MSDS PAGE: CAS 7601-90-3 MSDS chemicalsolutionsinc_com---perchloric

PER C H LO R IC AC ID , 60% , A.C .S. R EAG EN T Page 1 of 3

Chemical Solutions, Inc.
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MATERIAL SAFETY DATA SHEET

SEC TIO N 1. - - - - - - - - - CH EM IC AL ID EN TIFIC ATIO N - - - - - - - - - -
CA TALOG #: 311413
NAM E: PER C HLO RIC AC ID , 60% , A.C .S. R EAG EN T
SEC TIO N 2. - - - - - CO M PO SITIO N /IN FO R M ATIO N ON IN G R ED IEN TS - - - - - -
CAS #: 7601-90-3
M F: H C LO 4
EC N O : 231-512-4
SEC TIO N 3. - - - - - - - - - - H AZAR D S ID EN TIFIC ATIO N - - - - - - - - -
LABEL PR EC AU TIO N AR Y STATEM EN TS
OXID IZIN G
COR RO SIVE
HEATIN G M AY C AU SE AN EXPLO SIO N.
CON TACT W ITH C OM BUSTIBLE M ATERIAL M AY CAU SE FIRE.
CAUSES SEVERE BUR NS.
HAR M FU L IF SW ALLO W ED .
KEEP A W AY FRO M C O M BU STIBLE M ATER IAL.
IN CASE O F AC C ID EN T O R IF YO U FEEL U NW ELL, SEEK M ED IC AL AD VIC E
IM M ED IATELY (SH O W TH E LABEL W H ER E PO SSIBLE).
IN C A SE OF C O N TA C T W ITH E YE S, R IN S E IM M E D IA TE LY W ITH P LE N TY O F
W ATER AND SEEK M EDICAL ADVICE.
W EAR SU ITABLE PR OTEC TIVE C LO TH IN G, G LO VES AN D EYE/FAC E
PR OTEC TIO N.
DO NO T BR EATH E VAPO R.
SEC TIO N 4. - - - - - - - - - - FIR ST-AID M EASU R ES- - - - - - - - - - -
IF SW ALLOW ED, W ASH OU T M OU TH W ITH W ATER PRO VIDED PERSON IS CON SCIOU S.
CALL A PH YSIC IAN .
IF IN H ALED , R EM O VE TO FRE SH AIR . IF BR EATH IN G BEC O M ES D IFFIC U LT,
CALL A PH YSIC IAN .
IN C ASE OF SKIN C ON TACT, FLUSH W ITH C OPIOU S AMO UN TS OF W ATER
FO R AT LEAST 15 M IN U TES. R EM O VE C ON TAM IN ATED CLO TH IN G AN D
SH OES. C ALL A PH YSIC IAN .
IN C ASE OF CO NTACT W ITH EYES, FLUSH W ITH C OPIOU S AMO UN TS OF W ATER
FO R AT LEAST 15 M IN U TES. ASSU R E AD EQ UATE FLU SH IN G BY SEPAR ATIN G
TH E EYELID S W ITH FIN GER S. C ALL A PH YSIC IAN .
SEC TIO N 5. - - - - - - - - - FIR E FIG H TIN G M EASU R ES - - - - - - - - - -
EXTIN G U ISH IN G M ED IA
CAR BO N D IO XID E, D R Y C H EM IC AL PO W D ER OR APPR O PR IATE FO AM .
SPECIAL FIREFIGH TING PROC EDU RES
W EAR SELF-C O N TAIN ED BR EATH IN G APPA RATU S AN D PR O TEC TIVE C LOTH IN G TO
PREVENT CO NTACT W ITH SKIN AN D EYES.
U NU SU AL FIR E AN D EXPLO SIO NS H AZAR D S
EMITS TOXIC FUM ES UND ER FIRE C ON DITION S.
CON TACT W ITH O THER M ATERIAL M AY CAU SE FIRE.
M AY AC C ELER ATE C OM BU STIO N.
