10092 - ILFOMED CP REVISION DATE : 05/07/99
MATERIAL SAFETY DATA SHEET
ILFOMED CP
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
ILFOMED CP
TRADE NAME:
A15
SYNONYMS:
IP91311
PART No.:
0
UN/NA (PIN) No.:
FOR MEDICAL EMERGENCY IN THE UNITED STATES AND CANADA CALL
EMERGENCY TELEPHONE:
1-800-842-9660 (PRODUCT MISUSE). FOR TRANSPORTATION EMERGENCY
CALL CHEMTREC 1-800-424-9300.
ILFORD Imaging USA Inc
SUPPLIER:
West 70 Century Road, Paramus, NJ 07653
Tel: 201-265-6000
Bryan Sammartino
CONTACT PERSON:
2. COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME: CAS No.: CONTENTS : EPA RQ: TPQ:
POTASSIUM SULFITE 10117-38-1 10-30 %
POTASSIUM CARBONATE 584-08-7 5-10 %
HYDROQUINONE 123-31-9 1-5 %
SODIUM HYDROXIDE 1310-73-2 0-1 %
POTASSIUM BROMIDE 7758-02-3 1-5 %
PHENYLMERCAPTOTETRAZOLE 86-93-1 0-1 %
DIETHYLENETRIAMINE PENTAACETIC ACID- 67-43-6 1-5 %
NA5
1-PHENYL-4-METHYL-4-HYDROXYMETHYL-3- 13047-13-7 0-1 %
-PYRAZOLIDONE
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Colorless or pale yellow, odorless, weakly alkaline, water-based, non-flammable liquid. Contains hydroquinone.
May cause sensitisation by skin contact.
ACUTE EFFECTS:
No specific health warnings noted.
INHALATION:
No specific health warnings noted.
INGESTION:
May cause sensitisation by skin contact. May cause allergic contact eczema.
SKIN:
No specific health warnings noted.
EYES:
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CHRONIC EFFECTS:
HEALTH WARNINGS:
Prolonged or repeated exposure may cause severe irritation. May cause skin irritation/eczema. May cause
sensitisation by skin contact.Liquid may irritate the skin.May cause allergy. May cause hypersensitivity.
ROUTE OF ENTRY:
Ingestion. Skin and/or eye contact.
MEDICAL INFORMATION:
May aggravate existing: Skin disorders and allergies.
4. FIRST AID MEASURES
Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get medical attention if any
INHALATION:
discomfort continues.
DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure. Rinse mouth thoroughly.
INGESTION:
Get medical attention immediately! Immediately give a couple of glasses of water, provided the victim is fully
conscious.
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin
SKIN:
immediately with soap and water. Get medical attention if irritation persists after washing.
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with lots of water
EYES:
while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
continues.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for surrounding fire.
HAZARDOUS COMBUSTION PRODUCTS:
Fire creates: Irritating gases/vapors/fumes. Sulfur dioxide.
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES:
Use appropriate protective clothing. Do not contaminate drainage or waterways. Absorb spill with non-reactive
absorbent and place in non-reactive containers for disposal. Contain Spill. Use large quantities of water to flush
small spills to sanitary sewer if local regulations permit. Do not flush to septic tank. See Section 13 for disposal
considerations. Flush with plenty of water to clean spillage area. Do not let washing down water contaminate
ponds or waterways. Inform Authorities if large amounts are involved.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS:
Avoid spilling, skin and eye contact. Provide good ventilation. Individuals liable to allergic reactions should not
handle the product Read and follow manufacturer's recommendations.
STORAGE PRECAUTIONS:
Keep in cool, dry, ventilated storage and closed containers. Store below 75掳F. Keep in original container. Keep
containers closed tightly.
STORAGE CRITERIA:
Chemical storage.
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8. EXPOSURE CONTROLS, PERSONAL PROTECTION
PROTECTIVE EQUIPMENT:
ENGINEERING CONTROLS:
Provide eyewash station and safety shower.
Provide adequate general and local exhaust ventilation. Must not be handled in confined spaces without adequate
VENTILATION:
ventilation. General room ventilation should provide for 10 - 15 room air changes per hour.
RESPIRATORS: Respiratory protection must be used if air concentration exceeds acceptable level. An acid gas/organic vapor
cartridge should be used.
PROTECTIVE GLOVES:
Use protective gloves made of: Rubber (natural,latex). Neoprene. Polyethylene.
EYE PROTECTION:
Wear approved safety goggles.
PROTECTIVE CLOTHING:
Wear appropriate clothing to prevent any possibility of skin contact. Wear rubber apron.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid. Water soluble.
APPEARANCE/PHYSICAL STATE:
Yellow.
COLOR:
No characteristic odor.
ODOR:
Soluble in water.
SOLUBILITY DESCRIPTION:
212 PRESSURE: 760mmHg
BOILING POINT (掳F, interval):
1.263 TEMPERATURE (掳F): 68
DENSITY/SPECIFIC GRAVITY (g/ml):
10.85
pH-VALUE, CONC. SOLUTION:
10. STABILITY AND REACTIVITY
Normally stable.
STABILITY:
CONDITIONS TO AVOID:
Avoid excessive heat for prolonged periods of time. Avoid contact with acids.
HAZARDOUS POLYMERIZATION:
Will not polymerize.
