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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER PROBE-MET
IDENTIFICATION NUMBER: 20-3385
PRODUCT USE/CLASS : Modified epoxy
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500
PREPARE DATE: 05/22/06; 22 May 06
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
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01 Epoxy resin blend UNKNOWN 10.0-30.0
02 Amine UNKNOWN 1.0-5.0
03 Carbon Black 1333-86-4 0.1-1.0
04 Silicon dioxide (quartz) 14808-60-7 1.0-5.0
05 Antimony oxide 1309-64-4 1.0-5.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 N.E. N.E. N.E. N/E N.E. NO
02 N.E. N.E. N.E. N/E N.E. NO
03 3.5 mg/m3 N.E. 3.5 mg/m3 N/E 3.5 mg/m3 NO
04 0.1 mg/m3 N.E. 0.1 mg/m3 N/E 0.1 mg/m3 NO
05 N.E. N.E. N.E. N/E 0.5 mg/m3 NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: Vapors from heated material may be irritating.
Contact with heated material can cause thermal burns. Potential skin
sensitizer. Repeated and prolonged inhalation of dust may be harmful.
Harmful if swallowed.
ACUTE EFFECTS - EYE CONTACT: Contact may cause eye irritation. Exposure
to hot material may cause thermal burns.
ACUTE EFFECTS - SKIN CONTACT: Prolonged or repeated skin contact may cause
irritation. May cause allergic skin reaction. Contact with product at
elevated temperatures can result in thermal burns.
ACUTE EFFECTS - INHALATION: Dust or vapors may be slightly irritating to
respiratory tract.
ACUTE EFFECTS - INGESTION: Irritating to mouth, throat and stomach, with
nausea. Harmful if swallowed.
Continued on Page 2)
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9111498
Product: 20-3385
Preparation Date: 05/22/06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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CHRONIC OVEREXPOSURE EFFECTS: *Repeated and prolonged inhalation of
graphite or carbon dusts may cause pulmonary fibrosis, emphysema, and
pneumoconiosis. the severity of these effects is greatly influenced by the
presence of other harmful mineral dusts, most notably crystalline silica.
*This product contains encapsulated silicon dioxide (quartz, silica). No
exposure to free respirable silica is anticipated during normal use of this
product. It should be noted, however, that free respirable silica may be
released by grinding or machining of cured compound and has been listed as
a confirmed human carcinogen by NTP and IARC. Inhalation of free
respirable silica may cause silicosis or other serious delayed lung injury.
Recent studies have also suggested that individuals with silicosis are at
increased risk of developing tuberculosis, scleroderma, and/or increased
incidence of kidney lesions. *This product contains encapsulated antimony
trioxide. Repeated and prolonged inhalation of antimony trioxide may cause
benign pneumoconiosis. Such pneumoconiosis may exist with or without
decrease in lung function. Long-term inhalation studies indicate
commercial grade antimony oxide causes malignant lung tumors in rats. No
exposure to free respirable antimony oxide is anticipated during normal use
of this product. Antimony oxide may be released, however, by grinding or
machining coated parts. Use NIOSH-approved dust/mist respirator when
grinding or machining on coated parts. *Component(s) in this product
showed adverse reproductive effects in animal feeding studies.
OTHER INFORMATION: No information.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: For hot product, immediately immerse in or flush the
affected area with large amounts of cold water to dissipate heat. Cover
with clean cotton sheeting or gauze and get prompt medical attention. No
attempt should be made to remove material from skin or to remove
contaminated clothing as the damaged flesh can be easily torn. Immediately
flush affected area(s) thoroughly with water at least 15 minutes. Remove
and wash contaminated clothing. Contaminated leather articles should be
disposed of. Obtain medical attention.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention.
INGESTION: If swallowed, induce vomiting immediately as directed by
medical personnel. Never give anything by mouth to an unconscious person.
Get medical attention immediately.
