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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER PLATINUM PAINT AEROSOL
IDENTIFICATION NUMBER: R-8702
PRODUCT USE/CLASS : Paint
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 303-333-1876,
PREPARE DATE: 05/22/06; 22 MAY 06
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Toluene 108-88-3 1.0-5.0
02 2-Heptanone 100-43-0 1.0-5.0
03 Isopropyl acetate 108-21-4 5.0-10.0
04 n-Butyl acetate 123-86-4 5.0-10.0
05 Xylene 1330-20-7 1.0-5.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 50 ppm N.E. 200 ppm 300 ppm 100ppm NIOSH YES
02 50ppm N.E. 100ppm N/E 50ppm NO
03 250 ppm 310 ppm 250 ppm 310 ppm 250 ppm NO
04 150 ppm 200 ppm 150 ppm N.E. N.E. NO
05 100ppm 150ppm 100ppm 150ppm 100 ppm NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: Harmful if inhaled or swallowed. High vapor
concentrations may cause drowsiness. Flammable liquid and vapor.
Contents under pressure. May cause skin irritation. May cause eye
irritation. Repeated and prolonged overexposure may cause target organ
effects. See chronic effects information.
ACUTE EFFECTS - EYE CONTACT: Severely irritating to the eyes. Contact may
cause injury to eye tissue if not removed promptly.
ACUTE EFFECTS - SKIN CONTACT: Moderate irritant. Prolonged contact may
cause dermatitis.
ACUTE EFFECTS - INHALATION: Liquid aspirated into lungs may cause chemical
pneumonitis. Can cause severe central nervous system depression, including
unconsciousness. Liquid particles breathed into the lungs may cause injury
to the lungs, liver, or kidneys. Vapors may have a strong offensive odor
which may cause headaches, nausea and vomiting. Causes respiratory tract
irritation.
Continued on Page 2)
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Product: R-8702
Preparation Date: 05/22/06; 22 MAY 06 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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ACUTE EFFECTS - INGESTION: May cause nausea and vomiting.
CHRONIC OVEREXPOSURE EFFECTS: *Repeated inhalation of vapors from heated
material may cause respiratory sensitization with asthma-like response.
Previously sensitized persons may experience effects even at levels below
recommended safe exposure limits. *Teratogenicity (damage to fetus)
similar to that of fetal alcohol syndrome is found in human studies where
there is repeated excessive in-utero exposure toluene. Chronic toluene
abuse produces kidney damage. *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components.
*Overexposure to xylene has been found to cause anemia, liver
abnormalities, kidney damage, and/or eye damage in animals. Repeated or
prolonged overexposure may cause injury to the red blood cells, ECG
abnormalities, dyspnea, cyanosis, or damage to the central nervous system.
Xylene at about 100 ppm may affect equilibrium, slow reaction time, or
affect manual coordination. *Studies suggest that solvent chronic
overexposure effects are targeted at the liver and central nervous system.
Deliberate and repeated inhalation of concentrated solvent vapors may cause
permanent neural injury. Consumption of alcohol in conjunction with
repeated solvent exposure may cause color vision defects.
OTHER INFORMATION: No information.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT,
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: Immediately wash skin with soap and plenty of water. Remove
contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: No information.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 35 F LOWER EXPLOSIVE LIMIT: 1.1 %
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 7.9 %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM,WATER FOG
Continued on Page 3)
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9111698
Product: R-8702
Preparation Date: 05/22/06; 22 MAY 06 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol containers may rupture or
explode when exposed to direct heat. Vapors are heavier than air, and may
travel along the ground to be reignited at locations distant from the
source; flashback of flame may occur. "Empty" containers may retain
dangerous product residues or explosive vapors. Store full and empty
containers away from heat, sparks, flame, and other sources of ignition.
