MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2006
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Print Date: 07/10/2006
Page: 1/7
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK XTOL Developer, Part A
Product code: 8751752 - Part A
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6311
2. Hazards identification
CONTAINS: Sodium sulphite (7757-83-7), Sodium metaborate, tetrahydrate (10555-76-7), 4-
hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-13-7)
WARNING!
MAY BE HARMFUL IF INHALED, ABSORBED THROUGH SKIN, OR SWALLOWED
DUST IRRITATING TO RESPIRATORY TRACT
CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
HMIS III Hazard Ratings: Health - 2, Flammability - 0, Physical Hazard - 0
NFPA Hazard Ratings: Health - 2, Flammability - 0, Instability - 0
NOTE: HMIS III and NFPA 704 (2001) hazard indexes involve data review and interpretation that may
vary among companies. They are intended only for rapid, general identification of the magnitude of the
potential hazards. An asterisk (*), in the HMIS III health field, designates potential chronic or target organ
hazards. To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
90 - 95 Sodium sulphite (7757-83-7)
5 - 10 Sodium metaborate, tetrahydrate (10555-76-7)
1- 5 Pentetic acid, pentasodium salt (140-01-2)
0.1 - 1 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-13-7)
4. First aid measures
MATERIAL SAFETY DATA SHEET
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Inhalation: If inhaled, move to fresh air. Get medical attention.
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Destroy or
thoroughly clean contaminated shoes. Wash contaminated clothing before re-use.
Ingestion: If swallowed, only induce vomiting as directed by medical personnel. Never give anything by
mouth to an unconscious person. Call a physician or poison control center immediately.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: None (noncombustible), (see also Hazardous Decomposition
Products section).
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Shovel into suitable container for disposal. Clean surface thoroughly to
remove residual contamination.
7. Handling and storage
Personal precautions: Do not breathe dust at concentrations greater than the exposure limits. Keep
container closed. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash
thoroughly after handling.
Prevention of Fire and Explosion: No special technical protective measures required.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Sodium metaborate, ACGIH time weighted average 2 mg/m3
tetrahydrate
Form of exposure: Inhalable fraction.
ACGIH Short term exposure limit 6 mg/m3
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Form of exposure: Inhalable fraction.
4-hydroxymethyl-4- EK HPG Time Weighted Average (TWA): 0.2 mg/m3
methyl-1-phenyl-3-
pyrazolidinone
Sulphur dioxide ACGIH time weighted average 2 ppm
ACGIH Short term exposure limit 5 ppm
OSHA Z1 Permissible exposure limit 5 ppm 13 mg/m3
Ventilation: Use process enclosures, local exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits. Controls should be sufficient so that applicable
occupational exposure limits are not exceeded.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: N95 Particulate
Filter. A respirator should be worn if hazardous decomposition products are likely to be or have been
released. Respirator type: Acid gas. If respirators are used, a program should be instituted to assure
compliance with applicable federal, state, commonwealth, provincial, or local laws and regulations.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: solid (powder)
Colour: off-white
Odour: odourless
Specific gravity: No data available
Vapour pressure: negligible
Vapour density: No data available
Volatile fraction by weight: negligible
Melting point/range: No data available
Water solubility: complete
pH: No data available
Flash point: does not flash
10. Stability and reactivity
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Stability: Stable.
Incompatibility: Acids. Contact with strong acids liberates sulphur dioxide.
Hazardous decomposition products: sulphur oxides.
Hazardous Polymerization: Hazardous polymerization does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Sodium metaborate, tetrahydrate. Based on repeated-dose ingestion studies in
animals, may cause adverse reproductive and developmental effects. However, the doses
administered were many times those to which humans would normally be exposed.
Contains: 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone. May cause adverse
reproductive effects such as infertility based on animal data. Based on repeated-dose ingestion
studies in animals, this chemical may cause blood, testicular, and adverse reproductive effects.
Inhalation: May be harmful if inhaled. Airborne dust irritating. In contact with strong acids or if
heated, sulphites may liberate sulphur dioxide gas. Sulphur dioxide gas is irritating to the respiratory
tract. Some asthmatics or hypersensitive individuals may experience difficult breathing.
Eyes: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through skin. May be absorbed in toxic
amounts through damaged or abraded skin. May cause allergic skin reaction based on human
experience.
Ingestion: May be harmful if swallowed. Some asthmatics or sulfite-sensitive individuals may
experience wheezing, chest tightness, stomach upset, hives, faintness, weakness and diarrhea.
