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| SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER ANTHRACITE PAINT
IDENTIFICATION NUMBER: R-8797
PRODUCT USE/CLASS : Paint
SUPPLIER:
Buehler UK, Ltd. Buehler GmbH
Saturn Building In der Steele 2, 40599 D眉sseldorf
101, Lockhurst Lane Postfach 16 03 55, 40599 D眉sseldorf
Coventry CV6 5SF ENGLAND
TEL: (+44) (0) 24 7658 2158 Telefon: (+49) 0211-974100
FAX: (+44) (0) 24 7658 2159 Telefax: (+49) 0211-9741079
PREPARER: Technical Department, PREPARE DATE: 06/02/03
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
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01 Toluene 108-88-3 1.0-5.0
Classification: FLAMMABLE F; HARMFUL Xn; R11-20
02 2-Heptanone 100-43-0 1.0-5.0
Classification: Xn; Harmful; R10-R20/22
03 Isopropyl acetate 108-21-4 10.0-30.0
Classification: F, Highly Flammable; Xi, Irritant; R36-R66-R67
04 n-Butyl acetate 123-86-4 5.0-10.0
Classification: NONE; R10-66-67
05 Xylene 1330-20-7 1.0-5.0
Classification: HARMFUL, Xn; IRRITANT, Xi; R10-20/21-38
06 Carbon Black 1333-86-4 1.0-5.0
Classification: No information; N.E.
---------------------- EXPOSURE LIMITS --------------------
U/K GERMANY OTHER
ITEM 8-HR REL 15-MIN STEL 8-HR MAK 15-MIN MAK 8-HR TWA SKIN
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01 50 ppm 150 ppm 100 ppm N/E 100 ppm NO
02 50ppm N.E. 100ppm N/E 50ppm NO
03 250 ppm 310 ppm 250 ppm 310 ppm 250 ppm NO
04 150 ppm 200 ppm 150 ppm N.E. N.E. NO
05 100ppm 150ppm 100ppm N/E 100 NO
06 3.5mg/m3 N.E. 3.5mg/m3 N/E N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - IDENTIFICATION OF HAZARDS |
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EMERGENCY OVERVIEW: (R10) Flammable. (R20/21) Harmful by inhalation and
in contact with skin. (R36) Irritating to eyes. (R66) Repeated exposure
may cause skin dryness or cracking. (R67) Vapours may cause drowsiness and
dizziness.
PRIMARY ROUTE(S) OF ENTRY: INHALATION, EYE CONTACT, SKIN CONTACT,
Continued on Page 2)
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Product: R-8797
Preparation Date: 06/02/03 Page 2
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Flush eye with water for 15 minutes. Get medical attention.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation develops or persists.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control centre immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: Treat symptomatically.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 4 C LOWER EXPLOSIVE LIMIT: 1.1 %
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 7.9 %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,FOAM,DRY CHEMICAL,WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapours are heavier than air, and may
travel along the ground to be reignited at locations distant from the
source; flashback of flame may occur. "Empty" containers may retain
dangerous product residues or explosive vapors. Full or empty containers
exposed to fire or direct heat may explode.
SPECIAL FIREFIGHTING PROCEDURES: Treat as petroleum fire.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Eliminate
heat, sparks, flames, and sources of ignition if safe to do so. Wipe up
residue with non-sparking tools. Wash spill area with mild detergent
solution.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Use only in a well ventilated area. Follow all MSDS/label
precautions even after container is emptied because it may retain product
residues. Avoid contact with skin and eyes. Follow good general
industrial safety practices during use and handling. FOR PROFESSIONAL USE
ONLY.
STORAGE: Store full and empty containers away from heat, sparks, flame,
and other sources of ignition. Do not store in direct sunlight.
KEEP OUT OF THE REACH OF CHILDREN.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate for limited
use. Supplemental ventilation equipment should be approved for use with
flammable vapours.
RESPIRATORY PROTECTION: If recommended safe exposure limits are exceeded,
if use is performed in a poorly-ventilated space, or if inhalation effects
occur, use approved organic vapour cartridge respirator.
Continued on Page 3)
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Product: R-8797
Preparation Date: 06/02/03 Page 3
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves.
Supported PVA gloves.
EYE PROTECTION: Safety glasses or goggles.
OTHER PROTECTIVE EQUIPMENT: Not Applicable.