SEC TIO N 6. - - - - - - - - AC C ID EN TAL R ELEASE M EASU R ES- - - - - - - - -
AB SO R B ON S AN D O R V ER M IC U LITE AN D P LA C E IN C LO S ED C O N TA IN E R S FO R
DISPO SAL.
VENTILATE AREA AND W ASH SPILL SITE AFTER M ATERIAL PICKU P IS COM PLETE.
EVACU ATE AREA.
W EAR SELF-CO NTAINED BREATHING APPARATUS, RU BBER BOOTS AND HEAVY
RUBBER G LOVES.
SEC TIO N 7. - - - - - - - - - - H AN D LIN G AN D STO R AG E- - - - - - - - - - -
RE FER TO SEC TIO N 8.
SEC TIO N 8. - - - - - - EXPO SU R E C O N TR O LS/PER SO N AL PR O TEC TIO N - - - - - -
DO NO T BR EATH E VAPO R.
D O N O T G ET IN E YE S, O N SK IN , O N C LO TH IN G .
AVOID PR OLONG ED OR REPEATED EXPOSUR E.
KEEP AW AY FRO M CO M BUSTIBLE M ATERIALS, HEAT, SPARKS, AND OPEN FLAM E.
KEEP TIG HTLY C LO SED .
STOR E IN A CO OL DRY PLACE.
USE O NLY IN A C HEM IC AL FU M E H OO D.
SAFETY SH OW ER AN D EYE BATH .
PER C H LO R IC AC ID , 60% , A.C .S. R EAG EN T Page 2 of 3

NIO SH /M SH A-APPR OVED RESPIR ATO R.
COM PATIBLE CH EM ICAL-RESISTANT GLOVES.
CHEM ICAL SAFETY GOG GLES.
W A SH TH O R O U G H LY A FTE R H AN D LIN G .
REM O VE AN D W ASH C O N TAM IN ATED C LO TH IN G PR O M PTLY.
SEC TIO N 9. - - - - - - - PH YSIC AL AN D C H EM IC AL PR O PER TIES - - - - - - -
AP PE AR A N C E A N D O D O R
CO LO R LESS LIQU ID
PHYSICAL PROPERTIES
FLASH PO IN T N ON E
VAPO R PR ESS U R E: 7M M 25 C
SPEC IFIC GR AVITY: 1.535
SW ISS PO ISO N CLASS: 1
SEC TIO N 10. - - - - - - - - -STABILITY AN D R EAC TIVITY - - - - - - - - -
STABILITY
STABLE.
C O N D ITION S TO AVO ID
ALTH OU GH 68-72% C OLD PER C HLO RIC AC ID BEH AVES AS A STR ON G BU T N ON -
O XID IZIN G A C ID , IT B EC O M E S AN E XTR E M E O XID A N T A N D PO W E R FU L D E H YD R A TO R
AT ELEVATED TEM PER ATU R ES (>160'C ) OR W H EN AN H YD R O U S. IT M AY BE FAIR LY
READILY DEH YDR ATED TO THE ANH YDR OU S ACID, E.G. STRO NG CO NC ENTRATED
AC ID S (SU LFU R IC , O LEU M , FU M IN G N ITR IC ), IN OR GAN IC AN H YD R ID ES (SU LFU R
TRIO XID E AN D D IO XID E, PH O SPH O R O U S PEN TO XID E, TH IO N YL C H LO R ID E ETC .),
O R G AN IC A N H YD R ID E S A N D H ALO G EN S . C O N TA C T W ITH A LC O H O LS , G LYC O LS OR
PO LYH YD R OXY C OM PO UN D S PR OD U CE EXPLO SIVE C OM PO UN D S. C ON TAC T W ITH W O OD ,
CELLU LO SE AN D ITS D ER IVATIVES (PAPER , C AR D BO AR D , ETC .) C AN PR OD U CE
VIO LE N T E XP LO S IO N S . A TTE M P TS TO D IS SO LV E B IS M U TH O R ITS ALLO YS IN H O T
PE R C H LO R IC A C ID C A R R IE S A V ER Y H IG H R IS K O F A N EXP LO S IO N O C C U R R IN G .
