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MSDS Material Safety Data Sheet
CAS

67-56-1

File Name: adsil_com---msds-ad25.asp
AD25                                                                                                page1


MATERIAL SAFETY DATA SHEET

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Material Identification: MicroGuard AD25 M & M Clear Waterproofing Sealer (Part A)
Adsil 386-445-8239 PHONE
P.O. Box 353880 386-445-0471 FAX
Palm Coast, FL 32135-3880 CHEMTREC: 1-800-424-9300
SECTION 2: OSHA HAZARDOUS COMPONENTS

C.A.S. Number(s) Wt% Components Exposure Limits
Proprietary 鈥? Mixture 98% Alkoxysilanes No exposure limits established

67-56-1 2% Methyl Alcohol TWA 200 ppm, STEL 250 ppm
ACGIH TLV-skin TWA 200 ppm

The above components are hazardous as defined in 29 CFR 1910.1200.

NFPA/HMIS Code: Health 1, Flammability 3, Reactivity 0
SECTION 3: PHYSICAL DATA FOR MATERIAL
pH: Not Applicable (non-aqueous)
Solubility in water: None
Appearance: Clear Colorless Liquid
Odor: Strong Odor
Specific Gravity @ 250 C: 0.95
Boiling Point: >350 C., >950 F.
VOC Content: 709 g./liter (Components A, B, C mixed); Method 24

SECTION 4: FIRE & EXPLOSION HAZARD OF MATERIAL
Flash Point: 46.90 F./8.30 C.
Fire Hazards: Static electricity may accumulate and ignite vapors. Prevent a possible fire hazard by
suitable means such as bonding and grounding, inert gas purge, vapor dilution and the like. Vapors are
heavier than air and can travel along the ground to remote ignition sources.
Unusual Fire Hazards: Thermal breakdown of this product during fire or very high heat conditions may
evolve the following hazardous decomposition products; Silicon Dioxide, Carbon Dioxide and traces of
incompletely burned carbon compounds, Formaldehyde.
Extinguishing Media: Carbon Dioxide (CO2), Water Fog, Dry Chemical.
Fire Fighting Procedures: Self contained breathing apparatus and protective clothing should be worn in
fighting fires involving chemicals. Heat exposure pressurizes closed containers. Evacuate the area in cases
of overheating or fire.

SECTION 5: HEALTH & HAZARD DATA
Eye Contact: Causes eye irritation.
Skin Contact: Causes skin irritation.
Inhalation: Spray mist causes damage to respiratory tract.
Ingestion: Product generates methyl alcohol, which may cause blindness and possibly death, if swallowed.
Signs & Symptoms of Exposure: Burning pain in the nose and throat (inhalation), pain, redness and
tearing (eye exposure), itching or burning (skin exposure).
AD25 page2



Special Hazards: Carcinogens 鈥? none known
Teratogens 鈥? none known
Mutagens 鈥? none known
Reproductive Toxins 鈥? none known
Sensitizers 鈥? When heated to temperatures above 1500 C., in the presence of air, product
can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory
sensitizer and an irritant to the eyes, nose, throat, skin and digestive system.

Warning: Product will give off additional methyl alcohol when exposed to moisture or humid air.

Comments: Methyl Alcohol forms on contact with water or humid air. Provide adequate ventilation to
control exposures within guidelines or OSHA PEL:
TWA 200 ppm and ACGIH TLV-skin TWA 200 ppm, STEL 250 ppm.

SECTION 6: FIRST AID MEASURES
Eyes: Immediately flush with water for 15 minutes. Get medical attention.
Skin: No first aid should be needed.
Inhalation: Remove to fresh air. Get medical attention if ill effects persist.
Oral: Get immediate medical attention. If conscious, give lukewarm water (pint or 陆 liter) to dilute
ingested material. Do not induce vomiting. Lie down, keep warm and cover eyes to exclude light.
Comments: Treat same as methyl alcohol poisoning.

SECTION 7: REACTIVITY DATA
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None
Materials to Avoid: Concentrated nitric and sulfuric acids, strong oxidizers, aldehydes, halogens and
halogen compounds.

