SAFETY DATA SHEET 1st. ed. 15.06.07
HANS O. MAHN & CO. KG
Printed 27.11.2007
acc 2001/58/EG
Page: 1/1
Rollei ATP DC Entwickler
1. Substance/ Indications for Preparation and Producer/ Distributor
a) Product Details:
Trade name: Rollei ATP DC Developer
b) Producer and Distributor:
Producer: SPUR, Dipl.-Ing H. Schain + Partner,
Johannes - Haack-Str. 2
D-52379 Langerwehe
GERMANY
Phone: +49 (0) 2423 6198 Fax: +49 (0) 2423 406980
E-mail: schain@spur-photo.com
Distributor: Hans O. Mahn & Co. KG
Photo Division, Maco Photo Products
Brookstieg 4
D-22145 Stapelfeld
Phone: +49 (0) 40 2370 0888 Fax: +49 (0) 40 2370 08 488
Email: photo@mahn.net
Assistance and Information: Phone +49 (0) 40 2370 0888
Emergencies: Phone +49 (0) 30 19240
Advice Centre for Symptoms of Poisoning and Embryonic
Toxicology in Berlin, Germany
2. Composition/ Ingredients
a) Harmful Ingredients
(Gravimetric Proportions of Substance in % - CAS-No. - Symbol and Risk
Phrases of Pure Substance)
5-20 % Sodium sulfite | 7757-83-2 | Xi | R 36/ 37/ 38
1-10 % Diethyleneglycol | 111-46-6 | Xn | R 20/ 21/ 22
0.1-1 % Potassium thiocyanate | 333-20-0 | Xn | R 20/ 21/ 22-32
0,1 -3 % Potassium hydroquinone sulphonate | 21799-87-1 | Xi | R 36/ 38
0,1 - 2 % 1-Phenyl-3-pyrazolidinone | 92-43-3 | Xn | R 22
0.1-2 % Hydroxy-methyl-phenidone | 13047-13-7| Xn | R 36/ 37/ 38
0.1-2 % Sodium hydroxide | 1310-73-2 | C | R 35
b) Description:
Developer for the continous tone developing of document copy films
3. Possible Risks
Irritates eyes and skin. Contact with skin can lead to sensibilisation. Harmful if swallowed.
24 hour transportation emergency telephone number: Chemtrec 800-424-9300
SAFETY DATA SHEET 1st. ed. 15.06.07
HANS O. MAHN & CO. KG
Printed 27.11.2007
acc 2001/58/EG
Page: 2/2
Rollei ATP DC Entwickler
4. First Aid
a) If inhaled: casualty to lie down quietly and to be exposed to fresh air. If symptoms persist
consult a doctor.
b) Eye contact: rinse with plenty of water and consult a doctor
c) Skin contact: rinse thoroughly with plenty of water
d) If swallowed: casualty to drink plenty of water. Do not under any circumstances cause casualty
to vomit - Vomiting should only be triggered off by the casualty himself when he is fully
conscious. If casualty is unconscious, do not under any circumstances insert anything into his
mouth or pour anything down his throat. Consult a doctor.
e) Special information for doctor: none
5. Firefighting
a) Suitable extinguishing agents: water, foam, slaked lime
b) Extinguishing agents unsuitable for safety reasons: none
c) Special risks: dangerous fumes in case of fire: sulphur dioxide
d) Special safety precautions: do not inhale explosion or incendiary gas; wear breathing apparatus
a protective clothing
6. Unintentional Release
a) Precautions regarding persons: use breathing apparatus if exposed to vapours/ dust/ aerosol
b) Measures for environmental protection: keep away from surface or ground water
c) Cleaning: take up with inert absorbent and collect in suitable containers, label according to
refuse laws, and then dispose of.
d) Additional hints: rinse residue with water
7. Handling and Storage
a) Hints for secure handling: avoid long-term and repeated contact with skin; no other special
measures are required if product is handled correctly.
b) Hints for protection against fire and explosion: no special measures required
c) Requirements regarding store rooms and containers: use a floor tub without drain. Keep
container closed.
d) Hints for storage: do not store together with incompatible substances and lining materials.
e) Ventilation: provide for good ventilating. Adapt ventilation to conditions of work environment.
