|-------------------------------------------------------|
| MATERIAL SAFETY DATA SHEET |
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|=========================================================================|
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
|=========================================================================|
PRODUCT NAME : BUEHLER PLANARMET AL & FIBRMET DISCS
IDENTIFICATION NUMBER: 30-6008-020, 30-6010-020, 30-6012-020, 69-2580 to
69-3275
PRODUCT USE/CLASS : Abrasive
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500
PREPARE DATE: 2 Oct 2006; 10/02/06
|=========================================================================|
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
|=========================================================================|
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Aluminum oxide 1344-28-1 20.0-80.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO
(See Section 16 for abbreviation legend)
|=========================================================================|
| SECTION 3 - HAZARDS IDENTIFICATION |
|=========================================================================|
EMERGENCY OVERVIEW: Dust irritating to respiratory tract. Repeated and
prolonged inhalation of dust or vapors may be harmful (see chronic effects).
ACUTE EFFECTS - EYE CONTACT: Mechanical irritant. Contact may cause
tearing and redness.
ACUTE EFFECTS - SKIN CONTACT: Mechanical irritant. Prolonged contact may
cause skin abrasion.
ACUTE EFFECTS - INHALATION: Dust or vapors may be slightly irritating to
respiratory tract. Prolonged inhalation of dust may be harmful.
ACUTE EFFECTS - INGESTION: Not expected to present a hazard in normal
industrial use.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components.
*When heated to high temperatures (above 150 degrees C), this product may
release formaldehyde or phenol vapors. Product may release trace amounts
of phenol or formaldehyde from dust during grinding or polishing.
Formaldehyde is irritating to the skin, eyes, nose, and throat, and has
been listed as a carcinogen by IARC. Repeated or prolonged overexposure
may cause serious respiratory and/or skin sensitization. Formaldehyde
overexposure testing in animals has shown reproductive effects.
OTHER INFORMATION: Not Applicable.
PRIMARY ROUTE(S) OF ENTRY: INHALATION
Continued on Page 2)
===========================================================================
9111598
Product: 30-6008-020, 30-6010-020, 30-6012-020, 69-2580 to 69-3275,
Preparation Date: 2 Oct 2006; 10/02/06 Page 2
|=========================================================================|
| SECTION 4 - FIRST AID MEASURES |
|==========================================================================
EYE CONTACT: Immediately flush eyes with plenty of water. Get medical
attention, if irritation persists.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation develops or persists.
INHALATION: No specific treatment is necessary since this material is not
likely to be hazardous by inhalation. If exposed to excessive levels of
dusts or fumes, remove to fresh air and get medical attention if cough or
other symptoms develop.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: Not Applicable.
|=========================================================================|
| SECTION 5 - FIRE FIGHTING MEASURES |
|=========================================================================|
FLASH POINT: N.A. LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: N/A
EXTINGUISHING MEDIA: N/A
UNUSUAL FIRE AND EXPLOSION HAZARDS: Not Applicable.
SPECIAL FIREFIGHTING PROCEDURES: Does not burn.
|=========================================================================|
| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
|=========================================================================|
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: N/A
|=========================================================================|
| SECTION 7 - HANDLING AND STORAGE |
|=========================================================================|
HANDLING: Minimize dust generation and accumulation.
STORAGE: Not Applicable.
|=========================================================================|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|=========================================================================|
ENGINEERING CONTROLS: General ventilation usually adequate.
RESPIRATORY PROTECTION: If exposure levels are unknown, if levels exceed
TLV/PEL, or if effects occur, use NIOSH-approved dust/mist respirator in
accordance with applicable health and safety regulations and manufacturer's
recommendations.
SKIN PROTECTION: Clean clothing to cover skin.
EYE PROTECTION: Safety glasses or goggles.
OTHER PROTECTIVE EQUIPMENT: Cloth or synthetic gloves
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Continued on Page 3)
===========================================================================
9111598
Product: 30-6008-020, 30-6010-020, 30-6012-020, 69-2580 to 69-3275,
Preparation Date: 2 Oct 2006; 10/02/06 Page 3
|=========================================================================|
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
|=========================================================================|
BOILING RANGE : N.A. VAPOR DENSITY : N/A
ODOR : NONE ODOR THRESHOLD : N/A
APPEARANCE : Solid wheel EVAPORATION RATE: N/A
SOLUBILITY IN H2O : Insoluble
FREEZE POINT : N/A SPECIFIC GRAVITY: > 1
VAPOR PRESSURE : N/A pH @ 0.0 % : N/A
PHYSICAL STATE : N/A VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A
(See Section 16 for abbreviation legend)
|=========================================================================|
| SECTION 10 - STABILITY AND REACTIVITY |
|=========================================================================|
CONDITIONS TO AVOID: Not Applicable.