CO NTAC T W ITH SU LFO XID ES O R ETH ER S M AY PR OD U CE EXPLO SIO NS. TH E
CR YSTALLIN E SALT O BTAIN ED BY THE AC TIO N OF PH O SPH IN E O N 68%
PERC HLOR IC AC ID AT -20'C IS DANG EROU SLY EXPLOSIVE, SENSITIVE TO M OIST
AIR , IN C REASE IN TEM PER ATU R E, O R FR IC TIO N AN D C AN N OT BE D RIED .
VIO LEN T R EAC TIO NS W ITH TR IC H LO RETH YLEN E, SO DIU M PH OSPH IN ATE, ZIN C
PHOSPHIDE, OR GANO PHOSPH OR OU S COM POUN DS AND UN SATUR ATED OR GAINICS H AVE
OC C UR R ED ON HEATIN G W ITH PER C HLO RIC AC ID .
INC OM PATIBILITIES
OR G AN IC M ATER IALS
FIN ELY PO W D ER ED M ETALS
H AZAR D O U S C O M BU STIO N OR D EC O M PO SITIO N PR O D U C TS
CAR BO N M O NO XID E, C AR BO N D IO XID E
H A ZA R D O U S P OLYM E R IZA TIO N
W ILL N OT O CC U R.
SEC TIO N 11. - - - - - - - - - TO XIC O LO G IC AL IN FO R M ATIO N - - - - - - - -
AC U TE EFFECTS
MATERIAL IS EXTREM ELY DESTRUC TIVE TO TISSUE OF THE M UC OU S M EM BRAN ES
AN D U PPER RESPIR ATO RY TR AC T, EYES AN D SKIN .
IN H ALATIO N M AY R ESU LT IN SPASM , IN FLAM M A TIO N AN D ED EM A O F TH E
LARYNX AND BRON CH I, CH EM ICAL PNEUM ON ITIS AND PU LMON ARY EDEM A.
SYM P TO M S O F E XP O SU R E M A Y IN C LU D E BU R N IN G S EN S ATIO N , C O U G H IN G ,
W H EEZIN G, LAR YN GITIS, SH OR TN ESS O F BR EATH , H EAD AC H E, N AU SEA AN D
VO M ITIN G .
TO TH E BEST O F O UR KN OW LED GE, TH E C HEM IC AL, PH YSIC AL, AN D
TO XIC OLO GIC AL PR OPER TIES H AVE N OT BEEN TH OR OU GH LY IN VESTIG ATED .
M AY C AU SE SKIN IR R ITATIO N.
M AY BE H AR M FU L IF ABSO RBED TH R OU GH TH E SKIN .
M AY C AU SE EYE IR R ITATIO N.
M AY BE H AR M FU L IF IN H ALED .
MATERIAL M AY BE IRR ITATING TO M UC OU S M EM BRAN ES AND U PPER
RE SPIR ATOR Y TRA C T.
M AY BE H AR M FU L IF SW ALLO W ED .
R TEC S #: SC 7500000
PER C H LO R IC AC ID
TOXIC ITY D ATA
OR L-R AT LD50:1100 M G /KG GTPZAB 17(8),33,1973
SC U -M U S LD50:250 M G /KG GTPZAB 17(8),33,1973
OR L-D O G LD50:400 M G /KG GTPZAB 17(8),33,1973
TARG ET OR G AN D ATA
BEH AVIO R AL (EXCITEM EN T)
LUN GS, THO RAX OR RESPIRATION (DYSPNAE)
NUTRITION AL AND GR OSS M ETABOLIC (BODY TEM PERATUR E DECR EASE)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CH EM ICAL SUBSTANC ES
(R TE C S) D A TA IS PR E SE N TE D H ER E . S EE AC TU A L E N TR Y IN R TE C S FO R
PER C H LO R IC AC ID , 60% , A.C .S. R EAG EN T Page 3 of 3

CO M PLETE IN FO RM ATIO N.