SECTION 8: LEAK OR SPILL INFORMATION
Containment/Clean-up: Disposal of collected product, residues and clean up materials may be
governmentally regulated. Observe all applicable local, state and federal waste management regulations.
Remove possible ignition sources and if needed, use non-sparking tools and equipment. To prevent
possible spontaneous combustion, store rags, mops, absorbent, etc; used during clean up in appropriate
containers or covered with water. Mop, wipe or soak up with absorbent material and contain for salvage or
disposal. For large spills, provide diking or other appropriate containment to keep material from spreading.
Clean any remaining slippery surfaces by appropriate techniques, such as washing with mild, caustic
detergents or solutions, or high-pressure steam for larger surface areas. Observe any safety precautions
applicable to the cleaning material used.

SECTION 9: SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use respiratory protection, unless adequate local exhaust ventilation is provided
or air-sampling data show exposures are within recommended exposure guidelines; NIOSH 鈥? black
cartridge, minimum.
Gloves: No special precautions are needed. Wash at mealtime or end of shift.
Eye Protection: Safety glasses at minimum.
Protective Equipment: Eye wash station (bottle) should be within direct access of work area.
Personal Hygiene: Do not get in eyes or on clothing. Avoid contact with skin. Wash thoroughly after
handling. Wash contaminated clothing before reuse.
AD25 page3


SECTION 10: TRANSPORT INFORMATION
DOT Information (49 CFR 172.101)

Proper Shipping Name: FLAMMABLE LIQUID, n.o.s.

Hazard Technical Name: METHOXYSILANE/METHANOL

Hazard Class: 3

UN Number: UN1993

Packing Group: II

SECTION 11: HANDLING & STORAGE
Handling: No special precautions are needed.

Storage: Keep container closed and stored away from heat, sparks and open flame. Store away from water
or moisture.

SECTION 12: REGULATORY INFORMATION
TSCA Status: All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings:

Section 302 CERCLA Extremely Hazardous Substances: None

Section 304 CERCLA Hazardous Substances: None

Section 312 Hazard Class:
Acute: Yes
Chronic: Yes
Fire: Yes
Pressure: No
Reactive: No

Section 313 Toxic Chemicals:
CAS Number Wt% Component Name
67-56-1 2.0 Methyl Alcohol

Supplemental State Compliance Information: California

Warning: This product contains the following chemical(s) listed by the State of California under the
Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause
cancer, birth defects or other reproductive harm.

None known.

Revision Date: 01/05
Prepared by: Adsil - MSDS Coordinator
Palm Coast, Florida 32137
PH: 386-445-8239
AD25 page4


MATERIAL SAFETY DATA SHEET

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Material Identification: MicroGuard AD25 M & M Clear Waterproofing Sealer (Part B)
Adsil 386-445-8239 PHONE
P.O. Box 353880 386-445-0471 FAX
Palm Coast, FL 32135-3880 CHEMTREC: 1-800-424-9300
SECTION 2: OSHA HAZARDOUS COMPONENTS

C.A.S. Number(s) Wt% Components Exposure Limits
7732-18-5 96% - 98% Distilled Water Not Applicable

64-19-7 2% - 4% Acetic Acid TWA 10 ppm, STEL n/e

NFPA/HMIS Code: Health 0, Flammability 0, Reactivity 0

SECTION 3: PHYSICAL DATA FOR MATERIAL
pH: 4.0 (+/- 0.5)
Solubility in water: N/A
Appearance: Clear Liquid (colorless)
Odor: Slight Vinegar
Specific Gravity @ 250 C: 1.00
Boiling Point: 1000 C., 2120 F.
VOC Content: None

SECTION 4: FIRE & EXPLOSION HAZARD OF MATERIAL
Flash Point: N/A
Fire Hazards: None
Unusual Fire Hazards: None
Extinguishing Media: Not Flammable.
Fire Fighting Procedures: N/A