INCOMPATIBILITY: None known.
HAZARDOUS DECOMPOSITION PRODUCTS: N/A
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|=========================================================================|
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
|=========================================================================|
No product or component toxicological information is available.
|=========================================================================|
| SECTION 12 - ECOLOGICAL INFORMATION |
|=========================================================================|
ECOLOGICAL TEST DATA: Not Available
|=========================================================================|
| SECTION 13 - DISPOSAL CONSIDERATIONS |
|=========================================================================|
DISPOSAL METHOD: Material as sold may be disposed of in landfill if local
regulations permit. If material becomes contaminated, follow disposal
instructions for contaminant.
|=========================================================================|
| TRANSPORTATION INFORMATION |
|=========================================================================|
DOT PROPER SHIPPING NAME: Not regulated for transport
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Not regulated for transport
INTERNATIONAL ID NUMBER: N/A
IMDG CLASS (1酶,2酶): N/A PACKING GROUP: N/A
IMDG EMS: N/A IATA CLASS (1酶,2酶): N/A
Continued on Page 4)
===========================================================================
9111598
Product: 30-6008-020, 30-6010-020, 30-6012-020, 69-2580 to 69-3275,
Preparation Date: 2 Oct 2006; 10/02/06 Page 4
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories: NONE
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No components found.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
COMPONENT CAS NUMBER
Cloth backing none
Cured phenol/formaldehyde Resin 9003-35-4
Cured urea/formaldehyde Resin 9012-05-6
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
COMPONENT CAS NUMBER
Cloth backing none
Cured phenol/formaldehyde Resin 9003-35-4
Cured urea/formaldehyde Resin 9012-05-6
CALIFORNIA PROPOSITION 65: This product may release substances known to
the State of California to cause cancer.
VOLATILE ORGANIC COMPOUNDS (VOCS): 0 grams/ltr
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: NONE
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: Not Applicable.
CERCLA RQ VALUE (MINIMUM): None known
Continued on Page 5)
===========================================================================
9111598
Product: 30-6008-020, 30-6010-020, 30-6012-020, 69-2580 to 69-3275
Preparation Date: 2 Oct 2006; 10/02/06 Page 5
|=========================================================================|
| SECTION 16 - OTHER INFORMATION |
|=========================================================================|
HMIS RATINGS - HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 09/23/03
REASON FOR REVISION: updated Section(s): 1, 2
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
===========================================================================
===========================================================================
9111598
|-------------------------------------------------------|
| MATERIAL SAFETY DATA SHEET |
|-------------------------------------------------------|
|=========================================================================|
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
|=========================================================================|
PRODUCT NAME : BUEHLER ABRASIVE/POLISHING DISK/CLOTH ADHESIVE
IDENTIFICATION NUMBER: PSA
PRODUCT USE/CLASS : Adhesive
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500
PREPARE DATE: 2 Oct 2006; 10/02/06
|=========================================================================|
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
|=========================================================================|
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Heavy petroleum distillate 64742-18-3 10.0-20.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA NIOSH
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING REL-STEL SKIN
---------------------------------------------------------------------------
01 5 mg/m3 N.E. 5 mg/m3 N/E 10 mg/m3 NO
(See Section 16 for abbreviation legend)
|=========================================================================|
| SECTION 3 - HAZARDS IDENTIFICATION |
|=========================================================================|
EMERGENCY OVERVIEW: Vapors irritating to respiratory tract.
ACUTE EFFECTS - EYE CONTACT: Mechanical irritant. Contact may cause
tearing and redness.
ACUTE EFFECTS - SKIN CONTACT: Mild irritant. Prolonged contact may cause
defatting and redness.
ACUTE EFFECTS - INHALATION: Product swallowed and subsequently aspirated
into lungs may cause serious injury or pulmonary pneumonitis. Inhalation
of vapors from heated material may be irritating.
ACUTE EFFECTS - INGESTION: May cause nausea and vomiting. Small amounts
(a tablespoonful) swallowed during normal handling operations are not
likely to cause injury; swallowing amounts larger than that may cause
injury.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components.
OTHER INFORMATION: No information.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION
Continued on Page 2)
===========================================================================
9111598
Product: PSA
Preparation Date: 2 Oct 2006; 10/02/06 Page 2
|=========================================================================|
| SECTION 4 - FIRST AID MEASURES |
|=========================================================================|
EYE CONTACT: Immediately flush eyes with plenty of water. Get medical
attention, if irritation persists.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation develops or persists.
