LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
1 PRODUCT AND COMPANY IDENTIFICATION
EMERGENCY PHONE NUMBERS:
Functional Additives
Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887
2000 Market Street
Medical: Rocky Mountain Poison Control Center
28th Floor
(866) 767-5089 (24Hrs)
Philadelphia, PA 19103-3222
Information Telephone Numbers Phone Number Available Hrs
Customer Service Number (800) 331-7654 8:00 AM - 5:00 PM EST
Product Name LUPEROX 554M75
Product Synonym(s)
Chemical Family Organic Peroxide - Peroxyester
Chemical Formula
Chemical Name Tertiary-Amyl Peroxypivalate
EPA Reg Num
Product Use Polymerization Initiator
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS RegistryNumber Typical % OSHA
t-Amyl hydroperoxide 3425-61-4 < 0.4 N
Di-t-amyl peroxide 10508-09-5 < 0.4 N
2,2-Dimethylpropanoic acid 75-98-9 < 0.5 N
Impurities including: N
Petroleum distillate 64742-48-9 < 25 Y
Odorless mineral spirits 64741-65-7 < 25 Y
tert-Amyl peroxypivalate 29240-17-3 75 Y
The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the
criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
This material is classified as hazardous under Federal OSHA regulation.
The components of this product are either on the TSCA Inventory list or exempt as impurities.
3 HAZARDS IDENTIFICATION
Emergency Overview
Clear liquid, sharp, sweet odor
DANGER!
ORGANIC PEROXIDE
THERMALLY UNSTABLE - REFRIGERATION REQUIRED
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Product Code: 969000 Page 1
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LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. Based on
single exposure animal tests, it is considered to be practically non-toxic if swallowed, no more than slightly toxic if
absorbed through skin, slightly irritating to eyes and severely irritating to skin. Prolonged or repeated contact removes
oils from the skin and may dry skin and cause irritation, redness and rash. High vapor concentrations may be irritating
to the eyes and respiratory tract, and may result in central nervous system (CNS) effects such as headache, dizziness,
nausea, drowsiness and, in severe exposures, loss of consciousness and death. Mild to severe lung injury may occur
if this material is drawn into the lungs (aspirated) during swallowing, or during vomiting after swallowing. Symptoms of
injury may include increased breathing and heart rate, coughing and related signs of respiratory distress.
4 FIRST AID MEASURES
IF IN EYES, immediately flush with plenty of water.
IF ON SKIN, immediately wash with soap and plenty of water. Remove contaminated clothing and shoes.
Get medical attention. Wash clothing before reuse. Destroy contaminated shoes.
IF SWALLOWED, do NOT induce vomiting. Give water to drink. Get medical attention immediately. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF INHALED, remove to fresh air.
5 FIRE FIGHTING MEASURES
Fire and Explosive Properties
Auto-Ignition Temperature NE
Flash Point 46 C / 114 F Flash Point Method Seta CC
Flammable Limits- Upper NE
NE
Lower
Extinguishing Media
Use water spray, foam or dry chemical.
Fire Fighting Instructions
Fight fire with large amounts of water from a safe distance. Use water spray to cool containers exposed to fire.
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out
gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or
equivalent). Fire fighting equipment should be thoroughly decontaminated after use. After a fire, wait until the
material has cooled to room temperature before initiating clean up activities.
Fire and Explosion Hazards
Contact with incompatible materials or exposure to temperatures exceeding the SADT may result in a self
accelerating decomposition reaction with release of flammable vapors which may autoignite.
6 ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Use inert, non-combustible absorbant material such as sodium bicarbonate, sodium carbonate, calcium
carbonate, clean sand or non-acidic clay directly on the spilled peroxide, then wet down (dampen) the mixture
with water. Sweep or scoop up using non-sparking tools and place into a polyethylene bag for disposal. The
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LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
6 ACCIDENTAL RELEASE MEASURES
sweepings should be wetted down further with water. Dispose of immediately. After all of the material has
been collected, wash down the area with detergent and water. Consult a regulatory specialist to determine
appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous
waste disposal and other requirements listed in pertinent environmental permits.
7 HANDLING AND STORAGE
Handling
Contact with incompatible materials or exposure to temperatures exceeding SADT (See Section (9) may
result in a self accelerating decomposition reaction with release of flammable vapors which may autoignite.
Keep away from heat sparks and flame. Avoid contamination. Use only with adequate ventilation. Use
explosion proof equipment. Keep container closed. Do not reuse container as it may retain hazardous
product residue. Minimize exposure to ambient temperatures. flush the area with plenty of water. Remove
contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops
and persists. Thoroughly clean shoes before reuse.
