LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
1 PRODUCT AND COMPANY IDENTIFICATION
EMERGENCY PHONE NUMBERS:
Functional Additives
Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887
2000 Market Street
Medical: Rocky Mountain Poison Control Center
21st Floor
(866) 767-5089 (24Hrs)
Philadelphia, PA 19103-3222
Information Telephone Numbers Phone Number Available Hrs
Customer Service Number (800) 331-7654 8:00 AM - 5:00 PM EST
Product Name LUPEROX TBIC M75
Product Synonym(s)
Chemical Family
Chemical Formula Organic Peroxide - Peroxyester
Chemical Name
EPA Reg Num
Product Use Polymerization Initiator
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS RegistryNumber Typical % OSHA
t-Butyl alcohol 75-65-0 < 0.4 N
Isopropanol 67-63-0 < 0.5 N
tert-Butyl hydroperoxide 75-91-2 < 0.5 N
Impurities including: N
Petroleum distillate 64742-48-9 < 25 Y
Odorless mineral spirits 64741-65-7 < 25 Y
Carbonoperoxoic acid, OO-(1,1-dimethylethyl) O-(1- 2372-21-6 75 Y
methylethyl) ester
The substance(s) marked with a "Y" in the OSHA column, are identified as hazardous chemicals according to the
criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
This material is classified as hazardous under Federal OSHA regulation.
The components of this product are either on the TSCA Inventory list or exempt as impurities.
3 HAZARDS IDENTIFICATION
Emergency Overview
Colorless liquid, pungent odor
DANGER!
ORGANIC PEROXIDE
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
Product Code: 074000 Page 1
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
Potential Health Effects
Inhalation and skin contact are expected to be the primary routes of occupational exposure to this material. Based on
single exposure animal tests, it is considered to be no more than slightly toxic if swallowed or absorbed through skin,
slightly irritating to eyes and severely irritating to skin. Repeated exposure may cause an allergic skin reaction.
Prolonged or repeated contact removes oils from the skin and may dry skin and cause irritation, redness and rash.
High vapor concentrations may be irritating to the eyes and respiratory tract, and may result in central nervous system
(CNS) effects such as headache, dizziness, nausea, drowsiness and, in severe exposures, loss of consciousness and
death. Mild to severe lung injury may occur if this material is drawn into the lungs (aspirated) during swallowing, or
during vomiting after swallowing. Symptoms of injury may include increased breathing and heart rate, coughing and
related signs of respiratory distress.
4 FIRST AID MEASURES
IN CASE OF CONTACT, immediately flush the area with plenty of water. Remove contaminated clothing and
shoes. Get medical attention. Wash clothing before reuse. Destroy contaminated shoes.
IF SWALLOWED, do NOT induce vomiting. Give water to drink. Get medical attention immediately. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF INHALED, remove to fresh air. If breathing is difficult, get medical attention.
5 FIRE FIGHTING MEASURES
Fire and Explosive Properties
Auto-Ignition Temperature
Flash Point Flash Point Method
Flammable Limits- Upper
Lower
Extinguishing Media
Use water spray, foam or dry chemical.
Fire Fighting Instructions
Fight fire with large amounts of water from a safe distance. Use water spray to cool containers exposed to fire.
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out
gear (full Bunker Gear) and self-contained breathing apparatus (pressure demand NIOSH approved or
equivalent). Fire fighting equipment should be thoroughly decontaminated after use. After a fire, wait until the
material has cooled to room temperature before initiating clean up activities.
Fire and Explosion Hazards
Contact with incompatible materials or exposure to temperatures exceeding the SADT may result in a self
accelerating decomposition reaction with release of flammable vapors which may autoignite.
6 ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak
Use inert, non-combustible absorbant material such as sodium bicarbonate, sodium carbonate, calcium
carbonate, clean sand or non-acidic clay directly on the spilled peroxide, then wet down (dampen) the mixture
with water. Sweep or scoop up using non-sparking tools and place into a polyethylene bag for disposal. The
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
6 ACCIDENTAL RELEASE MEASURES
sweepings should be wetted down further with water. Dispose of immediately. After all of the material has
been collected, wash down the area with detergent and water. Consult a regulatory specialist to determine
appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous
waste disposal and other requirements listed in pertinent environmental permits.
7 HANDLING AND STORAGE
Handling
Contact with incompatible materials or exposure to temperatures exceeding SADT (See Section (9) may
result in a self accelerating decomposition reaction with release of flammable vapors which may autoignite.
Keep away from heat sparks and flame. Avoid contamination. Use explosion proof equipment. Do not reuse
container as it may retain hazardous product residue. Avoid contact with eyes, skin and clothing. Wash
thoroughly after handling. Avoid breathing vapor or mist. Keep container closed. Use only with adequate
ventilation.