Data for Sodium sulphite (CAS 7757-83-7):
Acute Toxicity Data:
鈥? Oral LD50 (rat): > 1,600 mg/kg
鈥? Skin irritation: none
鈥? Eye irritation: slight; washing palliative
Data for Pentetic acid, pentasodium salt (CAS 140-01-2):
Acute Toxicity Data:
鈥? Oral LD50 (male rat): 3,200 mg/kg
鈥? Oral LD50 (female rat): 2,263 mg/kg
鈥? Skin Sensitization: none
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Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Oral (11 days, male rat): NOEL; 100 mg/kg/day
Data for 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (CAS 13047-13-7):
Acute Toxicity Data:
鈥? Oral LD50 (rat): 566 mg/kg
鈥? Oral LD50: 283 mg/kg
鈥? Dermal LD50: > 1,000 mg/kg
鈥? Skin irritation: slight
鈥? Skin irritation: slight exacerbation (repeated skin application)
鈥? Skin Sensitization: slight
鈥? Eye irritation: strong irritation
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Oral (12-day, rat): NOEL; 88 mg/kg/day
鈥? Oral (12-day, rat): LOEL; 440 mg/kg/day (target organ effects: blood, target organ effects:
testes)
鈥? Oral (28-day, rat): NOEL; 10 mg/kg/day
鈥? Oral (28-day, rat): LOEL; 40 mg/kg/day (target organ effects: blood, target organ effects:
testes)
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: 10 - 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
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COD (approximate): 0.15 g/g
BOD (approximate): 0.11 g/g
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
Not regulated for all modes of transportation.
For more transportation information, go to: www.kodak.com/go/ship.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Sodium sulphite
American Conference of Governmental Industrial Hygienists (ACGIH): Sodium metaborate,
tetrahydrate: Group A4 (Not classifiable as a human carcinogen.): Group A4 (Not classifiable as a
human carcinogen.)
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: Sodium sulphite (7757-83-7), Sodium metaborate, tetrahydrate (10555-76-7), 4-
hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-13-7)
WARNING!
MAY BE HARMFUL IF INHALED, ABSORBED THROUGH SKIN, OR SWALLOWED
DUST IRRITATING TO RESPIRATORY TRACT
CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
Do not breathe dust.
Avoid contact with eyes, skin, and clothing.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
MATERIAL SAFETY DATA SHEET
Revision Date: 05/09/2006
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Print Date: 07/10/2006
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FIRST AID: If inhaled, move to fresh air. Get medical attention. In case of contact, immediately flush
eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash contaminated clothing before re-use. Destroy
or thoroughly clean contaminated shoes. If swallowed, only induce vomiting as directed by medical
personnel. Never give anything by mouth to an unconscious person. Call a physician or poison
control center immediately.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
IN CASE OF SPILL: Shovel into suitable container for disposal. Clean surface thoroughly to remove
residual contamination.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-0, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 05/10/2006
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Print Date: 07/10/2006
Page: 1/6
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK XTOL Developer, Part B
Product code: 8751752 - Part B
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6327
2. Hazards identification
CONTAINS: Sodium sulphite (7757-83-7), Sodium metabisulphite (7681-57-4)
WARNING!
POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES
MAY BE HARMFUL IF INHALED OR SWALLOWED
HMIS III Hazard Ratings: Health - 1, Flammability - 1, Physical Hazard - 0
NFPA Hazard Ratings: Health - 1, Flammability - 1, Instability - 0
NOTE: HMIS III and NFPA 704 (2001) hazard indexes involve data review and interpretation that may
vary among companies. They are intended only for rapid, general identification of the magnitude of the
potential hazards. An asterisk (*), in the HMIS III health field, designates potential chronic or target organ
hazards. To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
70 - 75 Sodium sulphite (7757-83-7)
15 - 20 Sodium erythrobate (6381-77-7)
5 - 10 Sodium metabisulphite (7681-57-4)
4. First aid measures
Inhalation: If inhaled, move to fresh air. Get medical attention.
Eyes: Any material that contacts the eye should be washed out immediately with water. Get medical
attention if symptoms occur.
MATERIAL SAFETY DATA SHEET
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Skin: Wash off with soap and water. Get medical attention if symptoms occur.
Ingestion: If swallowed, only induce vomiting as directed by medical personnel. Never give anything by
mouth to an unconscious person. Call a physician or poison control center immediately.
5. Fire-fighting measures
Extinguishing Media: water spray, carbon dioxide (CO2), dry chemical.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: Carbon oxides, (see also Hazardous Decomposition Products
section).
Unusual Fire and Explosion Hazards: Dust may form explosive mixture in air.
6. Accidental release measures
Methods for cleaning up: Shovel into suitable container for disposal. Avoid dust formation. Clean
surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Do not breathe dust at concentrations greater than the exposure limits. Avoid
contact with eyes, skin, and clothing. Keep container closed. Use only with adequate ventilation. Wash
thoroughly after handling.
