MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 1/6
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK FLEXICOLOR Bleach III Replenisher, Part B
Product code: 8214637 - Part B
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6286
2. Hazards identification
CONTAINS: Acetic acid (64-19-7)
WARNING!
CAUSES SKIN AND EYE IRRITATION
DUST, MIST OR VAPOUR IRRITATING TO THE EYES AND RESPIRATORY TRACT
HMIS II Hazard Ratings:
Health - 2, Flammability - 1, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 1, Flammability - 1, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
80 - 85 Water (7732-18-5)
5 - 10 Acetic acid (64-19-7)
1- 5 Ferric ammonium propylenediaminetetraacetic acid (111687-36-6)
3 Ammonium nitrate (6484-52-2)
<1 Ammonium acetate (631-61-8)
4. First aid measures
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 2/6
Inhalation: If symptomatic, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before re-use. Destroy or thoroughly clean contaminated shoes.
Ingestion: Drink 1-2 glasses of water. Seek medical attention. Never give anything by mouth to an
unconscious person.
Notes to physician:
Symptoms: If signs and symptoms of cyanosis are present, treat for methemoglobinemia.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: Carbon oxides nitrogen oxides (NOx) (see also Hazardous
Decomposition Products section).
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Flush into sewer with plenty of water. Otherwise, absorb spill with vermiculite
or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove
residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 3/6
Chemical Name Regulatory List Value Type Value
Acetic acid ACGIH Time Weighted Average (TWA): 10 ppm
ACGIH Short Term Exposure Limit (STEL): 15 ppm
OSHA Z1 PEL: 10 ppm 25 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: full-face organic
vapour cartridge. A respirator must be worn if hazardous decomposition products are likely to be or have
been released. Respirator type: full-face positive-pressure air-supplied. See Stability and Reactivity
Section. If respirators are used, a program should be instituted to assure compliance with OSHA
Standard 29CFR 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: green
Odour: vinegar
Specific gravity: 1.05
Vapour pressure (at 20.0 掳C (68.0 掳F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 85 - 95 %
Boiling point/range: > 100.0 掳C (> 212.0 掳F)
Water solubility: complete
pH: 4.1
Flash point: None.
10. Stability and reactivity
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 4/6
Stability: Stable
Incompatibility: strong bases, sodium hypochlorite (bleach), oxidizing agents. Contact with sodium
hypochlorite (bleach) may form chloramine (toxic gas).
Hazardous decomposition products: ammonia, chloramine.
Hazardous Polymerization: Hazardous polymerization does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Ferric ammonium propylenediaminetetraacetic acid. This compound can chelate
metals and may alter calcium and other cation balances.
Contains: Ammonium nitrate. Under some circumstances methemoglobinemia may occur
when nitrates are converted by bacteria in the stomach to nitrites.
Inhalation: High vapour concentrations may cause irritation.
Eyes: Causes irritation.
Skin: Causes irritation.
Ingestion: Expected to be a low ingestion hazard. May cause irritation of the gastrointestinal tract.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 114 g/l
BOD (approximate): 57 g/l
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 5/6
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
The information given below is provided to assist in documentation. It may supplement the information on
the package. The package in your possession may carry a different version of the label depending on the
date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be
subject to specific regulatory exceptions. Please consult the product packaging for further details.
UN Number: UN3265
IATA:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s. (Acetic acid)
Class: 8
Packaging group: III
UN Number: UN3265
IMDG:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(Acetic acid)
Class: 8
Packaging group: III
UN Number: UN3265
US DOT:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packaging group: III
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): none
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: Ammonium nitrate (as
a source of aqueous ammonia), Ammonium acetate (as a source of aqueous ammonia)
16. Other information
US/Canadian Label Statements:
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2005
Z17000000175/Version: 1.0
Print Date: 12/28/2005
Page: 6/6
CONTAINS: Acetic acid (64-19-7)
WARNING!
