. SKIN - WASH THOROUGHLY WITH SOAP AND WATER. KEEP OUT OF REACH OF CHILDREN.
Potential health effects
Skin contact Skin absorption Eye contact Inhalation Ingestion
Primary routes of exposure:
Symptoms of acute overexposure:
Skin: Corrosive action causes burns and frequently deep ulceration with subsequent scarring. Prolonged contact
destroys tissue. Can cause irritant dermatitis.
Eyes: Causes severe burns; small quantities can result in permanent damage and/or loss of vision.
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ITW Philadelphia Resins
Part No.: 3024R Page 2
Inhalation:
Inhalation of mists can cause damage to the upper respiratory tract and to lung tissue depending upon the severity of
exposure. Effects can range from mild irritation of mucous membranes to severe pneumonitis and destruction of lung
tissue.
Ingestion:
Can cause serious damage to the mucous membranes or other tissues with which contact is made, and may be fatal.
Effects of chronic overexposure:
The effect of long-term, low-level exposures to this product have not been determined. Safe handling of this material
on a long-term basis should emphasize the avoidance of all effects from repetitive acute exposures.
Carcinogenicity -- OSHA regulated: No ACGIH: No National Toxicology Program: No
International Agency for Research on Cancer:No
Cancer-suspect constituent(s) : None
Medical conditions which may be aggravated by exposure:
None known
4. FIRST AID MEASURES
First aid for eyes:
Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Rinse continuously
with water while on way to get medical attention.
First aid for skin:
Remove contaminated clothing and contaminant. Wash with soap and water. Continue washing with water until slick
skin feeling is gone. Get immediate medical attention.
First aid for inhalation:
Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get
immediate medical attention.
First aid for ingestion:
Do NOT induce vomiting. If conscious drink large quantities of water or acidic beverage (tomato juice, orange juice,
carbonated soft drinks). Do not give anything by mouth to an unconscious person. Prevent aspiration of vomit. If
vomiting occurs give additional water. Get immediate medical attention.
5. FIRE FIGHTING MEASURES
Extinguishing media:
Carbon dioxide Dry chemical Foam Alcohol foam
Water
Flash Point (掳F): None Method:
Explosive limits in air (percent) -- Lower: N/A Upper: N/A
Special firefighting procedures:
Use appropriate extinguishing media for surrounding fire.
Unusual fire and explosion hazards:
Contact with some metals, particularly magnesium, aluminum and galvanized zinc can rapidly generate hydrogen
(explosive).
Hazardous products of combustion:
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ITW Philadelphia Resins
Part No.: 3024R Page 3
6. ACCIDENTAL RELEASE MEASURES
Spill control:
Avoid personal contact. Eliminate ignition sources. Ventilate area. Wear protective equipment.
Containment:
Use absorbent material
Cleanup:
Neutralize with dilute acid. Absorb material on an inert absorbent material and place in a properly labeled container
for disposal.
Special procedures:
Do not allow this material to be released to sewers or waterways.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before
eating, drinking, smoking, applying cosmetics, or using toilet facilities. Avoid breathing vapors and mists. Launder
contaminated clothing and protective gear before reuse. Discard contaminated leather articles. Use caution when
mixing with acids. Do not add to warm or hot water. Hazardous carbon monoxide can form upon contact with food
and beverage products in enclosed vessels and can cause death.
Storage:
Store in a cool, dry place with adequate ventilation. Keep away from open flame and high temperatures. Do not store
in direct sunlight. Store above freezing point. Keep containers closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
Ventilation :
General exhaust should be sufficient under most uses. Local exhaust when dusts or mists are generated. Sufficient
ventilation should be used to keep concentrations below the established TLVs.
Other engineering controls :
Have emergency showers and eye wash available.
Personal protective equipment
Eye and face protection:
Chemical goggles or face shield.
Skin protection:
Nitrile, neoprene, or natural rubber gloves and other protective gear as required to prevent skin contact.
Respiratory protection:
None required for normal use. If mists are generated use a NIOSH approved filter respirator (P100).
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ITW Philadelphia Resins
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9. PHYSICAL AND CHEMICAL PROPERTIES
212
2.1
Specific gravity: Boiling point (掳F):
n/d >1
Vapor density (air = 1):
Melting point (掳F):
Evaporation rate (butyl acetate = 1): slower than ether
n/d at 0 掳F
Vapor pressure (mmHg):
n/d complete
VOC (grams/liter): Solubility in water:
Percent volatile by volume: 90 pH (5% solution or slurry in water): > 12
10
Percent solids by weight:
10. STABILITY AND REACTIVITY
This material is chemically stable. Hazardous polymerization will not occur.
Conditions to avoid :
Reaction with various food sugars may form carbon monoxide.
Incompatible materials:
Organic mat'ls & acids may cause violent reactions. Contact with magnesium, aluminum, zinc (galvanized), tin,
chromium, brass & bronze generates hydrogen gas. Water. Carbon dioxide
Hazardous products of decomposition:
When heated to decomposition it emits toxic fumes of Na2O.
Conditions under which hazardous polymerization may occur:
none
11. TOXICOLOGICAL INFORMATION
Acute oral effects: LD50 (rat): Not available.
Acute dermal effects: LD50 (rabbit): Not available.
Acute inhalation effects: Exposure: hours.
LC50 (rat): Not available.
Eye irritation:
Not available.
Subchronic effects:
Not available.
Carcinogenicity, teratogenicity, and mutagenicity:
Not available.
Other chronic effects:
Not available.
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ITW Philadelphia Resins
Part No.: 3024R Page 5
Toxicological information on hazardous chemical constituents of this product:
Oral LD50 Dermal LD50 Inhalation LC50
Constituent
(rat) (rabbit) 4hr, (rat)
Sodium Hydroxide 500 mg/kg n/d n/d
'n/d' = 'not determined'
12 ECOLOGICAL INFORMATION
Ecotoxicity:
Not available.
Mobility and persistence:
Not available.
Environmental fate:
Not available.
13. DISPOSAL CONSIDERATIONS Please see also Section 15, Regulatory Information.
Waste management recommendations:
Dispose of in accordance with all federal, state and local regulations.
14. TRANSPORT INFORMATION
ORM-D :
Proper shipping name: Sodium hydroxide solution
N/A
Technical name : LtdQty :
8
Hazard class :
1824
UN number:
II
Packing group:
154
Emergency Response Guide no.:
N/A
IMDG page number:
Other:
15. REGULATORY INFORMATION
U.S. Federal Regulations
TSCA
:
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
The following RCRA code(s) applies to this material if it becomes waste:
D002
Regulatory status of hazardous chemical constituents of this product:
MSDS0619
Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3024R Page 6
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
Sodium Hydroxide No No 1000.0 Not required
*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301
Extremely Hazardous Substance list.
**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of
Toxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations .
For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard
classes apply to this material: - Immediate health hazard -- Reactivity hazard -
Canadian regulations
WHMIS hazard class(es) : E
All components of this product are on the Domestic Substances List.
16. OTHER INFORMATION
Hazardous Materials Health Flammability Reactivity
Identification System (HMIS)
3 0 1
ratings:
The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no
other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document.
MSDS0619
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