Conforms to 93/112/EC and ISO 11014-1
SAFETY DATA SHEET
Marble impregnator
WHMIS (Pictograms) WHMIS (Classification) Protective Clothing
CLASS B-3: Combustible liquid with a flash point between 37.8掳C (100掳F) and
93.3掳C (200掳F).
Section 1. Product Identification and Uses
Product Name
Marble impregnator 771210000
Code
Mixture.
Supplier Solstrand Trading CAS #
CEPA DSL: No products were found.
Address 90 Hooper Road, Barrie, Ontario, Canada, L4N 8Z9 DSL
1.04
MSDS#
Telephone No.: +1 (705) 726 5445
Validation Date 29-7-2004
Manufacturer HG International b.v.
Country Netherlands Print Date 29-7-2004
In Case of Emergency Chem. Tel Inc.
(813) 248 0585 or
Toll free (800) 255 3924
Section 2. Composition, Information on Ingredients
Name CAS # Exposure Limits
% by LC50/LD50
Weight
1) Mesitylene 108-67-8 0-1 TWA: 25 (ppm) from Not available.
Arbeidsinspectie [Holland]
2) Propylbenzene 103-65-1 0-1 Not available. Not available.
3) 1.2.4-trimethylbenzene 95-63-6 1-5 TWA: 25 (ppm) from ACGIH Not available.
(TLV) [United States]
4) Neocryl B-875 27881-32-9 5-15 Not available. Not available.
TWA: 575 (mg/m3) from
5) White spirit 64742-82-1 30-100 Not available.
Arbeidsinspectie [Holland]
[1999]
TWA: 100 (mg/m3) from
6) Xylene 1330-20-7 0-1 ORAL (LD50): Acute: 4300
Arbeidsinspectie [Holland] mg/kg [Rat]. DERMAL
[1997] (LD50): Acute: 1700 mg/kg
TWA: 100 (ppb) from OSHA [Rabbit].
(PEL) [United States] [1999]
TWA: 100 STEL: 150 (ppm)
from ACGIH (TLV) [United
States] [1999]
Section 3. Hazards Identification
Potential Acute Health Effects No specific information is available in our database regarding the acute toxic effects of this material for
humans.
CARCINOGENIC EFFECTS: Not available.
Potential Chronic Health
MUTAGENIC EFFECTS: Not available.
Effects
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
Eye Contact
least 15 minutes. Get medical attention if symptoms appear.
In case of contact, immediately flush skin with plenty of water. Remove and launder or clean contaminated
Skin Contact
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention
if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Get medical attention if symptoms appear.
If swallowed, do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration
Ingestion
hazard if swallowed- can enter lungs and cause damage. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention.
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SAFETY DATA SHEET
Marble impregnator
Section 5. Fire Fighting Measures
These products are carbon oxides (CO, CO2).
Products of Combustion
Combustible liquid, insoluble in water.
Fire Fighting Media
and Instructions SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressure
build-up, autoignition or explosion.
COMBUSTIBLE.
Special Remarks on Fire
Hazards
No additional remark.
Special Remarks on
Explosion Hazards
Section 6. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Small Spill and Leak
Combustible liquid, insoluble in water.
Large Spill and Leak
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not get water inside container. Do not touch spilled material.
Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
local authorities.
Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
a Large Spill specialist BEFORE handling this product.
Section 7. Handling and Storage
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
Precautions
breathe gas/fumes/ vapor/spray.
Not considered to be reactive according to our database.
Incompatibility
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
Storage
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
Engineering Controls
their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Personal Protection
Eyes Safety glasses.
Body Lab coat.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Hands Gloves (impervious).
Feet Boots (advisable)
Protective Clothing
(Pictograms)
Mesitylene
Exposure Limits
TWA: 25 (ppm) from Arbeidsinspectie [Holland]
1.2.4-trimethylbenzene
TWA: 25 (ppm) from ACGIH (TLV) [United States]
White spirit
TWA: 575 (mg/m3) from Arbeidsinspectie [Holland] [1999]
Xylene
TWA: 100 (mg/m3) from Arbeidsinspectie [Holland] [1997]
TWA: 100 (ppb) from OSHA (PEL) [United States] [1999]
TWA: 100 STEL: 150 (ppm) from ACGIH (TLV) [United States] [1999]
Consult local authorities for acceptable exposure limits.
