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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER EPOTHIN RESIN
IDENTIFICATION NUMBER: 20-8140-032, 20-8140-128
PRODUCT USE/CLASS : Epoxy resin
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500,
PREPARE DATE: 1/24/08; 24 Jan 08
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Bisphenol-A Epoxy resin 25068-38-6 60.0-100.0
02 N-Butyl Glycidyl Ether 2426-08-6 10.0-30.0
03 Acrylic ester TRADE SECRET 1.0-5.0
04 Diglycidyl ether TRADE SECRET 1.0-5.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 N.E. N.E. N.E. N/E N.E. NO
02 25 ppm N.E. 50 ppm N/E 5ppm-C NIOSH NO
03 N.E. N.E. N.E. N/E N.E. NO
04 N.E. N.E. N.E. N/E N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: Combustible. Harmful if swallowed. Causes skin
irritation. May cause allergic skin reaction. Contact may cause eye
injury.
ACUTE EFFECTS - EYE CONTACT: Severely irritating to the eyes.
ACUTE EFFECTS - SKIN CONTACT: Repeated or prolonged contact may cause
sensitization. Irritating to skin. Contact may cause redness and
dermatitis.
ACUTE EFFECTS - INHALATION: Vapors and/or aerosols formed at elevated
temperatures can be irritating.
ACUTE EFFECTS - INGESTION: Irritating to mouth, throat and stomach, with
nausea.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components. *Butyl
glycidyl ether is mutagenic "in-vitro." Mutagenicity tests in mice gave
mixed results.
OTHER INFORMATION: No information.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, EYE CONTACT, INHALATION,
Continued on Page 2)
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9106795
Product: 20-8140-032, 20-8140-128
Preparation Date: 1/24/08; 24 Jan 08 Page 2
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: Immediately wash skin with soap and plenty of water. Remove
contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: Swallowing less than an ounce will not cause significant harm.
For larger amounts, do not induce vomiting, but give one or two glasses of
water to drink and get medical attention.
NOTES TO PHYSICIAN: Treat symptomatically.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 165 F LOWER EXPLOSIVE LIMIT: N.A.
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:CO2,FOAM,DRY CHEMICAL,WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat.
Irritating and/or toxic gases or fumes may be generated by thermal
decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Reclaim clean
material. Wear appropriate protective equipment during cleanup. Absorb
with inert material, such as clay. Sweep or shovel into loosely-covered
waste container and remove to appropriate waste area. Dispose of in
accordance with federal, state, and local regulations.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Follow all MSDS/label precautions even after
container is emptied because it may retain product residues. Avoid contact
with eyes, skin, and clothing. FOR INDUSTRIAL USE ONLY.
STORAGE: Store full and empty containers in a cool dry place away from
heat, flames and sparks. Keep container closed when not in
use.
Continued on Page 3)
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9106795
Product: 20-8140-032, 20-8140-128
Preparation Date: 1/24/08; 24 Jan 08 Page 3
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Local exhaust as needed to control vapor or dust
levels to below lowest component TLV.
RESPIRATORY PROTECTION: If TLV/PEL is exceeded, if use is performed in a
poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved
vapor cartridge respirator in accordance with applicable health and safety
regulations and manufacturer's recommendations.
SKIN PROTECTION: Butyl rubber gloves. Nitrile gloves. Supported PVA
gloves.
EYE PROTECTION: Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. DO NOT reuse empty containers
without commercial clean or recondition.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 327 - 500 F VAPOR DENSITY : Is heavier than air
ODOR : Sweet ODOR THRESHOLD : No data
APPEARANCE : Clear thin yellowEVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Negligible Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 1.1299
VAPOR PRESSURE : <0.1 mm@20 degC pH @ 0.0 % : NA
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Reaction with amines and mercaptans in large amounts or under uncontrolled
conditions releases considerable heat and may release acrid fumes. Inert
gases. Free radical initiators. Oxygen scavengers.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Aldehydes and acids
from incomplete combustion. Phenolic compounds.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Bisphenol-A Epoxy resin Oral-rat=>11 g/kg No deaths/satd air
N-Butyl Glycidyl Ether Oral-rat=1660mg/kg Inh-rat=1030ppm/8H
Acrylate ester No information No information
Diglycidyl ether No information No information
Continued on Page 4)
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9106795
Product: 20-8140-032, 20-8140-128
Preparation Date: 1/24/08; 24 Jan 08 Page 4
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: No information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures. FOR
SMALL AMOUNTS: If both resin and hardener are available, mix and cure
in accordance with product directions. When cured, product is
non-hazardous, and may be placed in industrial or municipal landfill if
local regulations permit. Product disposed of in 鈥渁s sold鈥? condition is
not considered a hazardous waste under Federal RCRA regulations. Landfill
of free liquid NOT recommended. Fuels blending or incineration preferred
for free liquid if regulations permit.
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| TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Not regulated in containers < 110 gal
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: NA HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: NA PACKING GROUP: NA RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Not regulated as a dangerous good for
transport
INTERNATIONAL ID NUMBER: N/A
IMDG CLASS (1潞,2潞): N/A PACKING GROUP: N/A
IMDG EMS: N/A IATA CLASS (1潞,2潞): N/A
SUPPLEMENTAL INFORMATION: No information.
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| SECTION 15 - REGULATORY INFORMATION |
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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States: none
Continued on Page 5)
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9106795
Product: 20-8140-032, 20-8140-128
Preparation Date: 1/24/08; 24 Jan 08 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
CALIFORNIA PROPOSITION 65:
No Proposition 65 chemicals known to exist in this product.
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B, B3
COMPONENT RCRA CLASSIFICATIONS: NONE
COMPONENT RCRA CODES: N/A
CERCLA RQ VALUE (MINIMUM): N/A
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 06/18/03
REASON FOR REVISION: updated section(s): 2,11,13
VOLATILE ORGANIC COMPOUNDS (VOCS): 0 grams/ltr
LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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9106795
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