INHALATION: No specific treatment is necessary since this material is not
likely to be hazardous by inhalation. If exposed to excessive levels of
dusts or fumes, remove to fresh air and get medical attention if cough or
other symptoms develop.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: No information.
|=========================================================================|
| SECTION 5 - FIRE FIGHTING MEASURES |
|=========================================================================|
FLASH POINT: 400 F LOWER EXPLOSIVE LIMIT: no data
(Cleveland Open Cup) UPPER EXPLOSIVE LIMIT: No data
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA: ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: none known
SPECIAL FIREFIGHTING PROCEDURES: Treat as petroleum fire.
|=========================================================================|
| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
|=========================================================================|
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Not applicable.
|=========================================================================|
| SECTION 7 - HANDLING AND STORAGE |
|=========================================================================|
HANDLING: Avoid prolonged or repeated contact with skin.
FOR INDUSTRIAL USE ONLY.
STORAGE: Store away from heat. KEEP OUT OF THE REACH OF CHILDREN.
|=========================================================================|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|=========================================================================|
ENGINEERING CONTROLS: Local ventilation as needed to control vapor levels
to below lowest component TLV/PEL and respiratory effects level.
RESPIRATORY PROTECTION: None normally required under general ventilation.
If exposure levels are unknown, if levels exceed TLV/PEL, or if effects
occur, use NIOSH-approved dust/mist respirator in accordance with
applicable health and safety regulations and manufacturer's
recommendations.
Continued on Page 3)
===========================================================================
9111598
Product: PSA
Preparation Date: 2 Oct 2006; 10/02/06 Page 3
|=========================================================================|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|=========================================================================|
SKIN PROTECTION: Clean clothing to cover skin. Cloth or synthetic gloves.
EYE PROTECTION: Safety glasses.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. DO NOT reuse empty containers without commercial clean or
recondition. Follow all MSDS/label precautions even after container is
emptied.
|=========================================================================|
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
|=========================================================================|
BOILING RANGE : 555 鈥? N.D. F VAPOR DENSITY : Is heavier than air
ODOR : Oily ODOR THRESHOLD : No data
APPEARANCE : Light brown EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 0.789
VAPOR PRESSURE : <0.1mmHg @ 20C pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
|=========================================================================|
| SECTION 10 - STABILITY AND REACTIVITY |
|=========================================================================|
CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong bases or oxidants.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Various hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|=========================================================================|
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
|=========================================================================|
No product or component toxicological information is available.
|=========================================================================|
| SECTION 12 - ECOLOGICAL INFORMATION |
|=========================================================================|
ECOLOGICAL TEST DATA: No information.
|=========================================================================|
| SECTION 13 - DISPOSAL CONSIDERATIONS |
|=========================================================================|
DISPOSAL METHOD: Product 鈥渁s sold鈥? may be disposed of in landfill if
local regulations permit. If contaminated, follow disposal instructions
for contaminant.
Continued on Page 4)
===========================================================================
9111598
Product: PSA
Preparation Date: 2 Oct 2006; 10/02/06 Page 4
|=========================================================================|
| TRANSPORTATION INFORMATION |
|=========================================================================|
DOT PROPER SHIPPING NAME: Not regulated
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Not regulated
INTERNATIONAL ID NUMBER: N/A
IMDG CLASS (1酶,2酶): N/A IMDG PAGE NUMBER: N/A
IMDG EMS: N/A IATA CLASS (1酶,2酶): N/A
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
OSHA: Not Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories: none
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No components found.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product: NOT APPLICABLE
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%: NOT APPLICABLE
Continued on Page 5)
===========================================================================
9111598
Product: PSA
Preparation Date: 2 Oct 2006; 10/02/06 Page 5
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
CALIFORNIA PROPOSITION 65: This product contains a substance(s) listed
by the State of California as known to cause cancer. (petroleum distillate)
VOLATILE ORGANIC COMPOUNDS (VOCS): no data
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: NOT REGULATED
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: No information.
CERCLA RQ VALUE (MINIMUM): None known
|=========================================================================|
| SECTION 16 - OTHER INFORMATION |
|=========================================================================|
HMIS RATINGS - HEALTH: 0 FLAMMABILITY: 1 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 9/23/03
REASON FOR REVISION: 1
LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Safety and Health Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
Consult www.buehler.com periodically to assure latest revision.
===========================================================================
===========================================================================
9111598
|