SAFETY DATA SHEET 1st. ed. 15.06.07
HANS O. MAHN & CO. KG
Printed 27.11.2007
acc 2001/58/EG
Page: 3/3
Rollei ATP DC Entwickler
e) Further details as to conditions of storage: none
8. Restriction of Exposition and Personal Equipment for Protection
a) Hints for layout of technical installations: none
b) Ingredients with limits to be observed: sulphur dioxide 2ppm (MAK 1993)
c) Breathing apparatus: not necessary with sufficient ventilation
d) Eye protection: wear protective goggles
e) Hand protection: wear protective gloves
f) Body protection: wear light protective clothing made of synthetic material
g) Additional hint: do not eat, drink or smoke while at work.
9. Physical and Chemical Details
a) physical state: liquid
b) colour: light yellow
c) smell: specific
d) density: 1.07
e) steam pressure at 20掳 unknown
C:
f) boiling point: > 100掳
C
g) solubility in water: 100%
h) pH value: 11
i) flash point: n.a.
j) inflammability: n.a.
k) temperature of ignition: n.a.
l) self-inflammability: n.a.
m) incendiary features: n.a.
n) limits of explosion (upper or lower respectively): n.a.
o) viscosity at 20掳 unknown
C:
SAFETY DATA SHEET 1st. ed. 15.06.07
HANS O. MAHN & CO. KG
Printed 27.11.2007
acc 2001/58/EG
Page: 4/4
Rollei ATP DC Entwickler
10. Stability and Reactivity
a) Stability: constant
b) Incompatibility: reactions with strong acids, alkali and oxidants should be avoided
c) Dangerous substances produced by decomposition: sulphur oxides
d) Health-damaging polymerisation: n.a.
11. Toxicity
a) LD 50 (mouse,oral): 6,232 mg/ kg; (rat, intravenous): 874 mg/kg
b) The product itself was not tested for its toxicological effects; the above statements have been
deducted from the features of single components and ingredients of the product respectively.
c) The product does not contain any substances labelled toxic (symbol: T or T+), and also no
Hydroquinone.
12. Ecofriendliness
a) Degree of water pollution: 2 [author's estimate]
b) The preparation is alkaline and might be harmful to the environment. The product itself
has not been tested as to its ecofriendliness. All details stated are deducted from the features of
single components or ingredients respectively.
13. Disposal
a) The legal provisions relating to water and refuse must be complied with. When disposing of
concentrates (in Germany) you must state the refuse key nr. 090101.
b) The introduction into the sewerage system of used preparation is subject to local laws and may
only be possible after neutralisation.
c) Chemicals containers have to be emptied entirely and rinsed with water. Add rinsing solution to
preparation.
d) Non-contaminated packaging can be re-used.
e) Contaminated packaging can be re-used after emptying and appropriate cleaning.
14. Transport
a) Air Transport - International Civil Aviation Organization (ICAO)
No entry (no dangerous good)
b) Sea Transport - International Maritime Dangerous Goods (IMDG)
No entry (no dangerous good)
c) Land Transport - GGVS/ ADR
No entry (no dangerous good)
SAFETY DATA SHEET 1st. ed. 15.06.07
HANS O. MAHN & CO. KG
Printed 27.11.2007
acc 2001/58/EG
Page: 5/5
Rollei ATP DC Entwickler
15. Regulations
a) Labelling according to EC-Regulations/ Dangerous Substances Ordinance
Symbol: Xi | Risk Phrases: 22-36/ 38-43 | Safety Phrases: 2-24-26-46
Contains: 0,1-3 % Hydroquinone sulfonate (potassium salt)
b) National Regulations
VfB (Ordinance regarding flammable liquids): n.a.
WGK (Degree of water pollution): 2
16. Disclaimer
The particulars as stated in the present Safety Data Sheet are according to, and reflect our current state
of knowledge. They have been provided on a voluntary basis so as to increase security and avoid
damage. This Sheet does not constitute a guarantee of any kind. Any liability in this context is limited
to the monetary value of the product we have delivered, and will only be incurred by us if the named
product is faulty.
n. a.: not applicable
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