NOTES TO PHYSICIAN: Treat symptomatically.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 200 F LOWER EXPLOSIVE LIMIT: N.A.
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: No data
Continued on Page 3)
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9111498
Product: 20-3385
Preparation Date: 05/22/06 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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EXTINGUISHING MEDIA:CO2,DRY CHEMICAL,FOAM,WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Finely divided dust in air may present
explosion hazard. Prevent dust buildup.
SPECIAL FIREFIGHTING PROCEDURES: Does not burn. Treat as petroleum fire.
Wear appropriate approved protective equipment. Avoid directing water
stream directly into flame; it may cause frothing with subsequent spread of
flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Reclaim clean
material. Sweep or shovel into loosely-covered waste container and remove
to appropriate waste area. Dispose of in accordance with federal, state,
and local regulations. Prevent washings from entering waterways.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist or gas. Do not get in
eyes, on skin or clothing. DO NOT take internally. FOR INDUSTRIAL USE
ONLY.
STORAGE: Keep away from heat and flame.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate.
RESPIRATORY PROTECTION: None normally required under general ventilation.
If TLV/PEL is exceeded or if inhalation effects occur, use NIOSH-approved
dust/mist respirator in accordance with applicable regulations and
manufacturer鈥檚 recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves.
Nitrile gloves. Supported PVA gloves. Thermal gloves when handling hot
material.
EYE PROTECTION: Safety glasses.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 500 - 500 F VAPOR DENSITY : Is heavier than air
ODOR : Faint phenolic ODOR THRESHOLD : N/A
APPEARANCE : Black EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : N/A SPECIFIC GRAVITY: 2.0931
VAPOR PRESSURE : N/A pH @ 0.0 % : N/A
PHYSICAL STATE : Solid VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
Continued on Page 4)
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9111498
Product: 20-3385
Preparation Date: 05/22/06 Page 4
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Reaction with amines and mercaptans in large amounts or under uncontrolled
conditions releases considerable heat and may release acrid fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Aromatic and
aliphatic hydrocarbons. Aldehydes and acids from incomplete combustion.
Phenolic compounds. In the presence of nascent hydrogen, highly toxic
stibine gas may be envolved.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Epoxy resin blend No information No information
Amine No information No information
Carbon Black Oral-rat=>8 g/kg No information
Silicon dioxide (quartz) No information No information
Antimony oxide No information No information
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: No information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Material as sold may be disposed of in landfill if local
regulations permit. If material becomes contaminated, follow disposal
instructions for contaminant.
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| TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Not regulated
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Not regulated
INTERNATIONAL ID NUMBER: N/A
IMDG CLASS (1酶,2酶): N/A IMDG PAGE NUMBER: N/A
IMDG EMS: N/A IATA CLASS (1酶,2酶): N/A
ADR ITEM NO.: N/A ADR TREMCARD: N/A
SUPPLEMENTAL INFORMATION: No information.
Continued on Page 5)
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9111498
Product: 20-3385
Preparation Date: 05/22/06 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
Antimony oxide 1309-64-4 1.0-5.0
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No components found.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Fused amorphous silicon dioxide 60676-86-0
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Fused amorphous silicon dioxide 60676-86-0
CALIFORNIA PROPOSITION 65:
WARNING: This product contains a chemical(s) known to the state of
California to cause cancer. (silicon dioxide)
VOLATILE ORGANIC COMPOUNDS (VOCS): 0 grams/ltr
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: No information.
CERCLA RQ VALUE (MINIMUM): 1,000
Continued on Page 6)
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9111498
Product: 20-3385
Preparation Date: 05/22/06 Page 6
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE:
REASON FOR REVISION: new format
ADMINISTRATIVE REVISION DATE: 05/20/03
REASON FOR ADMINISTRATIVE REVISION: Updates to Sections 1, 8, 11, 16
LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
Consult www.buehler.com periodically to assure latest revision.
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9111498
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