MATERIALS TO AVOID:
Avoid contact with other photographic solutions and/or cleaning compounds.
HAZARDOUS DECOMPOSITION PRODUCTS:
Irritating gases/vapors/fumes of: Sulfur dioxide.
11. TOXICOLOGICAL INFORMATION
hydroquinone 320; Dimezone S 1007 mg/kg (oral rat)
TOXIC DOSE - LD 50:
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TOXICOLOGICAL INFORMATION:
This chemical formulation has not been tested for health effects. Exposure effects listed are based on existing
health data for the individual components which comprise the mixture.
12. ECOLOGICAL INFORMATION
0.1 hydroquinone; >300 DTPA; >1 Dimezone S
LC 50, 96 HRS, FISH, mg/l:
>10 DTPA; 7.1 Dimezone S
EC 50, 48 HRS, DAPHNIA, mg/l:
1.0 hydroquinone
IC 50, 72 HRS, ALGAE, mg/l:
ECOLOGICAL INFORMATION:
Not regarded as dangerous for the environment.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS:
Unused and spent solutions may be allowed to be discharged to sanitary sewer by permit IF allowed by local
regulations. Consult your local authority for advice. Waste may have to be pretreated before discharge. Consult
local authorities before discharging any waste to sewer. Do not discharge to septic system. Waste that cannot be
discharged to sewer may have to handled by a licensed hazardous waste contractor.
14. TRANSPORT INFORMATION
To obtain additional information on packaging for shipment refer to the Code of
GENERAL:
Federal Regulations - CFR 49 and your carrier.
U.S. DOT:
0
UN/NA No.:
No DOT label requirement noted
U.S. DOT HAZARD LABEL:
No classification noted.
U.S. DOT CLASS:
Not classified for road transport
INFORMATION ON ROAD TRANSPORT:
SEA TRANSPORT:
Not classified for sea transport
INFORMATION ON SEA TRANSPORT:
AIR TRANSPORT:
Not classified for air transport
INFORMATION ON AIR TRANSPORT:
15. REGULATORY INFORMATION
REGULATORY STATUS OF INGREDIENTS:
NAME: CAS No: TSCA: CERCLA: SARA 302: SARA 313: DSL(CAN):
POTASSIUM SULFITE 10117-38-1 Yes No No No
POTASSIUM CARBONATE 584-08-7 Yes No No No No
POTASSIUM BROMIDE 7758-02-3 Yes No No No Yes
PHENYLMERCAPTOTETRAZOLE 86-93-1 Yes No No No Yes
DIETHYLENETRIAMINE PENTAACETIC 67-43-6 Yes No No No Yes
ACID-
NA5
1-PHENYL-4-METHYL-4-HYDROXYMETHYL-3-
13047-13-7 Yes No No No Yes
US FEDERAL REGULATIONS:
TSCA: The ingredients of this product are on the TSCA Inventory.
REGULATORY STATUS:
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Hydroquinone: Clean Air Act, S.111 (40 CFR 60-EPA). IARC - Animal carcinogen.
ENVIRONMENTAL LISTING:
IARC-Int. Agency for Cancer Research. DOT Hazardous Mat. Transp. Act (49 CFR).
NTP-Annual Plan (DHHS). NIOSH Criteria Documents. IRPTC-International
Register of Potentially Toxic Chemicals (UNEP). OSHA Chemical Hazard
Communic. Std. - Air Contaminants (29CFR1910). ACGIH Threshold Limit Values.
EPA Reportable & Threshold Quantities. SARA Section 302, Extremely Hazardous
Substances. SARA Section 313, Toxic Chemicals. SARA Title III Consolidated
Chemical List (302, CERCLA, 313, RCRA).
STATE REGULATIONS:
Florida Hazardous Substance List Massachusetts Extraordinarily Hazardous
STATE REGULATORY STATUS:
Substances List Massachusetts Right-to-Know. New Jersey Right-to-Know. NJ
Environmental Hazardous Substances List NJ Special Hazardous Substances List
Pennsylvania Right-to-Know.
16. OTHER INFORMATION
ILFORD IMAGING USA INC. BELIEVES THE INFORMATION AND
USER NOTES:
RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON CORRECT
AND FACTUAL DATA. HOWEVER, NO EXPRESS OR IMPLIED GUARANTEE
OR WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THIS
INFORMATION. USE THIS INFORMATION ONLY TO SUPPLEMENT OTHER
INFORMATION YOU HAVE GATHERED AND THEN MAKE AN
INDEPENDENT DETERMINATION ABOUT THE COMPLETENESS AND
SUITABILITY OF ALL INFORMATION TO INSURE THE PROPER USE AND
DISPOSAL OF THIS PRODUCT AND THE HEALTH AND SAFETY OF
EMPLOYEES AND CUSTOMERS.
European Photographic Chemical Industry Code of Practice For Classification And
INFORMATION SOURCES:
Labelling Material Safety Data Sheet, Misc. manufacturers. Safeware Quasar Ltd
USA Regulatory Information ANSI Z400.1-1998 Material Safety Data Sheets -
Preparation
Dr D W Butcher, ILFORD IMAGING Limited, Mobberley, Knutsford, Cheshire,
PREPARED BY:
WA16 7JL. ENGLAND.
22/5/97
REVISION No./Repl. MSDS of:
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