Prevention of Fire and Explosion: Dust may form explosive mixture in air. Minimize dust generation
and accumulation. Use only with adequate ventilation. Keep away from sources of ignition. Refer to NFPA
654, "Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and
Handling of Combustible Particulate Solids." Keep from contact with oxidizing materials.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Sodium metabisulphite ACGIH time weighted average 5 mg/m3
Sulphur dioxide ACGIH time weighted average 2 ppm
ACGIH Short term exposure limit 5 ppm
OSHA Z1 Permissible exposure limit 5 ppm 13 mg/m3
Ventilation: Use process enclosures, local exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits. Controls should be sufficient so that applicable
occupational exposure limits are not exceeded.
MATERIAL SAFETY DATA SHEET
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Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: N95 Particulate
Filter. A respirator should be worn if hazardous decomposition products are likely to be or have been
released. Respirator type: Acid gas. See Stability and Reactivity Section. If respirators are used, a
program should be instituted to assure compliance with applicable federal, state, commonwealth,
provincial, or local laws and regulations.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: For operations where prolonged or repeated skin contact may occur,
impervious gloves should be worn.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: solid (powder)
Colour: off-white
Odour: odourless
Specific gravity: No data available
Vapour pressure: negligible
Vapour density: No data available
Volatile fraction by weight: negligible
Melting point/range: No data available
Water solubility: complete
pH: No data available
Flash point: not applicable, combustible solid
10. Stability and reactivity
Stability: Stable.
Incompatibility: Acids, strong oxidizing agents. Contact with strong acids liberates sulphur dioxide.
Hazardous decomposition products: sulphur oxides.
Hazardous Polymerization: Hazardous polymerization does not occur.
11. Toxicological information
MATERIAL SAFETY DATA SHEET
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Effects of Exposure
General advice:
Contains: Sodium metabisulphite. In contact with strong acids or if heated, sulphites may
liberate sulphur dioxide gas. Sulphur dioxide gas is irritating to the respiratory tract. Some
asthmatics or hypersensitive individuals may experience difficult breathing.
Inhalation: May be harmful if inhaled. In contact with strong acids or if heated, sulphites may liberate
sulphur dioxide gas. Sulphur dioxide gas is irritating to the respiratory tract. Some asthmatics or
hypersensitive individuals may experience difficult breathing.
Eyes: No specific hazard known. May cause transient irritation.
Skin: This material has a low potential to cause allergic skin reactions; however, cases of human
skin sensitization have been reported.
Ingestion: May be harmful if swallowed. Some asthmatics or sulfite-sensitive individuals may
experience wheezing, chest tightness, stomach upset, hives, faintness, weakness and diarrhea.
Data for Sodium sulphite (CAS 7757-83-7):
Acute Toxicity Data:
鈥? Oral LD50 (rat): > 1,600 mg/kg
鈥? Skin irritation: none
鈥? Eye irritation: slight; washing palliative
Data for Sodium metabisulphite (CAS 7681-57-4):
Acute Toxicity Data:
鈥? Oral LD50 (male rat): 1,900 mg/kg
鈥? Oral LD50 (female rat): 1,130 mg/kg
鈥? Dermal LD50: > 1,000 mg/kg
鈥? Skin irritation: slight
鈥? Skin irritation: moderate (repeated skin application)
鈥? Skin Sensitization: none
鈥? Eye irritation: moderate to strong
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Oral (14-day, rat): NOEL; > 1105 mg/kg/day
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
MATERIAL SAFETY DATA SHEET
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Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: 10 - 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 0.24 g/g
BOD (approximate): 0.15 g/g
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
Not regulated for all modes of transportation.
For more transportation information, go to: www.kodak.com/go/ship.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Sodium sulphite, Sodium metabisulphite: 3
(Classification not possible from current data.)
American Conference of Governmental Industrial Hygienists (ACGIH): Sodium metabisulphite: Group
A4 (Not classifiable as a human carcinogen.)
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
MATERIAL SAFETY DATA SHEET
Revision Date: 05/10/2006
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CONTAINS: Sodium sulphite (7757-83-7), Sodium metabisulphite (7681-57-4)
WARNING!
POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES
MAY BE HARMFUL IF INHALED OR SWALLOWED
Minimize dust generation and accumulation.
Do not breathe dust at concentrations greater than the exposure limits.
Keep container closed.
Avoid contact with eyes, skin, and clothing.
Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If inhaled, move to fresh air. Get medical attention. Wash off with soap and water. Get
medical attention if symptoms occur. If swallowed, only induce vomiting as directed by medical
personnel. Never give anything by mouth to an unconscious person. Call a physician or poison
control center immediately.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, carbon dioxide (CO2), dry chemical.
IN CASE OF SPILL: Shovel into suitable container for disposal. Avoid dust formation. Clean surface
thoroughly to remove residual contamination.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-1, F-1, C-0
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