HYGIENIC PRACTICES: DO NOT smoke or eat during use.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 88 - 151 C VAPOR DENSITY : Is heavier than air
ODOR : Strong solvent ODOR THRESHOLD : Appr 1 ppm
APPEARANCE : Black EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : NO DATA SPECIFIC GRAVITY: 1.60
VAPOR PRESSURE : NO DATA pH @ 100.0 % : N/A
PHYSICAL STATE : Aerosol VISCOSITY : Very low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Surface-active compounds.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Toluene oral-rat 5000mg/kg Mouse 5320 ppm/8H
2-Heptanone oral(rat)1600mg/kg Not Applicable
Isopropyl acetate Oral rat 3.0 g/kg No data
n-Butyl acetate No Information No information
Xylene oral(rat)4300mg/kg Not Applicable
Carbon black No information No information
Toxicological Test Data: Not Applicable.
ACUTE EFFECTS - EYE CONTACT: Severely irritating to the eyes. Contact may
cause injury to eye tissue if not removed promptly.
ACUTE EFFECTS - SKIN CONTACT: May be absorbed through the skin in harmful
amounts. Frequent or prolonged contact may irritate the skin and cause a
skin rash (dermatitis).
ACUTE EFFECTS - INHALATION: Harmful if inhaled. Liquid aspirated into
lungs may cause chemical pneumonitis. Can cause severe central nervous
system depression, including unconsciousness. Liquid particles breathed
into the lungs may cause injury to the lungs, liver, or kidneys. Causes
9111798EU
respiratory tract irritation. May cause drowsiness, headache, or nausea.
Continued on Page 4)
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Product: R-8797
Preparation Date: 06/02/03 Page 4
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| SECTION 11 - TOXICOLOGICAL INFORMATION |
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ACUTE EFFECTS - INGESTION: This material may be harmful or fatal if
swallowed.
CHRONIC OVEREXPOSURE EFFECTS: *Repeated inhalation of vapors from heated
material may cause respiratory sensitization with asthma-like response.
Previously sensitized persons may experience effects even at levels below
recommended safe exposure limits. *Teratogenicity (damage to fetus)
similar to that of fetal alcohol syndrome is found in human studies where
there is repeated excessive in-utero exposure toluene. Chronic toluene
abuse produces kidney damage. *Overexposure to xylene has been found to
cause anaemia, liver abnormalities, kidney damage, and/or eye damage in
animals. Repeated or prolonged overexposure may cause injury to the red
blood cells or damage to the central nervous system. *Studies suggest that
solvent chronic overexposure effects are targeted at the liver and central
nervous system. Deliberate and repeated inhalation of concentrated solvent
vapours may cause permanent neural injury. Consumption of alcohol in
conjunction with repeated solvent exposure may cause colour vision defects.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: None known.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: FLAMMABLE. Landfill disposal NOT recommended. Follow
local and national regulations for appropriate steps for disposal of full
and/or empty containers and contaminated or used equipment.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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INTERNATIONAL SHIPPING NAME: IATA: Aerosols, Flammable
IMDG: Aerosols
INTERNATIONAL ID NUMBER: UN1950
IMDG CLASS (1酶,2酶): 2, none IMDG PAGE NUMBER: N/A
IMDG EMS: 213 IATA CLASS (1酶,2酶): 2.1, none
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| SECTION 15 - REGULATORY INFORMATION |
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CHiP SUPPLY LABEL RISK PHRASES: (R10) Flammable. (R20/21) Harmful by
inhalation and in contact with skin. (R36) Irritating to eyes.
(R66) Repeated exposure may cause skin dryness or cracking. (R67) Vapours
may cause drowsiness and dizziness.
CHiP SUPPLY LABEL SAFETY PHRASES: (S16) Keep away from sources of ignition
- no smoking. (S24) Avoid contact with skin. (S26) In case of contact
with eyes, rinse immediately with plenty of water and seek medical advice.
(S33) Take precautionary measures against static discharges.
For industrial and professional use only.
CHiP SUPPLY LABEL SYMBOLS: Highly Flammable, F Harmful, Xn
Continued on Page 5)
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9111798EU
Product: R-8797
Preparation Date: 06/02/03 Page 5
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| SECTION 16 - OTHER INFORMATION |
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PREVIOUS MSDS REVISION DATE: 31/07/01
REASON FOR REVISION: modified formula
VOLATILE ORGANIC COMPOUNDS (VOCS): 316 grams/ltr (calculated)
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; UK = United Kingdom; REL = Recommended Exposure Limit; MAK =
Maximale Arbetisplatzkonzentration (Maximum Concentration in the
Workplace); TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hours); STEL = Short-Term Exposure Limit (15 minutes); C = Ceiling Value;
PEL = Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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9111798EU
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