MATERIAL SAFETY DATA SHEET
I PRODUCT IDENTIFICATION
MANUFACTURED FOR: FOR CHEMICAL EMERGENCY
L&W Stone Corporation
Spill, Leak, Fire Exposure or Accident
1036 South Street
CALL INFOTRAC 鈥? Day or Night:
Orland, CA 95963 800/535-5053
Outside the United States Call Collect:
(530) 865-5085 352/323-3500
PRODUCT TRADE NAME: Green Clean-200鈩?
II HAZARDOUS INGREDIENTS
ACGIH OSHA
CHEMICAL NAME (COMMON NAME) CAS NO. NFPA CODE
TLV/TWA PEL/TWA
Linear Primary Alcohol
Alcohol Ethoxylates 34398-01-1 Not Available Not established Not established
Ethoxylates
Chelating agent * * Not Available Not established Not established
* Specific chemical identity and percentage content withheld pursuant to OSHA regulations.
III PHYSICAL DATA
VAPOR
BOILING POINT VAPOR DENSITY EVAPORATION RATE
PRESSURE
(掳F) (Air = 1) (Butyl Acetate = 1)
(mm Hg)
< 0.1 (@ 100掳F)
Linear Primary Alcohol Ethoxylates > 350 掳F 15 N/A
Chelating agent > 100 掳C Not Available Not Available Not Available
SPECIFIC SOLUBILITY APPEARANCE AND
pH
GRAVITY IN WATER ODOR
Clear green liquid, fresh,
Green Clean-200鈩? * 1.07 10.5 100%
clean odor
*Typical
IV FIRE AND EXPLOSION HAZARD DATA
EMERGENCY OVERVIEW
Green Clean-200鈩? is a clear green liquid with a fresh, clean odor. Contact with the eyes or skin may result in irritation. Always wear
appropriate personal protective equipment when using this product.
FLASH POINT (METHOD): >212掳F (ASTM D 3278)
FLAMMABLE LIMITS: Not applicable.
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical, or CO2
SPECIAL FIRE FIGHTING PROCEDURES: Fire fighters should be equipped with self-contained breathing apparatus and turn-out
gear.
UNUSUAL FIRE AND EXPLOSION HAZARDS: There are no known unusual fire or explosion hazards.
V HEALTH HAZARD DATA
PRIMARY ROUTES OF EXPOSURE: Eye and skin contact, as well as ingestion.
CARCINOGEN INFORMATION:
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Pre-existing skin and eye disorders may be aggravated by exposure
to this product.
EFFECTS OF OVEREXPOSURE: Acute: Contact with eyes and skin may result in irritation. Ingestion may result in gastric
disturbances. Chronic: None anticipated.
EYE CONTACT: May irritate eyes, producing redness and swelling of the conjunctiva.
SKIN CONTACT: This product may cause skin irritation.
INHALATION: Mists or vapors may be irritating to upper respiratory tract, although this is not expected to be a relevant route of
exposure.
INGESTION: Swallowing large quantities may cause nausea and vomiting, as well as other gastric disturbances.
EMERGENCY AND FIRST AID PROCEDURES:
EYE CONTACT: Immediately flush exposed area with water for at least 15 minutes, holding eyelids apart to ensure flushing of the
entire eye surface. Get immediate medical attention. If physician is not immediately available, continue flushing with water.
Do not use chemical antidote.
SKIN CONTACT: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention.
Remove contaminated clothing. Launder contaminated clothing before reuse.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give
oxygen. Get medical attention.
INGESTION: Do not give liquids if victim is unconscious or very drowsy. Otherwise, give no more than 2 glasses of water and induce
vomiting by giving 30 cc (2 Tablespoons) syrup of Ipecac.* If Ipecac is unavailable, give two glasses of water and induce
vomiting by touching finger to the back of the victim鈥檚 throat. Keep victim鈥檚 head below hips while vomiting. Get medical
attention.
* If victim is a child, give no more than one glass of water and 15 cc (1 Tablespoon) syrup of Ipecac. If symptoms such as
loss of gag reflex, convulsions or unconsciousness occur before emesis, gastric lavage should be considered following
intubation with a cuffed endotracheal tube.
VI REACTIVITY DATA
STABILITY: Stable.
CONDITIONS TO AVOID: Extreme heat.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong acids and strong oxidizing agents.