Storage
REFRIGERATION REQUIRED. Detached storage is preferred. Keep out of direct sunlight. Store away
from combustibles and incompatible materials. Refer also to National Fire Protection Agency (NFPA) Code
432, Code for the Storage of Organic Peroxide Formulations. Minimize exposure to ambient temperatures.
To maintain stability and active oxygen content, store below
-7 C (20 F ).
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Investigate engineering techniques to reduce exposures. Provide ventilation if necessary to minimize
exposures. If practical, use local mechanical exhaust ventilation at sources of air contamination such as
open process equipment. Consult ACGIH ventilation manual or NFPA Standard 91 for design of exhaust
systems.
Eye / Face Protection
Use good industrial practice to avoid eye contact.
Skin Protection
Minimize skin contamination by following good industrial hygiene practice. Wearing rubber gloves is
recommended. Wash hands and contaminated skin thoroughly after handling.
Respiratory Protection
Avoid breathing vapor or mist. Where airborne exposure is likely, use NIOSH approved respiratory
protection equipment appropriate to the material and/or its components. Full facepiece equipment is
recommended and, if used, replaces need for face shield and/or chemical goggles. If exposures cannot be
kept at a minimum with engineering controls, consult respirator manufacturer to determine appropriate type
equipment for given application. Observe respirator use limitations specified by NIOSH or the manufacturer.
For emergency and other conditions where there may be a potential for significant exposure, use an
approved full face positive-pressure, self-contained breathing apparatus or positive-pressure airline with
auxiliary self-contained air supply. Respiratory protection programs must comply with 29 CFR 搂 1910.134.
Airborne Exposure Guidelines for Ingredients
Product Code: 969000 Page 3
Revision: 6 Issued: 02 JAN 2007 of 7
LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
The components of this product have no established Airborne Exposure Guidelines
-Only those components with exposure limits are printed in this section.
-Skin contact limits designated with a "Y" above have skin contact effect. Air sampling alone is insufficient to accurately quantitate
exposure. Measures to prevent significant cutaneous absorption may be required.
-ACGIH Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic reactions.
-WEEL-AIHA Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic skin reactions.
9 PHYSICAL AND CHEMICAL PROPERTIES
Clear liquid, sharp, sweet odor
Appearance/Odor
pH NA
Specific Gravity 0.867 @ 0 C
Vapor Pressure NE
Vapor Density NE
Melting Point <-45 C (<-49 F)
Freezing Point NE
Boiling Point NE
Solubility In Water Insoluble
Evaporation Rate NE
Percent Volatile 100 %
SADT 30 C/86 F (30 lb ctn.)
This material is chemically unstable and should only be handled under specified conditions. See HANDLING AND STORAGE section
of this MSDS for specified conditions.
SADT - Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-
accelerating decomposition reaction. This reaction will generate flammable vapors which may autoignite. The length of time to
generated a decomposition reaction, after the SADT has been reached or exceeded, is dependent upon how much the SADT has
been exceeded and the length of time needed for the reaction exotherm (heat spike from increasing decomposition rate) to initiate a
rapid decomposition reaction. Typically, SADT is inversely proportional to package size. Larger packages will have a lower SADT
due to smaller ratio to heat transfer area to volume of product.
Other Physical Data Active Oxygen Content = 6.29-6.46%
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LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
10 STABILITY AND REACTIVITY
Stability
This material is chemically unstable and should only be handled under specified conditions. See HANDLING
AND STORAGE section of this MSDS for specified conditions.
SADT - Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size
will undergo a self-accelerating decomposition reaction. This reaction will generate flammable vapors which
may autoignite. The length of time to generated a decomposition reaction, after the SADT has been reached
or exceeded, is dependent upon how much the SADT has been exceeded and the length of time needed for
the reaction exotherm (heat spike from increasing decomposition rate) to initiate a rapid decomposition
reaction. Typically, SADT is inversely proportional to package size. Larger packages will have a lower SADT
due to smaller ratio to heat transfer area to volume of product.
Hazardous Polymerization
Does not occur.
Incompatibility
Contact wiht foreign materials, such as, strong acids, alkalis, oxidizers, reducing agents, amines,&
promoters/accelerators may result in a violent decomposition reaction or in product degradation.
Hazardous Decomposition Products
Temperatures at or above the SADT can result in the release of hazardous decomposition products which are
flammable and may autoignite.
