10122005 COVER SHEET PAGE:1
CHEM-AQUA
DIVISION OF NCH CANADA INC.
253 ORENDA ROAD, BRAMPTON, ONTARIO L6T 1E6
CHEMTREC 1-800-424-9300
CHEM-AQUA
DIVISION OF NCH CANADA INC.
253 ORENDA ROAD,
BRAMPTON, ONTARIO
L6T 1E6
905-457-5561
MSDS DATE OF SUPERSEDE REV PRODUCT PRODUCT
NUMBER ISSUE DATE # CODE DESCRIPTION (PARTIAL)
00001723 10112005 4630AQ CB-3939
10122005 MATERIAL SAFETY DATA SHEET : 00001723 PAGE:1
CHEM-AQUA
DIVISION OF NCH CANADA INC.
253 ORENDA ROAD, BRAMPTON, ONTARIO L6T 1E6
CHEMTREC 1-800-424-9300
PRODUCT : CB-3939
SECTION 01: MANUFACTURER INFORMATION
MANUFACTURER.....................CHEM-AQUA
DIVISION OF NCH CANADA INC.
253 ORENDA ROAD,
BRAMPTON, ONTARIO ; L6T 1E6
CHEMTREC 1-800-424-9300
905-457-5561
WHMIS CLASS......................THIS PRODUCT IS EXEMPT FROM WHMIS DUE TO PCP REGISTRATION.
NFPA - HEALTH RISK...............3 = HIGH
NFPA - FLAMMABILITY..............1 = SLIGHT
NFPA - REACTIVITY................1 = SLIGHT
MATERIAL CODE....................4630
MATERIAL USE.....................COOLING TOWER TREATMENT. BIOCIDE
PRECAUTIONS......................READ ENTIRE LABEL BEFORE USING PRODUCT. KEEP OUT OF REACH OF CHILDREN
SECTION 02: HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
1-BROMO-3-CHLORO-5, 30 0.2 MG/M3 16079-88-2 NOT AVAILABLE NOT AVAILABLE
5-DIMETHYLHYDANTOIN
3-BROMO-1-CHLORO-5,5-DIMETHYL 30 0.2 MG/M3 126-06-7 NOT AVAILABLE NOT AVAILABLE
HYDANTOIN
SODIUM CHLORIDE 1-5 N/E 7647-14-5 ORL-RAT 3000 MG/KG IHL-RAT >42 G/M3/1H
SKN-RBT >10 G/KG
1,3-DICHLORO-5,5-DIMETHYL 25-30 0.2 MG/M3 118-52-5 NOT AVAILABLE NOT AVAILABLE
HYDANTOIN
1,3-DICHLORO-5-ETHYL-5-METHYL 10-15 0.2 MG/M3 89415-87-2 NOT AVAILABLE NOT AVAILABLE
HYDANTOIN
SECTION 03: PHYSICAL DATA
PHYSICAL STATE...................BRIQUETTES
COLOUR...........................OFF-WHITE
ODOUR............................PUNGENT
VAPOUR PRESSURE (mm Hg)..........NOT APPLICABLE
VAPOUR DENSITY (AIR=1)...........NOT APPLICABLE
EVAPORATION RATE.................< 1
BOILING POINT (deg C)............NOT APPLICABLE
pH...............................3.6
PERCENT VOLATILE BY VOLUME.......0
SPECIFIC GRAVITY.................1.6
SOLUBILITY IN WATER (% W/W)......APPRECIABLE
SECTION 04: FIRE & EXPLOSION DATA
FLAMMABILITY.....................NON COMBUSTIBLE
IF YES, UNDER WHICH
CONDITIONS?
EXTINGUISHING MEDIA..............FOAM. DRY CHEMICAL. WATER SPRAY
SPECIAL PROCEDURES...............FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE GEAR. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY TO PREVENT
BURSTING. AVOID HOSE STREAMS OR ANY METHOD WHICH WILL CREATE DUST CLOUDS.
UNUSUAL FIRE AND EXPLOSION.......AS WITH ALL ORGANIC DUSTS, FINE PARTICLES SUSPENDED IN AIR IN CRITICAL
HAZARDS PROPORTIONS AND IN THE PRESENCE OF AN IGNITION SOURCE MAY IGNITE AND/OR
EXPLODE. DUST MAY BE SENSITIVE TO IGNITION BY ELECTROSTATIC DISCHARGE,
ELECTRICAL ARCS, SPARKS, WELDING TORCHES, CIGARETTES, OPEN FLAME, OR OTHER
SIGNIFICANT HEAT SOURCES. AS A PRECAUTION, IMPLEMENT STANDARD SAFETY
MEASURES FOR HANDLING FINELY DIVIDED ORGANIC POWDERS RECOMMENDED IN
SECTION X.