Storage
Detached storage is preferred. Store out of direct sunlight in a cool well-ventilated place. Store away from
combustibles and incompatible materials. Refer also to National Fire Protection Agency (NFPA) Code 432,
Code for the Storage of Organic Peroxide Formulations. To maintain stability and active oxygen content,
store below 100 F, preferably between 65-85 F.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation
if necessary to control exposure levels below airborne exposure limits (see below). If practical, use local
mechanical exhaust ventilation at sources of air contamination such as open process equipment.
Eye / Face Protection
Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment available.
Skin Protection
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin
contact. Consult glove manufacturer to determine appropriate type glove material for given application.
Wear chemical goggles, a face shield, and chemical resistant clothing such as a rubber apron when
splashing may occur. Rinse immediately if skin is contaminated. Remove contaminated clothing promptly
and wash before reuse. Clean protective equipment before reuse. Provide a safety shower at any location
where skin contact can occur. Wash skin thoroughly after handling.
Respiratory Protection
Avoid breathing vapor or mist. Where airborne exposure is likely, use NIOSH approved respiratory
protection equipment appropriate to the material and/or its components. Full facepiece equipment is
recommended and, if used, replaces need for face shield and/or chemical goggles. If exposures cannot be
kept at a minimum with engineering controls, consult respirator manufacturer to determine appropriate type
equipment for given application. Observe respirator use limitations specified by NIOSH or the manufacturer.
For emergency and other conditions where there may be a potential for significant exposure, use an
approved full face positive-pressure, self-contained breathing apparatus or positive-pressure airline with
auxiliary self-contained air supply. Respiratory protection programs must comply with 29 CFR 搂 1910.134.
Airborne Exposure Guidelines for Ingredients
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
Exposure Limit Value
Isopropanol
ACGIH STEL - 400 ppm
ACGIH TWA - 200 ppm
OSHA TWA PEL - 400 ppm 980 mg/m3
t-Butyl alcohol
ACGIH TWA - 100 ppm
OSHA TWA PEL - 100 ppm (300 mg/m3)
-Only those components with exposure limits are printed in this section.
-Skin contact limits designated with a "Y" above have skin contact effect. Air sampling alone is insufficient to accurately quantitate
exposure. Measures to prevent significant cutaneous absorption may be required.
-ACGIH Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic reactions.
-WEEL-AIHA Sensitizer designator with a value of "Y" above means that exposure to this material may cause allergic skin reactions.
9 PHYSICAL AND CHEMICAL PROPERTIES
Colorless liquid, pungent odor
Appearance/Odor
pH NE
Specific Gravity 0.866 @ 25/25 C
Vapor Pressure NE
Vapor Density NE
Melting Point 5C
Freezing Point NE
Boiling Point NE
Solubility In Water Insoluble
SADT 60 C/140 F (5 gal ctn.)
This material is chemically unstable and should only be handled under specified conditions. See HANDLING AND STORAGE section
of this MSDS for specified conditions.
SADT - Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-
accelerating decomposition reaction. This reaction will generate flammable vapors which may autoignite. The length of time to
generated a decomposition reaction, after the SADT has been reached or exceeded, is dependent upon how much the SADT has
been exceeded and the length of time needed for the reaction exotherm (heat spike from increasing decomposition rate) to initiate a
rapid decomposition reaction. Typically, SADT is inversely proportional to package size. Larger packages will have a lower SADT
due to smaller ratio to heat transfer area to volume of product.
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
10 STABILITY AND REACTIVITY
Stability
This material is chemically unstable and should only be handled under specified conditions. See HANDLING
AND STORAGE section of this MSDS for specified conditions.
SADT - Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size
will undergo a self-accelerating decomposition reaction. This reaction will generate flammable vapors which
may autoignite. The length of time to generated a decomposition reaction, after the SADT has been reached
or exceeded, is dependent upon how much the SADT has been exceeded and the length of time needed for
the reaction exotherm (heat spike from increasing decomposition rate) to initiate a rapid decomposition
reaction. Typically, SADT is inversely proportional to package size. Larger packages will have a lower SADT
due to smaller ratio to heat transfer area to volume of product.
Hazardous Polymerization
Does not occur.
Incompatibility
Contact with foreign materials, such as, strong acids, alkalis, oxidizers, reducing agents, amines and
promoters/accelerators may result in a violent decomposition reaction or in product degradation.
Hazardous Decomposition Products
Temperatures at or above the SADT can result in the release of hazardous decomposition products which are
flammable and may autoignite.
11 TOXICOLOGICAL INFORMATION
Toxicological Information
Data on this material and/or its components are summarized below.