CAUSES SKIN AND EYE IRRITATION
DUST, MIST OR VAPOUR IRRITATING TO THE EYES AND RESPIRATORY TRACT
Avoid contact with eyes, skin, and clothing.
Avoid breathing mist or vapour.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: In case of contact, immediately flush eyes and skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical attention.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical, carbon dioxide (CO2).
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-1, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 1/6
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK FLEXICOLOR Bleach III Replenisher, Working Solution
Product code: 8214637 - Working Solution
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: None.
2. Hazards identification
LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING
HMIS II Hazard Ratings:
Health - 1, Flammability - 0, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 0, Flammability - 0, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
85 - 90 Water (7732-18-5)
1- 5 Acetic acid (64-19-7)
1- 5 Ferric ammonium propylenediaminetetraacetic acid (111687-36-6)
1- 5 Ammonium acetate (631-61-8)
1- 5 Ammonium bromide (12124-97-9)
1- 5 Ammonium nitrate (6484-52-2)
4. First aid measures
Inhalation: If symptomatic, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 2/6
Eyes: Any material that contacts the eye should be washed out immediately with water. Get medical
attention if symptoms occur.
Skin: Wash off with soap and water. Get medical attention if symptoms occur.
Ingestion: Drink 1 or 2 glasses of water. Get medical attention. Drink 1-2 glasses of water. Seek
medical attention.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: None (noncombustible) (see also Hazardous Decomposition
Products section).
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Flush into sewer with plenty of water. Otherwise, absorb spill with vermiculite
or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove
residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Acetic acid ACGIH Time Weighted Average (TWA): 10 ppm
ACGIH Short Term Exposure Limit (STEL): 15 ppm
OSHA Z1 PEL: 10 ppm 25 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 3/6
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. If respirators are used, a program
should be instituted to assure compliance with OSHA Standard 29CFR 1910.134 and 29CFR1910.1048.
Eye protection: It is a good industrial hygiene practice to minimize eye contact. Wear safety glasses
with side shields (or goggles).
Skin and body protection: It is a good industrial hygiene practice to minimize skin contact. For
operations where prolonged or repeated skin contact may occur, impervious gloves should be worn.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: colorless
Odour: slight vinegar
Specific gravity: 1.1
Vapour pressure: 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 85 - 95 %
Boiling point/range: > 100.0 掳C (> 212.0 掳F)
Water solubility: complete
pH: 4.5
Flash point: none, noncombustible liquid
10. Stability and reactivity
Stability: Stable
Incompatibility: strong bases, sodium hypochlorite (bleach), oxidizing agents. Contact with sodium
hypochlorite (bleach) may form chloramine (toxic gas).
Hazardous decomposition products: Carbon oxides, nitrogen oxides (NOx), chloramine, ammonia.
Hazardous Polymerization: Hazardous polymerization does not occur.
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 4/6
11. Toxicological information
Effects of Exposure
General advice:
Contains: Ferric ammonium propylenediaminetetraacetic acid. This compound can chelate
metals and may alter calcium and other cation balances.
Contains: Ammonium nitrate. Under some circumstances methemoglobinemia may occur
when nitrates are converted by bacteria in the stomach to nitrites.
Inhalation: Expected to be a low hazard for recommended handling.
Eyes: No specific hazard known. May cause transient irritation.
Skin: Expected to be a low hazard for recommended handling.
Ingestion: Expected to be a low hazard for recommended handling.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 76 g/l
BOD (approximate): 39 g/l
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 5/6
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): none
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: Ammonium nitrate (as
a source of aqueous ammonia), Ammonium bromide (as a source of aqueous ammonia), Ammonium
acetate (as a source of aqueous ammonia)
16. Other information
US/Canadian Label Statements:
LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING
Avoid prolonged or repeated breathing of mist or vapour.
Avoid contact with eyes, skin, and clothing.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: Treat symptomatically. Get medical attention if symptoms occur.
Keep out of reach of children.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-1, F-0, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 06/01/2005
000000013549/Version: 1.0
Print Date: 12/28/2005
Page: 6/6
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