11 TOXICOLOGICAL INFORMATION
Toxicological Information
Data on this material and/or its components are summarized below.
Single exposure (acute) studies indicate:
Oral - Slightly Toxic to Rats (LD50 4,270 mg/kg)
Dermal - No More Than Slightly Toxic to Rabbits (LD50 >2,000 mg/kg)
Inhalation - Practically Non-toxic to Rats (4-hr LC50 >9.5 mg/l)
Eye Irritation - Non-irritating to Rabbits (0.0/110)
Skin Irritation - Slightly Irritating to Rabbits (2.5/8.0)
Skin allergy was observed in guinea pigs following repeated exposure. Genetic changes were observed in
tests using bacteria and animal cells.
Petroleum distillate/Odorless mineral spirits
Single exposure (acute) studies indicate that this material is practically non-toxic if swallowed (rat LD50 >5,000
mg/kg), no more than slightly toxic if absorbed through skin (rabbit LD50 >3,160 mg/kg) or inhaled (rat 4-hr LC0
12.2 mg/l [592 ppm]), slightly irritating to rabbit eyes and moderately irritating to rabbit skin.
No skin allergy was observed in guinea pigs or humans following repeated exposure, although skin irritation
was noted. Human volunteers exposed to 100 ppm for 6 hours noted no symptoms associated with exposure.
Repeated inhalation studies in rats produced kidney tubule damage in male rats only indicative of hydrocarbon
nephropathy, but extensive studies have demonstrated that these effects occur only in male rats and are not
relevant to humans. Repeated inhalation exposure in dogs produced no adverse effects. Repeated skin
application of these types of materials has produced skin tumors in mice. No birth defects were observed in the
offspring of rats following inhalation exposure during pregnancy. No genetic changes were observed in tests
using bacteria, animal cells or animals.
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LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
12 ECOLOGICAL INFORMATION
Ecotoxicological Information
No data are available.
Chemical Fate Information
No data are available.
13 DISPOSAL CONSIDERATIONS
Waste Disposal
Dispose of in accordance with federal, state and local regulations. Dilution followed by incineration is the
preferred method. Dilution ration of 10:1 in a clean, compatible, combustible solvent (i.e., Fuel Oil #2, mineral
oil) will reduce reactivity hazard during incineration and transportation.
14 TRANSPORT INFORMATION
DOT Name Organic Peroxide Type C, Liquid, Temperature Controlled
DOT Technical Name [Tert-Amyl Peroxypivalate, <= 77%]
DOT Hazard Class 5.2
UN Number UN 3113
DOT Packing Group PG II
RQ
DOT Special Information DOT Control Temperature = 10 C
DOT Emergency Temperature = 15 C
15 REGULATORY INFORMATION
Hazard Categories Under Criteria of SARA Title III Rules (40 CFR Part 370)
Immediate (Acute) Health Y Fire Y
Reactive Y
Delayed (Chronic) Health N
Sudden Release of Pressure N
The components of this product are either on the TSCA Inventory list or exempt as impurities.
Ingredient Related Regulatory Information:
CERCLA RQ SARA TPQ
SARA Reportable Quantities
Petroleum distillate NE
t-Amyl hydroperoxide NE
2,2-Dimethylpropanoic acid NE
Di-t-amyl peroxide NE
tert-Amyl peroxypivalate NE
Odorless mineral spirits NE
New Jersey Right to Know
This product does contain the following chemical(s), as indicated below, currently on the New Jersey Right-to-Know Substances List.
Product Code: 969000 Page 6
Revision: 6 Issued: 02 JAN 2007 of 7
LUPEROX 554M75
Material Safety Data Sheet
Arkema Inc.
New Jersey Right to Know
This product does contain the following chemical(s), as indicated below, currently on the New Jersey Right-to-Know Substances List.
Di-t-amyl peroxide
t-Amyl hydroperoxide
16 OTHER INFORMATION
Revision Information
Revision Number 6
02 JAN 2007
Revision Date
Supercedes Revision Dated 11-OCT-2004
Revision Summary
This material has been transferred to the Functional Additives group.
Key
NE= Not Established NA= Not Applicable (R) = Registered Trademark
Miscellaneous
Back-up or emergency refrigeration should be available in case primary refrigeration is lost. Emergency dry ice
source(s) shoul be known in case of refrigeration failure. Temperature in storage areas should be monitored.
Refrigeration systems should have high temperature alarms to warn of loss of refrigeration.
Arkema Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other materials or in any process. Further, since the conditions and methods of use are
beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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