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SAFETY DATA SHEET
Marble impregnator
Section 9. Physical and Chemical Properties
Liquid.
Physical State and White Spirit
Odor
Appearance
Not applicable.
Taste
Not available.
Critical Temperature
Colorless.
Color
Not applicable.
pH (1% Soln/Water)
0.806 g/cm3
Density
177.5掳C (351.5掳F)
Boiling/Condensation Point
May start to solidify at -44掳C (-47.2掳F) based on data for: 1.2.4-trimethylbenzene.
Melting/Freezing Point
Instability Temperature
CLOSED CUP: 39掳C (102掳F) (Pensky-Martens.)
Flash point
Dynamic: The highest known value is 0.92 cP (Naptha (petroleum) low boiling naptha unspecified)
Viscosity
COMBUSTIBLE.
The Product is:
Not available.
Odor Threshold
Is not dispersed in cold water, hot water.
Dispersion Properties
See solubility in diethyl ether.
Not available.
Physical Chemical
Comments
Partially soluble in diethyl ether.
Solubility
Insoluble in cold water, hot water.
Section 10. Stability and Reactivity
The product is stable.
Stability
Not available.
Conditions of Instability
Not considered to be reactive according to our database.
Incompatibility with Various
Substances
Not available.
Corrosivity
Not available.
Hazardous Decomposition
Products
Special Remarks on Reactivity Not available.
Not available.
Special Remarks on
Corrosivity
Section 11. Toxicological Information
Absorbed through skin. Inhalation. Ingestion.
Routes of Entry
Acute oral toxicity (LD50): 3400 mg/kg [Rat]. (Naphta (petroleum) low boiling unspecified).
Toxicity to Animals
Acute Effects on Humans
Eyes Inflammation of the eye is characterized by redness, watering, and itching.
Skin Harmful if absorbed through the skin.
Inhalation Harmful by inhalation.
Ingestion Harmful: may cause lung damage if swallowed.
CARCINOGENIC EFFECTS: Not available.
Chronic Effects on Humans
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Not available.
Special Remarks on Toxicity
to Animals
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SAFETY DATA SHEET
Marble impregnator
Not available.
Special Remarks on Chronic
Effects on Humans
Not available.
Special Remarks on Other
Toxic Effects on Humans
Section 12. Ecological Information
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic enviroment.
Ecotoxicity
Not available.
BOD5 and COD
These products are carbon oxides (CO, CO2) and water.
Products of Biodegradation
not available
Toxicity of the Products of
Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Not available.
Waste Stream
Section 14. Transport Information
CLASS 3: Combustible liquid.
TDG Classification
3
PIN
TDG Class: Marine Pollutant. (Pollutant.)
Maritime Transportation
Not available.
Special Provisions for
Transport
Section 15. Other Regulatory Information and Pictograms
CLASS B-3: Combustible liquid with a flash point between 37.8掳C (100掳F) and 93.3掳C
WHMIS (Classification)
(200掳F).
No products were found.
Regulatory Lists
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Regulations
HCS Class: Combustible liquid having a flash point between 37.8掳C (100掳F) and 93.3掳C
Other Classifications HCS (U.S.A.)
(200掳F).
USA Regulatory Lists
SARA 313 toxic chemical notification and release reporting: Marble impregnator
R10- Flammable.
DSCL (EEC)
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65- Harmful: may cause lung damage if swallowed.
International Australia: Naphta (petroleum) low boiling naphta
Regulations Lists
China: Naphta (petroleum) low boiling naphta
Philippines (RA6969): Naphta (petroleum) low boiling naphta
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SAFETY DATA SHEET
Marble impregnator
Hazardous Material 2 National Fire
Health
Flammability
2
Information System 2 Protection
Flammability
2 0 Reactivity
(U.S.A.) Association (U.S.A.) Health
0
Reactivity
Specific Hazard
B
Personal Protection
DOT (U.S.A)
(Pictograms)
DSCL (Europe)
(Pictograms)
ADR (Europe)
(Pictograms)
Section 16. Other Information
References Not available.
Other Special Not available.
Considerations
Verified by T. Rutgers.
Validated by T. Rutgers on 29-7-2004.
Printed 29-7-2004.
Information Contact
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever
for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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