FLASH POINT (C)..................141.6
FLASH POINT METHOD...............CLEVELAND OPEN CUP (COC)
HAZARDOUS COMBUSTION PRODUCTS....FUMES OF BROMINE. FUMES OF CHLORINE. OXIDES OF CARBON (CO,CO2). OXIDES OF
NITROGEN
SECTION 05: REACTIVITY DATA
CHEMICAL STABILITY
YES........................STABLE, HAZARDOUS POLYMERIZATION WILL NOT OCCUR
NO, WHICH CONDITIONS ?.....HEAT, HOT SURFACES, SPARKS, AND OPEN FLAMES.
COMPATIBILITY WITH OTHER
SUBSTANCES
YES
10122005 MATERIAL SAFETY DATA SHEET : 00001723 PAGE:2
PRODUCT : CB-3939
SECTION 05: REACTIVITY DATA
NO, WHICH ONES?............ACIDS. ALKALIES. MOISTURE. STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH
AND CONCENTRATED HYDROGEN PEROXIDE.
SECTION 06: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:
ACUTE EFFECTS
SKIN CONTACT...............CORROSIVE. CAUSES BURNS AND POSSIBLE DEEP ULCERATIONS OR SCARRING. MAY
CAUSE ALLERGIC SKIN REACTION SEEN AS DELAYED SKIN RASH WHICH MAY BE
FOLLOWED BY BLISTERING, SCALING, AND OTHER SKIN EFFECTS.
EYE CONTACT................CORROSIVE. CAUSES BURNS, CORNEAL DAMAGE, AND POSSIBLE BLINDNESS.
INHALATION.................CAUSES SEVERE IRRITATION TO THE LUNGS WITH COUGHING, SNEEZING, CHEST PAIN,
POTENTIAL TISSUE DAMAGE, AND SYSTEMIC ABSORPTION.
INGESTION..................MAY CAUSE IRRITATION WITH POSSIBLE NAUSEA, VOMITING, AND DIARRHEA. MAY
CAUSE A BURNING SENSATION IN THE MOUTH, THROAT, ESOPHAGUS, CHEST, AND
STOMACH. SYMPTOMS MAY INCLUDE VOMITING OF BLOOD. BLOOD LOSS THROUGH
DAMAGED TISSUE CAN LEAD TO LOW BLOOD PRESSURE AND SHOCK, AND MAY BE FATAL.
EFFECTS OF CHRONIC EXPOSURE......MAY CAUSE SKIN SENSITIZATION. CHRONIC SKIN CONTACT MAY PROMOTE DERMATITIS
AND OIL ACNE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE ARE PRE-EXISTING
RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA, EMPHYSEMA, AND DERMATITIS.
CARCINOGENICITY OF MATERIAL......NOT APPLICABLE
TARGET ORGANS....................BLOOD FORMING ORGANS. LUNGS
PRIMARY ROUTE OF ENTRY...........ABSORPTION. INHALATION. THE PRIMARY ROUTES OF EXPOSURE ARE SKIN AND EYE
CONTACT.
SECTION 07: PREVENTIVE MEASURES
PROTECTIVE EQUIPMENT
GLOVES/ TYPE...............NEOPRENE OR NITRILE RUBBER GLOVES SHOULD BE WORN.
RESPIRATORY/TYPE...........WEAR A NIOSH/MSHA APPROVED RESPIRATOR WITH A DUST CARTRIDGE FILTER IF
EXPOSURE CAN EXCEED TLV/PEL. <10X PEL, USE AN N95 QUARTER OR HALF MASK
RESPIRATOR; <50X PEL, USE A FULL FACE RESPIRATOR EQUIPPED WITH N95
FILTERS; <200X PEL, USE A POWDERED AIR PURIFYING RESPIRATOR (POSITIVE
PRESSURE) WITH N95 FILTERS; >200X PEL, USE A FULL FACE, TYPE C SUPPLIED
AIR RESPIRATOR (CONTINUOUS FLOW MODE).
EYE/TYPE...................GOGGLES. FACE SHIELD
OTHER/TYPE.................WEAR PROTECTIVE CLOTHING WHEN HANDLING. AN EYEWASH STATION AND SAFETY
SHOWER SHOULD BE AVAILABLE.
VENTILATION REQUIREMENTS.........LOCAL EXHAUST AT POINTS OF EMISSION.