SECTION 5: HEALTH & HAZARD DATA
Eye Contact: May cause moderate eye irritation.
Skin Contact: May cause mild skin irritation.
Inhalation: None
Ingestion: None
Signs & Symptoms of Exposure: None
Special Hazards: Carcinogens 鈥? none known
Teratogens 鈥? none known
Mutagens 鈥? none known
Reproductive Toxins 鈥? none known

SECTION 6: FIRST AID MEASURES
Eyes: None
Skin: None
Inhalation: None
Oral: None
Comments: No first aid measures should be needed.
AD25 page5


SECTION 7: REACTIVITY DATA
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None
Materials to Avoid: None

SECTION 8: LEAK OR SPILL INFORMATION
Containment/Clean-up: Not applicable.

SECTION 9: SPECIAL PROTECTION INFORMATION
Respiratory Protection: None
Gloves: None
Eye Protection: None
Protective Equipment: None
Personal Hygiene: None

SECTION 10: TRANSPORT INFORMATION
DOT Information (49 CFR 172.101)

Not a regulated material.
SECTION 11: HANDLING & STORAGE
Handling: No special precautions.

Storage: Protect from freezing.

SECTION 12: REGULATORY INFORMATION
EPA SARA Title III Chemical Listings:

Section 304 CERCLA Extremely Hazardous Substances: Not Applicable

Section 304 CERCLA Hazardous Substances: Not Applicable

Section 312 Hazard Class:
Acute: No
Chronic: No
Fire: No
Pressure: No
Reactive: No

Section 313 Toxic Chemicals: Not Applicable

Supplemental State Compliance Information: California

Warning: This product contains the following chemical(s) listed by the State of California under the
Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause
cancer, birth defects or other reproductive harm.

None known.

Revision Date: 01/05 Prepared by: Adsil - MSDS Coordinator
Palm Coast, Florida 32137
PH: 386-445-8239
AD25 page6


MATERIAL SAFETY DATA SHEET

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Material Identification: MicroGuard AD25 M & M Clear Waterproofing Sealer (Part C)
Adsil 386-445-8239 PHONE
P.O. Box 353880 386-445-0471 FAX
Palm Coast, FL 32135-3880 CHEMTREC: 1-800-424-9300
SECTION 2: OSHA HAZARDOUS COMPONENTS

C.A.S. Number(s) Wt% Components Exposure Limits
67-63-0 36-38% Isopropyl Alcohol TWA 400 ppm, STEL 500 ppm

52125-53-8 28-32% Glycol Ether PE Not Established

1569-01-3 28-32% Glycol Ether PNP Not Established


NFPA/HMIS Code: Health 1, Flammability 3, Reactivity 0

SECTION 3: PHYSICAL DATA FOR MATERIAL
pH: Not Applicable (non-aqueous)
Solubility in water: Complete
Appearance: Clear Liquid (colorless)
Odor: Strong Odor (alcohol)
Specific Gravity @ 250 C: 0.79
Boiling Point: 880 C., 1900 F.
VOC Content: 709 g./liter (Components A, B, C mixed); Method 24

SECTION 4: FIRE & EXPLOSION HAZARD OF MATERIAL
Flash Point: 58.00 F./12.80 C
Fire Hazards: Static electricity may accumulate and ignite vapors. Prevent a possible fire hazard by
suitable means, such as bonding and grounding, inert gas purge, vapor dilution and the like. Vapors are
heavier than air and can travel along the ground to remote ignition sources.
Unusual Fire Hazards: Thermal breakdown of this product during fire or very high heat conditions may
evolve the following hazardous decomposition products; Silicon Dioxide, Carbon Dioxide and traces of
incompletely burned carbon compounds, Nitrogen Oxides, Formaldehyde.
Extinguishing Media: Carbon Dioxide (CO2), Water Fog, Dry Chemical.
Fire Fighting Procedures: Self contained breathing apparatus and protective clothing should be worn
when fighting fires involving chemicals. Heat exposure pressurizes closed containers. Evacuate the area in
cases of overheating or fire.