Luperox TBIC M75
Single exposure (acute) studies indicate that this material is no more than slightly toxic if swallowed (rat LD50
>2,000 mg/kg) or absorbed through skin (rat LD50 >2,000 mg/kg), severely irritating to rabbit skin (4-hr
exposure to 50% in odorless mineral spirits; 5.33/8.0) and slightly irritating to rabbit eyes (6.6/110.0).
Skin allergy was observed in guinea pigs following repeated exposure. Genetic changes were observed in
tests using bacteria, but not in tests using animals.
Petroleum distillate/Odorless mineral spirits
Single exposure (acute) studies indicate that this material is practically non-toxic if swallowed (rat LD50 >5,000
mg/kg), no more than slightly toxic if absorbed through skin (rabbit LD50 >3,160 mg/kg) or inhaled (rat 4-hr LC0
12.2 mg/l [592 ppm]), slightly irritating to rabbit eyes and moderately irritating to rabbit skin.
No skin allergy was observed in guinea pigs or humans following repeated exposure, although skin irritation
was noted. Human volunteers exposed to 100 ppm for 6 hours noted no symptoms associated with exposure.
Repeated inhalation studies in rats produced kidney tubule damage in male rats only indicative of hydrocarbon
nephropathy, but extensive studies have demonstrated that these effects occur only in male rats and are not
relevant to humans. Repeated inhalation exposure in dogs produced no adverse effects. Repeated skin
application of these types of materials has produced skin tumors in mice. No birth defects were observed in the
offspring of rats following inhalation exposure during pregnancy. No genetic changes were observed in tests
using bacteria, animal cells or animals.
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
12 ECOLOGICAL INFORMATION
Ecotoxicological Information
No data are available.
Chemical Fate Information
No data are available.
13 DISPOSAL CONSIDERATIONS
Waste Disposal
Dispose of in accordance with federal, state and local regulations. Dilution followed by incineration is the
preferred method. Dilution ration of 10:1 in a clean, compatible, combustible solvent (i.e., Fuel Oil #2, mineral
oil) will reduce reactivity hazard during incineration and transportation.
14 TRANSPORT INFORMATION
DOT Name Organic Peroxide, Type C, Liquid
DOT Technical Name [tert-Butylperoxy isopropylcarbonate, <=77%]
DOT Hazard Class 5.2
UN Number UN 3103
DOT Packing Group PG ll
RQ
15 REGULATORY INFORMATION
Hazard Categories Under Criteria of SARA Title III Rules (40 CFR Part 370)
Immediate (Acute) Health Y Fire Y
Reactive Y
Delayed (Chronic) Health N
Sudden Release of Pressure N
The components of this product are either on the TSCA Inventory list or exempt as impurities.
Ingredient Related Regulatory Information:
CERCLA RQ SARA TPQ
SARA Reportable Quantities
Isopropanol NE NE
Petroleum distillate NE
t-Butyl alcohol NE NE
tert-Butyl hydroperoxide NE NE
Carbonoperoxoic acid, OO-(1,1-dimethylethyl) O-(1-methylethyl) NE
ester
Odorless mineral spirits NE
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
SARA Title III, Section 313
This product does contain chemical(s) which are defined as toxic chemicals under and subject to the reporting requirements of, Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. See Section 2
Isopropanol
t-Butyl alcohol
Massachusetts Right to Know
This product does contain the following chemicals(s), as indicated below, currently on the Massachusetts Right to Know Substance
List.
Isopropanol
t-Butyl alcohol
tert-Butyl hydroperoxide
New Jersey Right to Know
This product does contain the following chemical(s), as indicated below, currently on the New Jersey Right-to-Know Substances List.
Carbonoperoxoic acid, OO-(1,1-dimethylethyl) O-(1-methylethyl) ester
Isopropanol
t-Butyl alcohol
tert-Butyl hydroperoxide
Pennsylvania Environmental Hazard
This product does contain the following chemical(s), as indicated below, currently on the Pennsylvania Environmental Hazard List.
Isopropanol
t-Butyl alcohol
Pennsylvania Right to Know
This product does contain the following chemical(s), as indicated below, currently on the Pennsylvania Hazardous Substance List.
Isopropanol
t-Butyl alcohol
tert-Butyl hydroperoxide
16 OTHER INFORMATION
Revision Information
Revision Number 8
02 JAN 2007
Revision Date
Supercedes Revision Dated 02-JAN-2007
Revision Summary
This product has been moved to the Functional Additives business unit.
Key
NE= Not Established NA= Not Applicable (R) = Registered Trademark
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LUPEROX TBIC M75
Material Safety Data Sheet
Arkema Inc.
Arkema Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other materials or in any process. Further, since the conditions and methods of use are
beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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