LEAK/SPILL.......................ELIMINATE ALL SOURCES OF IGNITION. VENTILATE THE AREA. WEAR APPROPRIATE
PROTECTIVE CLOTHING. TRANSFER SOLID USING NON-SPARKING EQUIPMENT INTO A
PROPERLY LABELED CONTAINER FOR REUSE OR DISPOSAL. IF NECESSARY WASH AREA
WITH WATER AND PICK UP WASH WATER FOR DISPOSAL. PREVENT PRODUCT FROM
CONTAMINATING SOIL OR FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS AND BODIES
OF WATER. TO NEUTRALIZE, USE SODIUM BISULFITE OR THIOSULFATE SOLUTIONS.
ADD CAUTIOUSLY WHILE MIXING.
WASTE DISPOSAL...................DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, PROVINCIAL, AND LOCAL
REGULATIONS.
HANDLING AND STORAGE.............STORE BETWEEN 0 & 49 C (32 & 120 F). ALWAYS STORE MATERIAL IN ITS ORIGINAL
PROCEDURES CONTAINER. KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID CREATING DUSTY
CONDITIONS. SEAL BROKEN BAGS IMMEDIATELY. ALTHOUGH THE RISK OF A DUST
EXPLOSION IS LOW, IMPLEMENT THE FOLLOWING SAFETY MEASURES AS A PRECAUTION:
1)BOND, GROUND, AND PROPERLY VENT CONVEYORS, DUST CONTROL DEVICES, AND
OTHER TRANSFER EQUIPMENT; 2) ELIMINATE IGNITION SOURCES (SPARKS, STATIC
BUILDUP, EXCESSIVE HEAT); 3) PROHIBIT FLOW OF POWDER OR DUST THROUGH
NON-CONDUCTIVE DUCTS, VACUUM HOSES, OR PIPES; ONLY USE GROUNDED,
ELECTRICALLY CONDUCTIVE TRANSFER LINES WHEN PNEUMATICALLY CONVEYING
PRODUCT; 4) STAY BELOW THE MINIMUM EXPLOSIVE CONCENTRATION BY PREVENTING
ACCUMULATION OF DUST (USE WELL- VENTILATED CONDITIONS, VACUUM SPILLS
PROMPTLY, CLEAN OVERHEAD HORIZONTAL SURFACES); 5) EXERCISE CARE WHEN
EMPTYING CONTAINERS, SWEEPING, MIXING, OR DOING OTHER TASKS WHICH CAN
CREATE DUST; 6) USE INERT GAS BLANKETING WHEN USE CONDITIONS OR PROCESSES
WARRANT. KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING
THIS PRODUCT. FOLLOW THE LABEL DIRECTIONS.
SECTION 08: FIRST AID MEASURES
EYE CONTACT......................IMMEDIATELY RINSE THE EYES WITH WATER. REMOVE ANY CONTACT LENSES AND
CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. HOLD THE EYELIDS APART TO
ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYES AND LIDS WITH WATER. GET
IMMEDIATE MEDICAL ATTENTION.
INGESTION........................GIVE 3 TO 4 GLASSES OF WATER. DO NOT INDUCE VOMITING. IF VOMITING OCCURS,
GIVE FLUIDS AGAIN. SEEK MEDICAL ATTENTION IF DISCOMFORT OCCURS.
INHALATION.......................IF DUST IS INHALED, REMOVE FROM THE AREA TO FRESH AIR. HAVE THE PERSON
BLOW THEIR NOSE TO REMOVE THE SUBSTANCE FROM THE NASAL PASSAGES AND KEEP
FROM INHALING FURTHER. IF NOT BREATHING, CLEAR THE AIRWAY AND START
MOUTH-TO-MOUTH ARTIFICIAL RESPIRATION. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT.....................IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND SHOES. WIPE AWAY MATERIAL
WITH A CLOTH. FLUSH AFFECTED AREAS WITH LARGE AMOUNTS OF WATER FOR 20 TO
30 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. DISCARD CLOTHING AND SHOES.
NOTES TO PHYSICIAN...............THERE IS NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY. PROBABLE MUCOSAL
DAMAGE CONTRAINDICATES THE USE OF GASTRIC LAVAGE.
10122005 MATERIAL SAFETY DATA SHEET : 00001723 PAGE:3
PRODUCT : CB-3939
SECTION 09: PREPARATION INFORMATION
NOTICE...........................THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN
LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED
REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE
USE THEREOF. THE MANUFACTURER ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE CAUSED BY THE USE, STORAGE, OR DISPOSAL OF THE
PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL
RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE, STORAGE, OR DISPOSAL OF THE
PRODUCT.
PREPARED BY......................LISA BOYNTON, REGULATORY SPECIALIST 972-438-0014
PREPARATION DATE.................OCT 11/2005
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