SECTION 5: HEALTH & HAZARD DATA
Eye Contact: Causes eye irritation.
Skin Contact: Causes skin irritation.
Inhalation: Spray mist causes damage to the respiratory tract.
Ingestion: Product generates methyl alcohol, which may cause blindness and possible death, if swallowed.
Signs & Symptoms of Exposure: Burning pain in the nose and throat (inhalation), pain, redness and
tearing (eye exposure), itching or burning (skin exposure).
AD25 page7



Special Hazards: Carcinogens 鈥? none known
Teratogens 鈥? none known
Mutagens 鈥? none known
Reproductive Toxins 鈥? none known
Sensitizers 鈥? When heated to temperatures above 1500 C., in the presence of air, product
can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory
sensitizer and an irritant to the eyes, nose, throat, skin and digestive system.

SECTION 6: FIRST AID MEASURES
Eyes: Immediately flush with clean water for 15 minutes. Get medical attention.
Skin: No first aid should be needed.
Inhalation: Remove to fresh air. Get medical attention, if ill effects persist.
Oral: Get immediate medical attention. Do not induce vomiting. If conscious, give lukewarm water (pint
or 陆 liter) to dilute ingested material. Lie down, keep warm and cover eyes to exclude light.
Comments: Treat the same as methyl alcohol poisoning.

SECTION 7: REACTIVITY DATA
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None
Materials to Avoid: Strong oxidizing material can cause a reaction. Water, moisture or humid air can
cause hazardous vapors to form, as described in Section 5.

SECTION 8: LEAK OR SPILL INFORMATION
Containment/Clean-up: Disposal of collected product, residues and clean up materials may be
governmentally regulated. Observe all applicable local, state and federal waste management regulations.
Remove possible ignition sources and if needed, use non-sparking tools and equipment. To prevent
possible spontaneous combustion, store rags, mops, absorbent, etc; used during clean up, only in
appropriate containers or covered with water. Mop, wipe or soak up with absorbent material and contain for
salvage or disposal. For large spills, provide diking or other appropriate containment to keep material from
spreading. Clean any remaining slippery surfaces by appropriate techniques, such as washing with mild,
caustic detergents or solutions or high-pressure steam for larger areas. Observe any safety precautions
applicable to the cleaning material used. Use self-contained breathing apparatus and suitable protective
wear, such a full-face respirator.

SECTION 9: SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use respiratory protection NIOSH 鈥? 陆 face black cartridge, minimum. Provide
for local exhaust ventilation, per recommended exposure guidelines.
Gloves: No special protection is needed. Wash hands at mealtime and end of shift.
Eye Protection: Safety glasses at a minimum.
Protective Equipment: Eyewash station (bottle) should be in direct access of work area.
Personal Hygiene: Do not get in eyes or on clothing. Avoid contact with skin. Wash thoroughly after
handling. Wash contaminated clothing before reuse.
AD25 page8


SECTION 10: TRANSPORT INFORMATION
DOT Information (49 CFR 172.101)

Proper Shipping Name: FLAMMABLE LIQUID, n.o.s.

Hazard Technical Name: CONTAINS ISOPROPANOL

Hazard Class: 3

UN Number: UN1993

Packing Group: II

SECTION 11: HANDLING & STORAGE
Handling: No special precautions.

Storage: Keep the container closed and away from heat, sparks and open flames. Store away from water or
moisture.

SECTION 12: REGULATORY INFORMATION
TSCA Status: All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings:

Section 302 CERCLA Extremely Hazardous Substances: None

Section 304 CERCLA Hazardous Substances: None

Section 312 Hazard Class:
Acute: Yes
Chronic: Yes
Fire: Yes
Pressure: No
Reactive: No

Section 313 Toxic Chemicals: None


Supplemental State Compliance Information: California
Warning: This product contains the following chemical(s) listed by the State of California under the
Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause
cancer, birth defects or other reproductive harm.
None known.

Revision Date: 01/05

Prepared by: Adsil - MSDS Coordinator
Palm Coast, Florida 32137
PH: 386-445-8239

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