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| SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER PROTECTIVE SKIN BARRIER
IDENTIFICATION NUMBER: 20-3041
PRODUCT USE/CLASS : Skin barrier
SUPPLIER:
Buehler UK, Ltd. Buehler GmbH
Saturn Building In der Steele 2, 40599 D眉sseldorf
101, Lockhurst Lane Postfach 16 03 55, 40599 D眉sseldorf
Coventry CV6 5SF ENGLAND
TEL: (+44) (0) 24 7658 2158 Telefon: (+49) 0211-974100
FAX: (+44) (0) 24 7658 2159 Telefax: (+49) 0211-9741079
PREPARER: Technical Department, PHONE: +18472955600, PREPARE DATE: 11/08/01
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
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01 Carbon Dioxide 124-38-9 30.0-60.0
Classification: No information; N.E.
02 Isopropyl myristate 110-27-0 5.0-10.0
Classification: No information.
03 Liquified petroleum gas, sweetened 66476-86-6 5.0-10.0
Classification: F+, T, Carc. Cat. 2; R12-43
04 Triethanolamine 102-71-6 5.0-10.0
Classification: No information; N.E.
---------------------- EXPOSURE LIMITS --------------------
U/K GERMANY OTHER
ITEM 8-HR REL 15-MIN STEL 8-HR MAK 15-MIN MAK 8-HR TWA SKIN
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01 5000 ppm 30000 ppm 10000 ppm N/E 5000 ppm NO
02 N.E. N.E. N.E. N.E. N.E. NO
03 1000 ppm N.E. 1000 ppm N/E N.E. NO
04 5ppm N.E. N.E. N/E N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - IDENTIFICATION OF HAZARDS |
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EMERGENCY OVERVIEW: (R48/20) Harmful: danger of serious damage to health
by prolonged exposure through inhalation.
PRIMARY ROUTE(S) OF ENTRY: INHALATION,
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Flush eye with water for 15 minutes. Get medical attention.
SKIN CONTACT: Wash with soap and water. Get medical attention if
irritation develops or persists.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: Swallowing less than an ounce will not cause significant harm.
For larger amounts, do not induce vomiting, but give one or two glasses of
water to drink and get medical attention.
NOTES TO PHYSICIAN: Treat symptomatically.
Continued on Page 2)
BUEHLER SAFETY DATA SHEET 9109495EU
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BUEHLER SAFETY DATA SHEET 9109495EU
Product: 20-3041
Preparation Date: 11/08/01 Page 2
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: Does not flash LOWER EXPLOSIVE LIMIT: N/A %
UPPER EXPLOSIVE LIMIT: N/A %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM,WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers are under pressure and
may explode if exposed to fire or direct heat.
SPECIAL FIREFIGHTING PROCEDURES: Keep containers away from heat sources.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wipe up excess
with towel or rag. 0Wash spill area with soap and water.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Use only in a well ventilated area. Follow all MSDS/label
precautions even after container is emptied because it may retain product
residues. Avoid contact with skin and eyes. Follow good general
industrial safety practices during use and handling. FOR INDUSTRIAL USE
ONLY.
STORAGE: Store full and empty containers away from heat, sparks, and
flame. Do not store in direct sunlight. KEEP OUT OF THE REACH OF
CHILDREN.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate.
RESPIRATORY PROTECTION: None normally required under good general
industrial ventilation.
SKIN PROTECTION: None normally required.
EYE PROTECTION: Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: No information.
HYGIENIC PRACTICES: DO NOT smoke or eat during use.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : -22 - -18 C VAPOR DENSITY : Is heavier than air
ODOR : Mild pleasant ODOR THRESHOLD : No data
APPEARANCE : White foam EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : Appreciable Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 0.2277
VAPOR PRESSURE : Very high pH @ 100.0 % : 8-9
PHYSICAL STATE : Aerosol VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat.
Continued on Page 3)
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BUEHLER SAFETY DATA SHEET 9109495EU
Product: 20-3041
Preparation Date: 11/08/01 Page 3
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| SECTION 10 - STABILITY AND REACTIVITY |
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INCOMPATIBILITY: No information.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Carbon Dioxide No information No information
Isopropyl myristate Derm-rbt=5 g/kg No information
Liquefied petroleum gas, sweetened No information No information
Triethanolamine oral(rat)8g/kg No information
Toxicological Test Data: No information.
ACUTE EFFECTS - EYE CONTACT: Mildly irritating to the eyes.
ACUTE EFFECTS - SKIN CONTACT: Not expected to present a hazard in normal
industrial use.
ACUTE EFFECTS - INHALATION: High gas, vapour, mist or dust concentrations
may be harmful if inhaled. Causes respiratory tract irritation.
ACUTE EFFECTS - INGESTION: Irritating to mouth, throat and stomach, with
nausea.
CHRONIC OVEREXPOSURE EFFECTS: Petroleum gas has been listed as a suspected
human carcinogen via inhalation.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: No information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: No information.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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INTERNATIONAL SHIPPING NAME: Aerosols
INTERNATIONAL ID NUMBER: UN1950
IMDG CLASS (1酶,2酶): 2.2, none PACKING GROUP: N/A
IMDG EMS: N/A IATA CLASS (1酶,2酶): 2.2, none
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| SECTION 15 - REGULATORY INFORMATION |
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CHiP SUPPLY LABEL RISK PHRASES: (R48/20) Harmful: danger of serious damage
to health by prolonged exposure through inhalation.
CHiP SUPPLY LABEL SAFETY PHRASES: (S35) This material and its container
must be disposed of in a safe way. (S51) Use only in well-ventilated
areas.
CHiP SUPPLY LABEL SYMBOLS: Harmful, Xn
Continued on Page 4)
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BUEHLER SAFETY DATA SHEET 9109495EU
Product: 20-3041
Preparation Date: 11/08/01 Page 4
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| SECTION 16 - OTHER INFORMATION |
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PREVIOUS MSDS REVISION DATE: 01/08/01
REASON FOR REVISION: new format
ADMINISTRATIVE REVISION DATE:
REASON FOR ADMINISTRATIVE REVISION:
VOLATILE ORGANIC COMPOUNDS (VOCS): 20 grams/ltr
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| SECTION 16 - OTHER INFORMATION |
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LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; UK = United Kingdom; REL = Recommended Exposure Limit; MAK =
Maximale Arbetisplatzkonzentration (Maximum Concentration in the
Workplace); TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hours); STEL = Short-Term Exposure Limit (15 minutes); C = Ceiling Value;
PEL = Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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BUEHLER SAFETY DATA SHEET 9109495EU
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