Irritating and/or toxic gases or fumes may be generated by thermal
decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Eliminate
heat, sparks, flames, and sources of ignition if safe to do so. Wipe up
residue with non-sparking tools. Wash spill area with mild detergent
solution. Dispose of contaminated articles in accordance with federal,
state, and local regulations. Dispose of damaged aerosol container in
accordance with state and local regulations regarding "empty" chemical
containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Use with adequate ventilation. Follow all MSDS/label
precautions even after container is emptied because it may retain product
residues. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY.
STORAGE: Keep away from heat, sparks and flame. Do not store in direct
sunlight. KEEP OUT OF THE REACH OF CHILDREN.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: For prolonged usage, local explosion-proof exhaust
as needed to control vapor or dust levels to below lowest component TLV.
RESPIRATORY PROTECTION: If TLV/PEL is exceeded, if use is performed in a
poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved
organic vapor cartridge respirator in accordance with applicable health
and safety regulations and manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves.
Teflon gloves. Viton gloves. Supported PVA gloves.
EYE PROTECTION: Safety glasses.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. Follow all MSDS/label precautions
even after container is emptied.
Continued on Page 4)
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9111698
Product: R-8702
Preparation Date: 05/22/06; 22 MAY 06 Page 4
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 190 - 304 F VAPOR DENSITY : Is heavier than air
ODOR : Strong solvent ODOR THRESHOLD : Appr 1 ppm
APPEARANCE : Pale gray EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 1.73
VAPOR PRESSURE : <100mmHg@20 C pH @ 100.0 % : N/A
PHYSICAL STATE : Aerosol VISCOSITY : N/A
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Prolonged exposure to heat.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Metals. Surface-active compounds.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Toluene oral-rat 5000mg/kg Mouse 5320 ppm/8H
2-Heptanone oral(rat)1600mg/kg No information
Isopropyl acetate Oral rat 3.0 g/kg No data
n-Butyl acetate No information No information
Xylene oral(rat)4300mg/kg no data
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: No information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures. DO NOT
landfill. If disposed of 鈥渁s sold鈥?, product is considered a hazardous
waste per Federal RCRA regulations.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Aerosols, flammable
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: 2.1 HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: UN1950 PACKING GROUP: N/A RESP. GUIDE PAGE: 126
Continued on Page 5)
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9111698
Product: R-8702
Preparation Date: 05/22/06; 22 MAY 06 Page 5
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| SECTION 14 - TRANSPORTATION INFORMATION |
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INTERNATIONAL SHIPPING NAME: ICAO/IATA: Aerosols, flammable
IMO/IMDG : Aerosols
INTERNATIONAL ID NUMBER: UN1950
IMDG CLASS (1酶,2酶): 2, none IMDG PAGE NUMBER: N/A
IMDG EMS: 213 IATA CLASS (1酶,2酶): 2.1, none
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| SECTION 15 - REGULATORY INFORMATION |
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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
Toluene 108-88-3 1.0-5.0
Xylene 1330-20-7 1.0-5.0
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:none
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Calcium carbonate/limestone 471-34-1
Polyurethane prepolymer unknown
Titanium Dioxide 13463-67-7
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Calcium carbonate/limestone 471-34-1
Polyurethane prepolymer unknown
Titanium Dioxide 13463-67-7
CALIFORNIA PROPOSITION 65:
WARNING: This product contains a chemical(s) known to the state of
California to cause cancer and birth defects or other reproductive harm.
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2A, A, B1
COMPONENT RCRA CLASSIFICATIONS: Ignitable. Toxic
COMPONENT RCRA CODES: D001 F005 U239 U220
CERCLA RQ VALUE (MINIMUM): 100
Continued on Page 6)
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9111698
Product: R-8702
Preparation Date: 05/22/06; 22 MAY 06 Page 6
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 3 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 11/30/99
REASON FOR REVISION: updated product formula
VOLATILE ORGANIC COMPOUNDS (VOCS): 316 grams/ltr
LEGEND: N.A. - No information, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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9111698
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