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS: Carbon monoxide and other unidentified organic compounds may
be formed during combustion.
VII SPILL OR LEAK PROCEDURES
SPILL, LEAK, WASTE DISPOSAL PROCEDURES: CAUTION: Wear appropriate protective safety equipment to prevent skin and
eye contact. Dike area to contain spilled material and use inert absorbent or a wet-vac to pick up material for disposal.
WASTE DISPOSAL METHODS: Based on Federal EPA solid waste definitions and waste water pretreatment guidelines, rinse water
generated during the use of this material can be disposed of to sanitary sewer systems in most regions with approval of
treatment plant operators. This material should not be permitted to enter storm sewers or surface waterways without specific
permission of regulatory authorities. The product as supplied is not classified as a hazardous waste under federal
regulations. Consult appropriate federal, state, and local regulatory agencies to ascertain proper disposal procedures.
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VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: NIOSH/MSHA approved respiratory protection should be worn in the absence of proper good
ventilation and proper environmental control. If product mist is present, wear an approved dust/mist respirator to avoid irritant
effect to lungs and upper respiratory tract. Respiratory protection program must be in accordance with 29 CFR 1910.134.
VENTILATION: Sufficient to maintain airborne concentrations as low as possible.
PROTECTIVE CLOTHING: Wear protective clothing and rubber boots as necessary to minimize contact.
PROTECTIVE GLOVES: Natural rubber or PVC.
EYE PROTECTION: Close fitting chemical safety goggles. Do not wear contact lenses because they may contribute to the severity of
an eye injury. A face shield may also be used if a splashing hazard exists.
OTHER PROTECTIVE EQUIPMENT: Eyewash should be accessible from work area. Provide fresh water for body rinsing. Personal
protective clothing and use of equipment must be in accordance with 29 CFR 1910.133 and 29 CFR 1910.132.
IX SPECIAL PRECAUTIONS
WORK PRACTICES: Proper work practices and planning should be utilized to avoid contact with workers, passersby, and non-
masonry surfaces. Test all surfaces that may come in contact with product or rinse water to determine compatibility. Rinse
off unintentional over spray with large quantities of clean water. Grass and plantings may be protected by running sprinklers
to supply a continuous rinse. Do not atomize during application. Beware of wind drift. Always follow published application
rates. See the Product Data sheet and label for specific precautions to be taken during use. Smoking, eating and drinking
should be discouraged during the use of this product. Wash hands before breaks and at the end of a shift.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Wear appropriate safety equipment and clothing. Do not get in
eyes, on skin, or on clothing. Do not take internally. Avoid breathing mist. Can cause irritation. Store in a cool, dry, well-
ventilated place. Separate from acids and organic peroxides.
Never touch eyes or face with hands or gloves that may be contaminated with this product.
Keep containers closed when not dispensing product. Use care around spilled material because it will be slippery. Treat
empty containers as if they were full.
OTHER PRECAUTIONS: Wash thoroughly after handling. Do not eat, drink, or smoke in work areas.
X REGULATORY INFORMATION
SHIPPING: This product is not regulated in domestic or international shipment.
NATIONAL MOTOR FREIGHT CLASSIFICATION: NMFC # 48580 Sub 3 Class Rate: 55
SARA 313 REPORTABLE:
CHEMICAL NAME CAS UPPERBOUND CONCENTRATION % BY WEIGHT
NA - Contains no chemicals listed under SARA 313.
XI OTHER
MSDS Status: Date of Revision: June 3, 2004
For Product Manufactured After: June 1, 2004
Changes: New product.
Item #: PSC41065
Approved By: Regulatory Department
Green Clean-200鈩? - Page 3 of 4
DISCLAIMER:
The information contained on the Material Safety Data Sheet has been compiled from data considered accurate. This data is
believed to be reliable, but it must be pointed out that values for certain properties are known to vary from source to source. L
& W Stone Corporation expressly disclaims any warranty express or implied as well as any liability for any injury or
loss arising from the use of this information or the materials described. This data is not to be construed as absolutely
complete since additional data may be desirable when particular conditions or circumstances exist. It is the responsibility of
the user to determine the best precautions necessary for the safe handling and use of this product for his unique application.
This data relates only to the specific material designated and is not to be used in combination with any other material. Many
federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused
material. It is the purchaser's responsibility to familiarize himself with all applicable regulations.
DATE OF PREPARATION: June 3, 2004
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