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| SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER REPLICATING TAPE
IDENTIFICATION NUMBER: 57-5000, 57-5002
PRODUCT USE/CLASS : Film
SUPPLIER:
Buehler UK, Ltd. Buehler GmbH
Saturn Building In der Steele 2, 40599 D眉sseldorf
101, Lockhurst Lane Postfach 16 03 55, 40599 D眉sseldorf
Coventry CV6 5SF ENGLAND
TEL: (+44) (0) 24 7658 2158 Telefon: (+49) 0211-974100
FAX: (+44) (0) 24 7658 2159 Telefax: (+49) 0211-9741079
PREPARER: Technical Department, PHONE: +18472955600, PREPARE DATE: 11/08/01
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Dibutyl Phthalate 84-74-2 10.0-30.0
Classification: No information; N.E.
02 Dimethyl phthalate 131-11-3 10.0-30.0
Classification: No information; N.E.
03 Dichloromethane 75-09-2 1.0-5.0
Classification: Harmful Xn; Carc. Cat. 3; R40
04 Methanol 67-56-1 1.0-5.0
Classification: FLAMMABLE F; TOXIC T; R11-23/24/25-39/23/24/25
---------------------- EXPOSURE LIMITS --------------------
U/K GERMANY OTHER
ITEM 8-HR REL 15-MIN STEL 8-HR MAK 15-MIN MAK 8-HR TWA SKIN
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01 5mg/m3 N.E. 5mg/m3 N/E N.E. NO
02 5mg/m N.E. 5mg/m3 N/E N.E. NO
03 100 ppm N.E. 500 ppm 200 ppm 100 ppm NO
04 200 ppm 250 ppm 200 ppm N/E 200 ppm NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - IDENTIFICATION OF HAZARDS |
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EMERGENCY OVERVIEW: Not considered a dangerous good for supply.
PRIMARY ROUTE(S) OF ENTRY: N/A
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water. Get medical
attention if irritation develops or persists.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation develops or persists.
INHALATION: No specific treatment is necessary since this material is not
likely to be hazardous by inhalation. If exposed to excessive levels of
dusts or fumes, remove to fresh air and get medical attention if cough or
other symptoms develop.
INGESTION: No information.
NOTES TO PHYSICIAN: Treat symptomatically.
Continued on Page 2)
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BUEHLER SAFETY DATA SHEET 9110195EU
Product: 57-5000, 57-5002
Preparation Date: 11/08/01 Page 2
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: N.A. LOWER EXPLOSIVE LIMIT: N/A %
UPPER EXPLOSIVE LIMIT: N/A %
AUTOIGNITION TEMPERATURE: N/A
EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: Irritating and/or toxic gases or fumes
may be generated by thermal decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Wear appropriate approved protective
equipment. For large fires, avoid aiming water stream directly into flame;
it may cause frothing with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Soak in water
and allow to harden.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Follow good general industrial safety practices during use and
handling. FOR INDUSTRIAL USE ONLY.
STORAGE: Store in a cool dry place.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: No special ventilation normally required.
RESPIRATORY PROTECTION: None normally required under good general
industrial ventilation.
SKIN PROTECTION: Rubber or synthetic gloves.
EYE PROTECTION: Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: No information.
HYGIENIC PRACTICES: No information.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 39 - 335 C VAPOR DENSITY : Is heavier than air
ODOR : Slight solvent ODOR THRESHOLD : NO DATA
APPEARANCE : Clear film EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : N/A SPECIFIC GRAVITY: 1.5796
VAPOR PRESSURE : NO DATA pH @ 0.0 % : N/A
PHYSICAL STATE : Solid film VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Exposure to moisture.
INCOMPATIBILITY: No information.
Continued on Page 3)
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BUEHLER SAFETY DATA SHEET 9110195EU
Product: 57-5000, 57-5002
Preparation Date: 11/08/01 Page 3
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| SECTION 10 - STABILITY AND REACTIVITY |
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HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Toxic monomers.
Aromatic and aliphatic hydrocarbons. Phosgene. Combustion under
oxygen-starved conditions may produce numerous toxic products including
nitriles, cyanic acid, isocyanates, amides, cyanogens, amides, carbamates.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Dibutyl Phthalate oral(rat)8g/kg 7.9mg/m3
Dimethyl phthalate oral(rat)6800mg/kg No information
Dichloromethane Oral/rat-1600mg/kg rat-30m 88000mg/m3
Methanol Oral-rat 5628mg/kg 64000 ppm/4H rat
Toxicological Test Data: No information.
ACUTE EFFECTS - EYE CONTACT: Not expected to present a hazard in normal
industrial use.
ACUTE EFFECTS - SKIN CONTACT: Not expected to present a hazard in normal
industrial use.
ACUTE EFFECTS - INHALATION: Not expected to present a hazard in normal
industrial use.
ACUTE EFFECTS - INGESTION: Solid article. Not an expected route of exposure.
CHRONIC OVEREXPOSURE EFFECTS: *Component(s) in this material are
considered to have caused cancer in laboratory animal studies.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: No information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Product may be placed in industrial or municipal landfill
if local regulations permit.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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INTERNATIONAL SHIPPING NAME: Not regulated for transport
INTERNATIONAL ID NUMBER: N/A
IMDG CLASS (1酶,2酶): N/A PACKING GROUP: N/A
IMDG EMS: N/A IATA CLASS (1酶,2酶): N/A
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| SECTION 15 - REGULATORY INFORMATION |
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CHiP SUPPLY LABEL RISK PHRASES: None required/Not regulated.
CHiP SUPPLY LABEL SAFETY PHRASES: None required.
CHiP SUPPLY LABEL SYMBOLS: NONE REQUIRED.
Continued on Page 4)
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BUEHLER SAFETY DATA SHEET 9110195EU
Product: 57-5000, 57-5002
Preparation Date: 11/08/01 Page 4
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| SECTION 16 - OTHER INFORMATION |
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PREVIOUS MSDS REVISION DATE: none
REASON FOR REVISION: new format
ADMINISTRATIVE REVISION DATE:
REASON FOR ADMINISTRATIVE REVISION:
VOLATILE ORGANIC COMPOUNDS (VOCS): 28 grams/ltr
LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; UK = United Kingdom; REL = Recommended Exposure Limit; MAK =
Maximale Arbetisplatzkonzentration (Maximum Concentration in the
Workplace); TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hours); STEL = Short-Term Exposure Limit (15 minutes); C = Ceiling Value;
PEL = Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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BUEHLER SAFETY DATA SHEET 9110195EU
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