SEC TIO N 12. - - - - - - - - - EC O LO G IC AL IN FO R M ATIO N - - - - - - - - - -
DATA NOT YET AVAILABLE.
SEC TIO N 13. - - - - - - - - - DISPO SAL C O N SID ER ATIO N S - - - - - - - - -
C O N TA C T A LIC E N SE D PR O FE SS IO N A L W A STE D IS PO S AL S ER V IC E TO D IS PO S E O F
THIS M ATER IAL.
OBSERVE ALL FEDER AL, STATE AND LOC AL ENVIRO NM ENTAL REGU LATION S.
SEC TIO N 14. - - - - - - - - - - TR AN SPO R T IN FOR M ATIO N - - - - - - - - -
CO NTAC T ALD R IC H C H EM IC AL C OM PAN Y FO R TR AN SPO RTATIO N IN FO RM ATIO N.
SEC TIO N 15. - - - - - - - - - REG U LATO R Y IN FO R M ATIO N - - - - - - - - - -
EU R O P EA N IN FO R M A TIO N
EC IN D EX N O : 017-006-00-4
OXID IZIN G
COR RO SIVE
R5
HEATIN G M AY C AU SE AN EXPLO SIO N.
R8
CON TACT W ITH C OM BUSTIBLE M ATERIAL M AY CAU SE FIRE.
R 35
CAUSES SEVERE BUR NS.
S 26
IN C A SE OF C O N TA C T W ITH E YE S, R IN S E IM M E D IA TE LY W ITH P LE N TY O F
W ATER AND SEEK M EDICAL ADVICE.
S 36/37/39
W EAR SU ITABLE PR OTEC TIVE C LO TH IN G, G LO VES AN D EYE/FAC E
PR OTEC TIO N.
S 45
IN CASE O F AC C ID EN T O R IF YO U FEEL U NW ELL, SEEK M ED IC AL AD VIC E
IM M ED IATELY (SH O W TH E LABEL W H ER E PO SSIBLE).
R EVIEW S, STAN D AR D S, AN D R EG ULATIO NS
OEL=MAK
OEL-PO LAN D : M AC (TW A) 1 M G /M 3, M AC (STEL) 3 M G /M 3, JAN 1999
NO H S 1974: H ZD 80182; N IS 34; TNF 2227; NO S 13; TNE 7468
NO ES 1983: H ZD 80182; N IS 27; TNF 1514; N O S 24; TNE 27220; TFE 11531
EPA TSC A SEC TIO N 8(B) C HEM IC AL IN VEN TO RY
EPA TSC A TEST SU BM ISSIO N (TSC ATS) D ATA BAS E, JAN U AR Y 2001
SEC TIO N 16. - - - - - - - - - - OTH ER IN FO R M ATIO N - - - - - - - - - - - -
THE ABO VE IN FOR M ATIO N IS BELIEVE D TO BE C O R R EC T BU T DO ES N O T PU R PO R T TO
BE ALL IN C LU SIVE AN D SH ALL BE U SED ON LY AS A G UID E. SIG M A, ALD R IC H ,
FLU KA SH ALL N OT BE H ELD LIABLE FO R AN Y D AM AG E R ESU LTIN G FR OM H AN D LIN G
O R FR O M C O N T AC T W ITH TH E AB O VE PR O D U C T. S EE R EV ER S E S ID E O F IN V O IC E O R
PACKING SLIP FOR ADD ITION AL TERM S AND C ON DITION S OF SALE.
C O PYR IG H T 2001 S IG M A -A LD R IC H C O .
LIC EN SE G R AN TED TO M AKE U N LIM ITED PAPE R C O PIES FO R IN TER N AL U SE O N LY

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cellsignal_com---antibodies.asp	N/A
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